Materials Literature
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Polyacrylamide−metal sulfide (Ag 2 S, Cu 2 S, HgS) nanocomposites with metal sulfide nanoparticles homogeneously dispersed in the polyacrylamide (PAM) matrix have been successfully synthesized using corresponding metal salt, sulfur powder, and acrylamide monomer (AM) in ethylene glycol (EG) by microwave heating. This…
Since many potential drugs are poorly water soluble, there is a high demand for solubilization agents. Here, we describe the synthesis of dendritic core-shell-type architectures based on hyperbranched polyglycerol for the solubilization of hydrophobic drugs. Amphiphilic macromolecules containing hydrophobic biphenyl g…
The frequency degenerate and nondegenerate two-photon absorption (2PA) spectra of direct band gap semiconductor quantum dots are studied. Measuring the spectra for both cases in samples of CdSe and CdTe with different quantum dot sizes and size distributions, we observe that the 2PA spectra and the 2PA coefficient are…
We have studied the statistics of plastic rearrangement events in a simulated amorphous solid at T=0. Events are characterized by the energy release and the ``slip volume'', the product of plastic strain and system volume. Their distributions for a given system size $L$ appear to be exponential, but a characteristic e…
The electromigration-induced shape evolution of two-dimensional vacancy islands on a crystal surface is studied using a continuum approach. We consider the regime where mass transport is restricted to terrace diffusion in the interior of the island. In the limit of fast attachment/detachment kinetics a circle translat…
We study the anomalous Hall conductivity in spin-polarized, asymmetrically confined two-dimensional electron and hole systems, focusing on skew-scattering contributions to the transport. We find that the skew scattering, principally responsible for the extrinsic contribution to the anomalous Hall effect, vanishes for…
We report on organic field-effect transistors with unprecedented resistance against gate bias stress. The single crystal and thin-film transistors employ the organic gate dielectric Cytop(TM). This fluoropolymer is highly water repellent and shows a remarkable electrical breakdown strength. The single crystal transist…
The dynamic behavior of the slip length in a fluid flow confined between atomically smooth surfaces is investigated using molecular dynamics simulations. At weak wall-fluid interactions, the slip length increases nonlinearly with the shear rate provided that the liquid/solid interface forms incommensurable structures.…
We report on how different cluster deposition regimes can be obtained and observed by in situ Scanning Tunneling Microscopy (STM) by exploiting deposition parameters in a pulsed laser deposition (PLD) process. Tungsten clusters were produced by nanosecond Pulsed Laser Ablation in Ar atmosphere at different pressures a…
The spin diffusion/transport in $n$-type (001) GaAs quantum well at high temperatures ($\ge120$ K) is studied by setting up and numerically solving the kinetic spin Bloch equations together with the Poisson equation self-consistently. All the scattering, especially the electron-electron Coulomb scattering, is explicit…
We consider the realistic case of a superconductor with a nonzero density of elastic scatterers, so that the normal state conductivity is finite. The quantum superconductor-metal (QSM) transition can then be tuned by varying either the attractive electron-electron interaction, the quenched disorder, or the applied mag…
In an attempt to extend the range of model jamming transitions, we simulate systems of athermal particles which attract when slightly overlapping. Following from recent work on purely repulsive systems, dynamics are neglected and relaxation performed via a potential energy minimisation algorithm. Our central finding i…
We propose an explanation for the experimentally observed temperature hysteresis of magnetization in single crystals of lanthanum manganite (La0.8Sr0.2MnO3). The phenomenon is interpreted within the framework of a double-exchange model with allowance for the interaction of the magnetic subsystem with a bistable mode o…
We studied electrical transport in magnetic semiconductors, which is determined by scattering of free carriers off localized magnetic moments. We calculated the scattering time and the mobility of the majority and minority-spin carriers with both the effects of thermal spin fluctuations and of spatial disorder of magn…
In this paper, we report the results of equilibrium pressure measurements designed to identify the volatile species in the Cr-O-H system and to resolve some of the discrepancies in existing experimental data. In addition, ab initio calculations were performed to lend confidence to a theoretical approach for predicting…
Self-healing resin systems have been discussed for over a decade and four different technologies had been proposed. However, little work on their application as composite matrices has been published although this was one of the stated aims of the earliest work in the field. This paper reports on the optimization of a…
This contribution details the synthesis and chemical/physical characterization of a series of unconventional twisted pi-electron system electro-optic (EO) chromophores. Crystallographic analysis of these chromophores reveals large ring-ring dihedral twist angles (80-89 degrees) and a highly charge-separated zwitterion…
The efficiency of chemical energy production of a photosynthetic system can be strongly enhanced in the presence of metal nanoparticles. Two competing effects contribute to the photosystem efficiency: plasmon enhancement of photon fields inside the light-absorbing chlorophyll molecules and energy transfer from chlorop…
We report a protocol for manipulating the surface composition of CdSe nanocrystals. By combining the successive ion layer adhesion and reaction (SILAR) method developed by Li et al. J. Am. Chem. Soc. 2003, 125, 12567 with a phosphine-free selenium precursor, the surface stoichiometry of CdSe can be tunably altered fro…
High-quality nanocrystals formed in organic solvents can be completely solubilized in water using amphiphilic copolymers containing poly(ethylene glycol) or PEG. These copolymers are generated using a maleic anhydride coupling scheme that permits the coupling of a wide variety of PEG polymers, both unfunctionalized an…