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Characterisation of aluminium alloys after HNO3/HF–NaOH–HNO3/HF pretreatment

K. J. Nelson、A.E. Hughés、Roger Taylor 等 6 位作者2001-10-01Materials Science and Technology

The effect of a pretreatment sequence on several aluminium alloys was examined by X-ray photoelectron spectroscopy and SEM. The pretreatment consisted of vapour degreasing followed by a three step sequence comprising 1 min immersions in (a) nitric acid–hydrofluoric acid solution, (b) sodium hydroxide solution and (c)…

Corrosion Behavior and InhibitionRecycling and Waste Management TechniquesElectron and X-Ray Spectroscopy Techniques

Experimental observations of the stress experienced by a solid surface when a laser-created bubble oscillates in its vicinity

Stephen Shaw、W. P. Schiffers、D. C. Emmony2001-10-01The Journal of the Acoustical Society of America

In an attempt to shed more light on the complex process by which cavities interact destructively with rigid boundaries we consider experimentally the interaction of a laser-generated bubble with a nearby solid boundary. To determine the stresses the surface of the boundary experiences, particularly during the final st…

Laser Material Processing TechniquesUltrasound and Cavitation PhenomenaLaser-Ablation Synthesis of Nanoparticles

High Turnover Numbers for the Catalytic Selective Epoxidation of Alkenes with 1 atm of Molecular Oxygen

Yoshiyuki Nishiyama、Yoshinao Nakagawa、Noritaka Mizuno2001-10-01Angewandte Chemie

Das Dieisen-substituierte Silicowolframat γ-SiW10{Fe3+(OH2)}2O386− (schematisch gezeigt) ist ein effektiver Katalysator für die Oxygenierung von Alkenen in homogener Lösung mit 1 atm O2. So betrugen bei der Epoxidierung von Cycloocten die Selektivität für Cyclooctenoxid 98 % und die Umsatzzahl 10 000. Der Katalysator…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Some Insight into the Effects of Oxygen Diffusion in the Reduction Kinetics of Ceria

Francesca Giordano、Alessandro Trovarelli、Carla de Leitenburg 等 5 位作者2001-10-01Industrial & Engineering Chemistry Research

The aim of this paper is to discuss the main features of the temperature-programmed reduction of high-surface-area ceria in the low-temperature range ( T < 900 K) with particular emphasis on the role of oxygen diffusion. By making use of a cell model for the reaction/diffusion process, it is shown that the observed ki…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Mirrorless Lasing and Energy Transfer in Cholesteric Liquid Crystals Doped with Laser Dyes

M. E. Álvarez‐Ramos、Meng He、Antonio Muñoz 等 7 位作者2001-10-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

Lasing in cholesteric liquid crystal (CLC) films doped with a mixture of laser dyes has been observed under UV excitation with 35ps pulses at 355nm. To probe optical interactions between molecules of different species, the emission and excitation spectra of the constituents have been studied in the 300–700nm range. Tw…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochemistry and Electron Transfer Studies

Energy transfer at optical frequencies to silicon-based waveguiding structures

Brian J. Soller、Dennis G. Hall2001-10-01Journal of the Optical Society of America A

For decades, crystalline silicon (Si) has been the semiconductor of choice for the majority of applications in microelectronics. Recent advances in material science have focused attention on the silicon-on-insulator (SOI) platform, a submicrometer-thick layer of single crystal Si resting on an insulating silicon dioxi…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsSilicon Nanostructures and Photoluminescence

Crystallization Behavior of Syndiotactic Poly(propylene) Freeze-Dried from Toluene at Very Dilute Concentration

Qing Sun、Qiang Fu、Gi Xue 等 4 位作者2001-10-01Macromolecular Rapid Communications

Syndiotactic poly(propylene)s (s-PPs) were freeze-dried from toluene solutions of various concentrations. FT-IR spectroscopy and wide-angle X-ray diffraction were used to characterize the s-PPs prepared. The isothermal crystallization behavior was also investigated by means of differential scanning calorimetry. The di…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Highly sensitive recognition element based on birefringent porous silicon layers

Elisabeth Groß、D. Kovalev、N. Künzner 等 6 位作者2001-10-01Journal of Applied Physics

Anisotropically nanostructured silicon layers exhibit a strong in-plane birefringence. Their optical anisotropy parameters are found to be extremely sensitive to the presence of dielectric substances inside of the pores. Polarization-resolved transmittance measurements provide an extremely sensitive tool to analyze th…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Processing enhancers for rotational molding of polyethylene

Bharat I. Chaudhary、E. Takács、J. Vlachopoulos2001-10-01Polymer Engineering and Science

Abstract Rotational molding is a zero shear process used to manufacture hollow plastic parts. One disadvantage of this process is long cycle times, which are significantly affected by the sintering rates of thermoplastic powder. The objective of this work was to evaluate low molecular weight additives as sintering enh…

Additive Manufacturing and 3D Printing TechnologiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Transverse Thermal Conductivity of Thin C/SiC Composites Fabricated by Slurry Infiltration and Pyrolysis

Min Z. Berbon、Donald R. Dietrich、David B. Marshall 等 4 位作者2001-10-01Journal of the American Ceramic Society

Thin C/SiC composites were fabricated by infiltrating a woven carbon fiber fabric with a slurry of SiC powder and polymer precursor for SiC, followed by heat treatment for pyrolysis. The effects of heat treatment parameters on the crystallization of the polymer‐derived SiC, the composite microstructure, and the transv…

Advanced ceramic materials synthesisThermal properties of materialsAdvanced materials and composites

