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“Tuning in” to Mollusk Shell Nacre- and Prismatic-Associated Protein Terminal Sequences. Implications for Biomineralization and the Construction of High Performance Inorganic−Organic Composites

John Spencer Evans2008-09-13Chemical Reviews

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXT“Tuning in” to Mollusk Shell Nacre- and Prismatic-Associated Protein Terminal Sequences. Implications for Biomineralization and the Construction of High Performance Inorganic−Organic CompositesJohn Spencer Evans*View Author Information Laboratory for Chemical Physics, Center…

Calcium Carbonate Crystallization and InhibitionEnzyme Production and CharacterizationDiatoms and Algae Research

Multiplexed Multi-Color Raman Imaging of Live Cells with Isotopically Modified Single Walled Carbon Nanotubes

Zhuang Liu、Xiaolin Li、Scott M. Tabakman 等 6 位作者2008-09-13arXiv

We show that single walled carbon nanotubes with different isotope compositions exhibit distinct Raman Gband peaks and can be used for multiplexed multi-color Raman imaging of biological systems. Cancer cells with specific receptors are selectively labeled with 3 differently colored SWNTs conjugated with various targe…

Materials Science

Role of Chemical Structure in Fragility of Polymers: A Qualitative Picture

K. Kunal、Christopher G. Robertson、Sebastian Pawlus 等 5 位作者2008-09-13OpenAlex

Understanding microscopic parameters that control steepness of the temperature variations of segmental relaxation (fragility) and the glass transition phenomenon remains a challenge. We present dielectric and mechanical relaxation studies of segmental dynamics in various polymers with different side groups and backbon…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Graphene-Based Ultracapacitors

Meryl D. Stoller、Sungjin Park、Yanwu Zhu 等 5 位作者2008-09-13OpenAlex

The surface area of a single graphene sheet is 2630 m(2)/g, substantially higher than values derived from BET surface area measurements of activated carbons used in current electrochemical double layer capacitors. Our group has pioneered a new carbon material that we call chemically modified graphene (CMG). CMG materi…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

In-line broadband 270° (3λ/4) chevron four-reflection wave retarders

R. M. A. Azzam、Hazem K. Khanfar2008-09-12Applied Optics

The net differential phase shift Delta(t) introduced between the orthogonal p and s linear polarizations after four successive total internal reflections inside an in-line chevron dual-Fresnel-rhomb retarder is a function of the first internal angle of incidence phi and prism refractive index n. Retardance of 3lambda/…

Photonic and Optical DevicesOptical Coatings and GratingsOptical Polarization and Ellipsometry

Influence of disorder strength on phase-field models of interfacial growth

Tiia Laurila、Marc Pradas、A. Hernández‐Machado 等 4 位作者2008-09-12Physical Review E

We study the influence of disorder strength on the interface roughening process in a phase-field model with locally conserved dynamics. We consider two cases where the mobility coefficient multiplying the locally conserved current is either constant throughout the system (the two-sided model) or becomes zero in the ph…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenaFluid Dynamics and Thin Films

Probing Crystal Nucleation from Fluid Phases: The Nucleation of para-Azoxyanisole from Its Nematic Liquid Crystalline State

Sophie Janbon、Roger J. Davey、Geoffrey Dent2008-09-12The Journal of Physical Chemistry C

Detailed understanding of structural evolution during the process of crystal nucleation is limited. In this contribution nucleation from the single component nematic phase of para -azoxyanisole is studied with particular emphasis on the structural relationships between liquid crystalline and crystalline phases in this…

Liquid Crystal Research AdvancementsCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Influence of potential on the structure and properties of microarc oxidation coating on Mg alloy

Shu-hao Deng、YI Dan-qing、Gong Zhu‐qing 等 4 位作者2008-09-12Anti-Corrosion Methods and Materials

Purpose To obtain an optimized microarc oxidation (MAO) coating on magnesium alloy from an environmentally‐friendly electrolyte free of Cr 6 + and P O 4 3− and to investigate the influence of oxidation potential on the morphology, composition, structure, and other properties such as micro‐hardness and corrosion resist…

Supercapacitor Materials and FabricationCorrosion Behavior and InhibitionMagnesium Alloys: Properties and Applications

Linear and A2+B3‐type hyperbranched polyesters comprising phenylbenzothiazole unit: Preparation, liquid crystalline, and optical properties

Moriyuki Sato、Atsushi Nakashima、Yuzuru Sato 等 4 位作者2008-09-12Journal of Polymer Science Part A Polymer Chemistry

Abstract Novel liquid crystalline (LC) hyperbranched (HB) polyesters comprising phenylbenzothiazole (PBT) unit as mesogen in the interiors were prepared at various feed mole ratios (A 2 /B 3 ) by solution polycondensation of a dioxydiundecanol derivative of PBT (A 2 monomer) with trimesic acid trimethyl ester (B 3 mon…

Luminescence and Fluorescent MaterialsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Silicon‐containing azo polymers with paired mesogens and their applications to optical memory media

Min‐Jeong Lee、Han‐Na Ji、Yang‐Kyoo Han2008-09-12Journal of Polymer Science Part A Polymer Chemistry

Abstract We synthesized a novel photoresponsive monomer, silicon‐containing azo monomer with paired mesogens in the side chain, by reacting 3‐methacryloxypropylmethyldichlorosilane with 2‐[2‐(4‐cyano‐azobenzene‐4′‐oxy)ethylene‐oxy]ethyl alcohol, a mesogenic group. Corresponding homopolymer and copolymers with methyl m…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

Influence of Aging on Autohesive Tack of Brominated Isobutylene-co-p-methylstyrene (BIMS) Rubber in the Presence of Phenolic Resin Tackifier

K. Dinesh Kumar、Anil K. Bhowmick、Andy H. Tsou2008-09-12The Journal of Adhesion

The role of phenolic resin tackifier on autohesive tack of brominated isobutylene-co-p-methylstyrene (BIMS) rubber was studied by a 180° peel test with particular reference to aging. Phenolic resin showed very little effect on the unaged tack of BIMS rubber. The tack strength of the rubber/resin mixture marginally inc…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Potassium Is an Activator of Homoisocitrate Dehydrogenase from Saccharomyces cerevisiae

Ying Lin、Ann H. West、Paul Cook2008-09-12Biochemistry

Potassium is an activator of the reaction catalyzed by homoisocitrate (HIc) dehydrogenase (HIcDH) from Saccharomyces cerevisiae with either the natural substrate, homoisocitrate, or the slow substrate isocitrate. On the basis of initial velocity studies, the selectivity of the activator site for monovalent ions was de…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Metal Al Produced by H2 Plasma Reduction of AlCl3: A Thermodynamic and Kinetic Study on the Plasma Chemistry

Jie Zheng、Bo Sun、Rong Yang 等 6 位作者2008-09-12The Journal of Physical Chemistry B

In this paper we reported that low temperature plasma may reverse the direction of a chemical reaction. The thermodynamically forbidden reaction between H 2 and AlCl 3 was able to take place with the assistance of low temperature plasma, yielding metal Al. The plasma chemistry of the reaction was investigated by optic…

Graphene research and applicationsEnergetic Materials and CombustionBoron and Carbon Nanomaterials Research

Evidence for the monoclinic–tetragonal phase coexistence in Pb(Zr0.53Ti0.47)O3thin films

E. B. Araújo、E. C. Lima、J. D. S. Guerra 等 6 位作者2008-09-12Journal of Physics Condensed Matter

The structure and ferroelectric properties of PbZr 0.53 Ti 0.47 O 3 thin films were investigated in detail by using the x-ray diffraction technique. The surface morphology of the film was studied by using the atomic force microscopy technique, showing a film with a dense morphology and a smooth surface. Based on recen…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Biomimetic Synthesis of Calcium Carbonate Polymorphs Using the Lamellar Lyotropic Liquid Crystalline Systems of Calcium Dodecyl Sulfate

Qiang Shen、Liancheng Wang、Xinping Li 等 4 位作者2008-09-12Crystal Growth & Design

Lyotropic liquid crystalline phases have immediate relevance in biology because of the prevalence of organized lipid structures in living systems. The incorporation of hydrophilic reagents in water domains with well-defined nanoscale geometry favors the construction of nanostructured materials of inorganics, and/or th…

Calcium Carbonate Crystallization and InhibitionSeaweed-derived Bioactive CompoundsCephalopods and Marine Biology

The Effect of Protonation on the Optical Properties of Conjugated Fluorene–Pyridine Copolymers

Stefan Kappaun、Stephan Horner、Anne‐Marie Kelterer 等 14 位作者2008-09-12Macromolecular Chemistry and Physics

Abstract A series of conjugated alternating and statistical copolymers of fluorene and pyridine are synthesized and characterized. The compounds under investigation, namely poly[2,7‐(9,9‐dihexylfluorenyl)‐ alt ‐(2,6‐pyridinyl)] and poly[2,7‐(9,9‐dihexylfluorenyl)‐ stat ‐(2,6‐pyridinyl)], are prepared by a Suzuki‐type…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Structures and Gelation Properties of a Series of Salts Derived from an Alicyclic Dicarboxylic Acid and n-Alkyl Primary Amines

Amar Ballabh、Tapas Kumar Adalder、Parthasarathi Dastidar2008-09-12Crystal Growth & Design

Structures and the gelation property of a series of primary ammonium hydrogen dicarboxylate salts derived from cyclobutane-1,1-dicarboxylic acid and n-alkyl amines, that is, Me-(CH 2 ) n -NH 2 ( n = 3−15, reacted in 1:1 molar ratio) have been studied systematically as a function of alkyl chain length. While salts with…

Metal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsSupramolecular Self-Assembly in Materials

A2B2 type miktoarm star copolymers via alkyne homocoupling reaction

Eda Güngör、Gürkan Hızal、Ümit Tunca2008-09-12Journal of Polymer Science Part A Polymer Chemistry

Abstract The terminal alkyne homocoupling reaction (oxidative alkyne coupling) is presented here as a new route for the preparation of A 2 B 2 type 4‐miktoarm star copolymer. The block copolymer with terminal alkyne at the junction point prepared by NMP‐ATRP and ROP‐NMP sequential routes is coupled via diyne formation…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Tetraethylenepentamine‐Directed Controllable Synthesis of Wurtzite ZnSe Nanostructures with Tunable Morphology

Baojuan Xi、Shenglin Xiong、Dechen Xu 等 8 位作者2008-09-12Chemistry - A European Journal

A novel tetraethylenepentamine (TEPA)-directed method has been successfully developed for the controlled synthesis of ZnSe particles with distinctive morphologies, including nanobelts, nanowires, and hierarchically solid/hollow spheres. These structures, self-assembled from nanobelts and nanorods, have been synthesize…

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Nonstoichiometric Gelation of Cyclodextrins and Included Planar Guests

Dan Rizkov、Shaul Mizrahi、Jenny Gun 等 6 位作者2008-09-12Langmuir

A generic family of low molecular weight binary gels comprising beta-cyclodextrin (beta-CD) and one of a large variety of polyaromatic hydrocarbons (PAHs) in dimethylformamide (DMF), pyridine, and other polar solvents is described. The system is rather general and robust. It tolerates large changes in each of the majo…

Lipid Membrane Structure and BehaviorSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials