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Atomistic Molecular Dynamics Simulations of Peptide Amphiphile Self-Assembly into Cylindrical Nanofibers

One‐Sun Lee、Samuel I. Stupp、George C. Schatz2011-02-22Journal of the American Chemical Society

Relaxation of a self-assembled structure of 144 peptide amphiphile (PA) molecules into cylindrical nanofibers is studied using atomistic molecular dynamics simulations including explicit water with physiological ion concentration. The PA for these studies includes a hydrophobic alkyl chain that is attached to the N-te…

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

Ultrafine Polysaccharide Nanofibrous Membranes for Water Purification

Hongyang Ma、Christian Bürger、Benjamin S. Hsiao 等 4 位作者2011-02-22Biomacromolecules

Ultrafine polysaccharide nanofibers (i.e., cellulose and chitin) with 5-10 nm diameters were employed as barrier layers in a new class of thin-film nanofibrous composite (TFNC) membranes for water purification. In addition to concentration, the viscosity of the polysaccharide nanofiber coating suspension was also foun…

Membrane Separation TechnologiesAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Controlled Intramolecular Electron Transfers in Cyanide-Bridged Molecular Squares by Chemical Modifications and External Stimuli

Masayuki Nihei、Yoshihiro Sekine、N. Suganami 等 8 位作者2011-02-22Journal of the American Chemical Society

A series of cyanide bridged Fe-Co molecular squares, [Co(2)Fe(2)(CN)(6)(tp*)(2)(dtbbpy)(4)](PF(6))(2)·2MeOH (1), [Co(2)Fe(2)(CN)(6)(tp*)(2)(bpy)(4)](PF(6))(2)·2MeOH (2), and [Co(2)Fe(2)(CN)(6)(tp)(2)(dtbbpy)(4)](PF(6))(2)·4H(2)O (3) (tp = hydrotris(pyrazol-1-yl)borate, tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate,…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Diels−Alder Chemistry of Graphite and Graphene: Graphene as Diene and Dienophile

Santanu Sarkar、Elena Bekyarova、Sandip Niyogi 等 4 位作者2011-02-22Journal of the American Chemical Society

The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strategy for the reversible modification of the electronic properties of graphene under very mild conditions.

Graphene research and applicationsMolecular Junctions and NanostructuresFullerene Chemistry and Applications

CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2

Fan Yang、Jesús Graciani、Jaime Evans 等 7 位作者2011-02-22Journal of the American Chemical Society

A Cu(111) surface displays a low activity for the oxidation of carbon monoxide (2CO + O(2) → 2CO(2)). Depending on the temperature, background pressure of O(2), and the exposure time, one can get chemisorbed O on Cu(111) or a layer of Cu(2)O that may be deficient in oxygen. The addition of ceria nanoparticles (NPs) to…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

The Effect of Interlayer Adhesion on the Mechanical Behaviors of Macroscopic Graphene Oxide Papers

Yun Gao、Luqi Liu、Sheng‐Zhen Zu 等 7 位作者2011-02-22OpenAlex

High mechanical performances of macroscopic graphene oxide (GO) papers are attracting great interest owing to their merits of lightweight and multiple functionalities. However, the loading role of individual nanosheets and its effect on the mechanical properties of the macroscopic GO papers are not yet well understood…

Graphene research and applicationsFiber-reinforced polymer compositesGraphene and Nanomaterials Applications

More than the Ions: The Effects of Silver Nanoparticles on Lolium multiflorum

Liyan Yin、Yingwen Cheng、Benjamin Espinasse 等 9 位作者2011-02-22OpenAlex

Silver nanoparticles (AgNPs) are increasingly used as antimicrobial additives in consumer products and may have adverse impacts on organisms when they inadvertently enter ecosystems. This study investigated the uptake and toxicity of AgNPs to the common grass, Lolium multiflorum. We found that root and shoot Ag conten…

TiO2 Photocatalysis and Solar CellsNanoparticles: synthesis and applicationsEnvironmental remediation with nanomaterials

Pharmaceutical Crystallization

Jie Chen、Bipul Sarma、James M. B. Evans 等 4 位作者2011-02-22OpenAlex

Crystallization is crucial in the pharmaceutical industry as a separation process for intermediates and as the final step in the manufacture of active pharmaceutical ingredients (APIs). In this perspective article to celebrate 10 years of Crystal Growth & Design, we focus on three areas related to crystallization in t…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

The Influence of Basalt Fiber Orientation on the Mechanical Property of Composite Board

Fei Zhu、Zhi Li Zhong、Hua Wu Liu 等 4 位作者2011-02-21Advanced materials research

The composite board was made of chopped basalt and polypropylene fibers. The manufacturing process included blending, carding, web formation, laminating and compression molding. The tension and bending properties were investigated experimentally. The load - displacement curve of the tensile test revealed that the elas…

Wood Treatment and PropertiesTextile materials and evaluationsMaterial Properties and Processing

Influence of Yttrium and Heat Treatment on Microstructure and Mechanical Properties of AM60 Alloy

Zheng Tian、Zhan Yi Cao、Jian Meng2011-02-21Advanced materials research

The effect of yttrium addition and heat treatment on the mechanical properties and microstructure of AM60 magnesium alloy have been investigated using X-ray phase analysis, microstructure investigation, tensile test, hardness measurement and fracture surfaces analysis. The results showed that the mechanical properties…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Synthesis and Characterization of Pyrochlore Lead Zinc Niobate Nanopowders Derived from Zn<sub>3</sub>Nb<sub>2</sub>O<sub>8</sub> Precursor

Phakkhananan Pakawanit、Supon Ananta2011-02-21Advanced materials research

A novel approach to synthesis cubic pyrochlore lead zinc niobate-based Pb 1.88 Zn 0.3 Nb 1.25 O 5.305 nanopowders with a modified mixed-oxide method has been developed. To ensure a pure phase pyrochlore formation, an intermediate phase of Zn 3 Nb 2 O 8 was employed as key precursor. The formation of pyrochlore phase i…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Photocatalytic Activity of W Doped Ta<sub>2</sub>O<sub>5</sub> Particles for Methylene Blue Degradation under UV-Light

Yan Zhao、Li Hou、Xiang Li 等 5 位作者2011-02-21Advanced materials research

Tungsten doped tantalum oxide (W-Ta 2 O 5 ) particles were synthesized by a low temperature hydrothermal method. The phase structure of W-Ta 2 O 5 particles was characterized by X-ray diffraction (XRD). The XRD results indicated that the samples belonged to orthorhombic crystal. The photocatalytic activity of samples…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Recent Developments in PA6/PP Nanocomposites

Hassan Azman、Muhammad Imran、Mat Uzir Wahit 等 4 位作者2011-02-21Key engineering materials

An overview of the recent developments in PA6/PP blend nanocomposites is presented in this paper with an emphasis on their mechanical, thermal and morphological properties. The role of organoclay as a reinforcing agent and polyethylene octene (POE) as an elastomer are discussed in detail. The organoclay increases the…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Influence of Surface Modifications on Interfacial Interaction of Zeolite Filled Polymer Composites

N. D. Zaharri、Nadras Othman、Z. A. Mohd Ishak2011-02-21Key engineering materials

Interfacial interaction in zeolite filled polymer composites was investigated in this study. Two types of polymer which are polypropylene (PP) and ethylene vinyl acetate (EVA) were used as matrix in the preparation of the composites. Moreover, different modifications of zeolite filled polymer composites such as zeolit…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

The Microwave Electromagnetic Properties of Sr<sup>2+</sup> Doped DyFeO<sub>3</sub>

Yan Shao、Xiao Gu Huang、Feng Dai 等 6 位作者2011-02-21Advanced materials research

Perovskite type ferrite doped with Sr 2+ , Dy 1-x M x FeO 3 (x = 0.0, 0.05, 0.15, 0.25) were prepared by the conventional solid-state reaction. The structure and electromagnetic properties of the calcined samples were studied using powder X-ray diffraction (XRD, Rigaku D/Max-2500) and network analyzer (Agilent 8722ET)…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

A Composite Consisting of a Set of Hexagonal Ceramic Bars - The Numerical Study of the Ballistic Resistance

Sebastian Stanisławek、A. Morka、T. Niezgoda2011-02-21Key engineering materials

The paper presents a numerical study of a double layer composite panels impacted by a AP (Armor Piercing) 51WC projectile. The standard panel is built with aluminum and Al2O3 ceramic continuum layers while the studied model consists of the same aluminum plate but the front one is built with a set of hexagonal ceramic…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

PVP Stabilized Ruthenium (0) Nanorods as Effective Catalysts in Hydrogen Generation from the Hydrolysis of Sodium Borohydride

Shu Peng、Jun Na Liu、Xiaofei Liu 等 5 位作者2011-02-21Advanced materials research

Poly (N-vinyl-2-pyrrolidone) (PVP) - stabilized ruthenium (0) nanorods have been successfully synthesized by refluxing ruthenium (Ⅲ) chloride (RuCl 3 ) in low boiling point alcohols (including ethanol, n-propanol, and n-butanol) using microwave heating for the first time. The effects of low boiling point alcohols on t…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

The Effect of Aging Temperature on Mechanical Properties of Banana Pseudostem Fiber Reinforced Polymer Composite

Siti Nur Zafirah M. Zain、Z.N. Ismarrubie、E.S. Zainudin2011-02-21Key engineering materials

Polymer composites using natural fibers as the reinforcing agents have found their use in many applications. The initial development of polymer composite based on high density polyethylene (HDPE) with banana pseudostem fiber was studied based on the effect of non-aging and aging treatments. Tensile, flexural and impac…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical ApplicationsMechanical Engineering and Vibrations Research

Fabrication and Characterization of Unidirectional Silk Fibre Composites

Mansur Ahmed、Md. Saiful Islam、Qumrul Ahsan 等 4 位作者2011-02-21Key engineering materials

Natural fibres offer a number of benefits as reinforcement for synthetic polymers since they have high specific strength and stiffness, high impact strength, biodegradability etc. The aim of this study is to fabricate and determine the performance of unidirectional silk fibre reinforced polymer composites. In the pres…

Natural Fiber Reinforced CompositesSilk-based biomaterials and applicationsMechanical Engineering and Vibrations Research

Effect of Fibre Size and Fibre Loading on Tensile Properties of Hybridized Kenaf/PALF Reinforced HDPE Composite

I. S. Aji、E.S. Zainuddin、Khalina Abdan 等 4 位作者2011-02-21Key engineering materials

Hybridization, especially where only variant natural lignocelluloses are combined, is fast receiving encouraging attention because it offers range of properties that are quite difficult to obtain with a single kind of reinforcement. In this work, tensile strength and modulus of hybridized kenaf/PALF reinforced HDPE co…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesCellular and Composite Structures