Materials Literature
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Oleic acid stabilized superparamagnetic iron oxide nanoparticles (SPION) were selected as the cores for fabrication of sub-50-nm monodisperse single-loaded SPION@SiO2 core-shell nanostructures. Parameters that influence the formation of SPION@SiO2 in the water-in-oil reverse microemulsion system have been systematical…
Eindringlinge: Der effiziente Transport von Antikrebswirkstoffen in Zellen gelingt mithilfe reversibel vernetzender Dextrannanopartikel, die unter reduktiven Bedingungen – wie sie im Zellinneren vorherrschen – schnell destabilisiert werden. Die Nanopartikel nehmen große Wirkstoffmengen auf, und sie können Doxorubicin…
Abstract The synthesis, micelle formation, and bulk properties of semifluorinated amphiphilic poly(ethylene glycol)‐ b ‐poly(pentafluorostyrene)‐ g ‐cubic polyhedral oligomeric silsesquioxane (PEG‐ b ‐PPFS‐ g ‐POSS) hybrid copolymers is reported. The synthesis of amphiphilic PEG‐ b ‐PPFS block copolymers are achieved…
This study proposes a one-dimensional sub-wavelength grating structure on GaN surface which behaves as a reflector for transverse-electric polarized light in the blue wavelength range. The rigorous coupled-wave analysis method was used to analyze the effects of various structural parameters on the reflectance spectra…
Evidence obtained by experiments in the gas phase and density functional theory calculations indicates that differences in the CO binding energy to the transition metal site and the overall change in energy and spin multiplicity from reactants to products, underlie the variation in relative reactivity observed for the…
Water-dispersible aminoclay synthesized in a single step process was used as an inorganic filler for preparing polyvinyl alcohol (PVA)-clay hybrid films. The PVA-clay hybrid films with different weight percentages of aminoclay were obtained by simple mixing and casting of aqueous solutions of clay and polymer. The com…
${\text{ScPO}}_{4}$ and ${\text{YPO}}_{4}$ with the tetragonal zircon-structure were studied at room temperature and pressures up to $\ensuremath{\sim}50\text{ }\text{GPa}$. Pressure-induced phase transitions to the sheelite structure occur at 30 GPa for ${\text{ScPO}}_{4}$ and 16.3 GPa for ${\text{YPO}}_{4}$, respect…
Using terahertz time-domain spectroscopy, we investigate the normal incidence transmission through periodically and randomly arranged planar split ring resonators (SRRs). The introduction of positional disorder in metamaterials has no effect on the quality factor of the fundamental inductive–capacitive ( LC ) resonanc…
An investigation into the relationship between the asymmetric and symmetric stretching modes of ancillary carboxylate ligands and their mode of binding in a family of manganese(III) complexes of tetradentate N(2)O(2) Schiff base ligands, which includes comparison of an (18)O isotopically labelled derivative, has been…
A facile seed-assisted electrochemical deposition (ECD) route has been presented to fabricate silver nanoplate arrays at room temperature. The nanoplates are hundreds of nanometres to several micrometres in dimension and tens of nanometres in thickness. All the nanoplates are standing vertically on the indium-tin oxid…
Abstract This highlight summarizes recent attempts and advances of macromolecular sciences to abstract the biological concept of regulation and import it into synthetic polymer systems. The differences of “responsive switching” exploited in smart polymers and “regulation” present in the biological world of proteins ar…
The syntheses, structures, and magnetic properties are reported for three new lanthanide complexes, [Ln(III)(4)(mu(3)-OH)(2)(mu(3)-O)(2)(cpt)(6)(MeOH)(6)(H(2)O)](2) (Ln = Dy (1.15MeOH), Ho (2.14MeOH), and Tb (3.18MeOH)), based on 4-(4-carboxyphenyl)-1,2,4-triazole ligand (Hcpt). The three complexes were confirmed to b…
We present a method of designing diffractive optical elements for transforming and focusing surface plasmons. The method is based on a phase modulation of the surface plasmon provided by the dielectric block with varying geometric parameters located on the interface. The problem of SP diffraction by a dielectric block…
A N-doped microporous carbon was synthesized by using NaY as a hard template and acetonitrile as the carbon and nitrogen precursor. The hydrogen storage measurements indicated that the N-doped microporous carbon had an 18% higher storage capacity than the pure carbon with a similar surface area. Furthermore, hydrogen…
Abstract Microwave (MW)‐assisted cellulose dissolution in ionic liquids (ILs) has routinely led either to incomplete biopolymer solubilization, or its degradation. We show that these problems can be avoided by use of low‐energy MW heating, coupled with efficient stirring. Dissolution of microcrystalline cellulose in t…
Abstract Strong honeycomb like nanocomposite sponges were fabricated from starch and PVA by using repeated cycles of freezing and thawing and reinforcing with cellulose whiskers. Their structure and properties were investigated with WAXD, FT‐IR, SEM, DMTA, rheological measurements, and LSCM. The results revealed that…
Abstract Thermo‐responsive PNIPAAm/PLLA nanofibrous films with tunable surface morphologies and better biocompatibility were prepared by electrospinning technique. The electrospun composite films possessed a “bead‐on‐string” structure. The wettability of nanofibrous films was observed by water CA measurements. The res…
Abstract An improved Single Fiber Tensile Test (SFTT) for the natural fibers was depicted. Natural fibers have irregular shape, and are not uniform along the fiber length and also from one fiber to another. Applying the conventional method, which determine the fiber cross‐section by measuring the fiber diameter using…
Abstract Colloidal Au‐amplified surface plasmon resonance (SPR), like traditional SPR, is typically used to detect binding events on a thin noble metal film. The two major concerns in developing colloidal Au‐amplified SPR lie in 1) the instability, manifested as a change in morphology following immersion in organic so…
Abstract A photoresponsive oil sorber (POS) with a hydrophobic, photoresponsive core and shell has been synthesized via suspension polymerization. Lauryl acrylate, isodecyl acrylate, and tert ‐butylstyrene were used as monomers, 4‐(methacrylamino)azobenzene (Azo‐M) used as photoresponsive monomer, and bis(methacryloyl…