The crystal chemistry of birefringent natural uvarovites: Part I. Optical investigations and UV-VIS-IR absorption spectroscopy

M. Andrut、Manfred Wildner2001-10-01American Mineralogist

Six garnet crystals with compositions close to the uvarovite-grossular binary from three different localities (Saranov, Veselovsk, and Saranka, Ural Mountains, Russia) were investigated by optical methods, electron microprobe analysis, and polarized UV-VIS-IR micro-spectroscopy. Under crossed polarizers the crystals d…

Crystal Structures and PropertiesMolecular spectroscopy and chiralityMineralogy and Gemology Studies

On recoil-energy-dependent defect accumulation in pure copper Part II. Theoretical treatment

B. N. Singh S. I. Golubov2001-10-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Abstract Over the years, an enormous amount of experimental results have been reported on damage accumulation (e.g. void swelling) in metals and alloys irradiated under vastly different recoil energy conditions. Unfortunately, however, very little is known either experimentally or theoretically about the effect of rec…

Fusion materials and technologiesIon-surface interactions and analysisIntegrated Circuits and Semiconductor Failure Analysis

The Nematic Lateral Phase: A Novel Phase in Discotic Supramolecular Assemblies

Paul H. J. Kouwer、Wolter F. Jager、W Mijs 等 4 位作者2001-10-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTThe Nematic Lateral Phase: A Novel Phase in Discotic Supramolecular AssembliesPaul H. J. Kouwer, Wolter F. Jager, Wim J. Mijs, and Stephen J. PickenView Author Information Delft University of Technology, Polymer Materials and Engine…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsAdvanced Materials and Mechanics

“Real Time” Raman Studies of Electrospun Fibers

Jean S. Stephens、Simon Frisk、Silke Megelski 等 5 位作者2001-10-01Applied Spectroscopy

Raman spectra of as-spun fibers produced through electrospinning have shown that high S/N data can be obtained on 50-μm diameter fibers in relatively short collection times (25 s). Using this same instrumental approach, “real time” Raman spectra of the electrospinning liquid fiber jet at the origin of the jet and 1 cm…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

Influence of the Stirrer Initial Position on Emulsion Morphology. Making Use of the Local Water-to-Oil Ratio Concept for Formulation Engineering Purpose

Serge E. Salager、Eric Tyrode、María-Teresa Celis 等 4 位作者2001-10-01Industrial & Engineering Chemistry Research

The initial location of the stirrer in the emulsification vessel can induce the resulting emulsion type. The interpretation in terms of mixing phenomena leads to the use of the local water-to-oil ratio (WOR) concept in the formulation-composition map. The know-how associated with this phenomenology allows us to interp…

Proteins in Food SystemsFluid Dynamics and MixingPickering emulsions and particle stabilization

Quantification of the graphical details of collagen fibrils in transmission electron micrographs

Yang Xia、K. R. Elder2001-10-01Journal of Microscopy

A novel 2D image analysis technique is demonstrated. Using the digitized images of articular cartilage from transmission electron microscopy (TEM), this technique performs a localized 'vector' analysis at each region that is large enough to include several or tens of collagen fibrils but small enough to provide a fine…

Machine Learning in Materials ScienceMolecular Biology Techniques and ApplicationsCollagen: Extraction and Characterization

Anisotropic Molecule Dopant Method for Synthesizing a Zero-Birefringence Polymer

Akihiro Tagaya、Shuichi Iwata、Eriko Kawanami 等 5 位作者2001-10-01Japanese Journal of Applied Physics

We have demonstrated the anisotropic molecule dopant method for synthesizing a zero-birefringence polymer that showed no orientational birefringence at any orientation degree of polymer chains. In this method, rod-like molecules such as trans -stilbene having opposite polarizability anisotropy to that of a host polyme…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsSynthesis and properties of polymers

The Persistence of Electrostatically Seeded Endothelial Cells Lining a Small Diameter Expanded Polytetrafluoroethylene Vascular Graft

Gary L. Bowlin、Andrew Meyer、Charles Fields 等 7 位作者2001-10-01Journal of Biomaterials Applications

PURPOSE: The purpose of this study was to evaluate the persistence of electrostatically seeded endothelial cells (ECs) lining an expanded polytetrafluorethylene (e-PTFE) graft after one week exposure to in vivo circulation in a canine femoral artery bypass model. This was accomplished by visualizing the PKH 26 (red fl…

Electrospun Nanofibers in Biomedical ApplicationsPeripheral Artery Disease ManagementInfectious Aortic and Vascular Conditions

LaPdO3: The First PdIII Oxide with the Perovskite Structure

Seung‐Joo Kim、Sylvain Lemaux、G. Demazeau 等 5 位作者2001-10-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTLaPdO3: The First PdIII Oxide with the Perovskite StructureSeung-Joo Kim, Sylvain Lemaux, Gérard Demazeau, Jong-Young Kim, and Jin-Ho ChoyView Author Information Institut de Chimie de la Matière Condensée de Bordeaux, UPR.CNRS 9048 87 avenue A. Schweitzer, 33608 Pessac…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Reflection Absorption Infrared Spectra of Thin Solid Films. Molecular Orientation and Film Structure

Pedro Antunes、Carlos José Leopoldo Constantino、Ricardo F. Aroca 等 4 位作者2001-10-01Applied Spectroscopy

The calculated and observed vibrational spectra of a new series of perylene tetracarboxylic derivatives (PTCDs) with different alkyl lateral chain lengths (5, 10, 15, and 20 C) are reported. With the use of characteristic vibrational modes, the question about the degree of molecular organization and packing in these P…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors