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Influence of Triphenyl Phosphate on Degradation Kinetics of Ultrahigh-molecular-weight Polyethylene in Inert and Oxidative Media

О. П. Коробейничев、Alexander A. Paletsky、Munko Gonchikzhapov 等 6 位作者2013-01-01Procedia Engineering

The kinetics and the mechanism of thermal decomposition of ultrahigh-molecular-weight polyethylene without additive and with TPP additives in oxidative and inert media has been studied using the method of differential mass-spectrometric thermal analysis at a high heating rate and the method of thermogravimetric analys…

Polymer Nanocomposites and PropertiesThermal and Kinetic AnalysisPolymer Science and PVC

Dielectric and Piezoelectric Properties of 2–2 PZT-Portland Cement Composites

Arnon Chaipanich、Rattiyakorn Rianyoi、Ruamporn Potong 等 5 位作者2013-01-01Integrated ferroelectrics

Piezoelectric composites made from lead zirconate titanate (PZT) and cement are developed as sensors in smart concrete structures due to its compatibility to the host structure concrete. In this work, PZT ceramic-Portland cement composites of 2–2 connectivity were produced using a dice and fill method and their dielec…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric materials and actuators

Electrical Conductivity of NaNO2Confined within Porous Glass

Л. Н. Коротков、V. Dvornikov、Marina P. Vlasenko 等 6 位作者2013-01-01Ferroelectrics

The AC electrical conductivity (σ) of polycrystalline NaNO2 and SiO2-NaNO2 composite, prepared by embedding of sodium nitrite into porous glasses with 7, 46 and 320 nm average pore diameter, have been studied at frequencies of 0.1 Hz–1 MHz within temperature range of 300–500 К. It was found a considerable increase of…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

The Fabrication and Output Power Characteristics of a Heat-Engine using a Shape Memory Alloy Spiral Spring Actuator

H. Cho、Masato SENJU、Yoichi Takeda 等 5 位作者2013-01-01Transactions of the Materials Research Society of Japan

Heat-engines using shape memory alloy (SMA) were expected to be employed as heat-engines driven by low-temperature thermal energy. Therefore, some trial products of heat-engines using SMA were produced and studied. However, since the inhomogeneous temperatures of the SMA element result during heating / cooling of the…

Shape Memory Alloy TransformationsCreativity in Education and Neuroscience

Reliability Provision of Rod Shells of Steady Roofs over Stadium Stands at Stage of Design Work

Yevgen Gorokhov、Volodymyr Mushchanov、Iurii Priadko2013-01-01Procedia Engineering

The design work of the spatial pivotal roof with a cut-out in the elliptic setting formed by the system of rigid threads through the sections based on determination of a numerical safety index of a designed structure has been described. The proposed method provides the sequence of solution of problem series: determina…

Structural mechanics and materials

Cleavable and removable polymer thermosets for organic field effect transistor packaging

Arulraj Arulkashmir、Manik Bhosale、Kothandam Krishnamoorthy2013-01-01RSC Advances

Recent years have witnessed tremendous progress in the design and synthesis of electroactive materials for the fabrication of organic electronic devices. However, very little research effort has been devoted to developing organic packaging materials, which are crucial for the efficient functioning of the devices. Poly…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Photoinduced anisotropy in an ensemble of CdSe/ZnS quantum rods

Maria Mukhina、В. Г. Маслов、А. В. Баранов 等 5 位作者2013-01-01RSC Advances

The photoluminescence anisotropy in initially disordered quantum rod ensemble induced by selective photochemical reaction under continuous irradiation with polarized light is demonstrated. A specific long-time relaxation of the photoinduced anisotropy in darkness, which is attributed to rotational diffusion of nanocry…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Adiabatic Temperature Change in Metamagnetic Ni(Co)-Mn-Al Heusler Alloys

Vladimir Khovaylo、Maria Lyange、Konstantin Skokov 等 7 位作者2013-01-01Materials science forum

Two representatives of Ni(Co)-Mn-Al metamagnetic shape memory alloy system, Ni45Co5Mn31Al19 and Ni35Co15Mn35Al15, have been studied with respect to their magnetocaloric properties. Experimental study of the magnetocaloric effect by a direct measurement of the adiabatic temperature change ΔTad revealed that in both the…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsCreativity in Education and Neuroscience

A bis(terpyridine)iron network polymer on carbon for a potential energy storage material

Kuo‐Hui Wu、Hiroaki Maeda、Tetsuya Kambe 等 7 位作者2013-01-01Dalton Transactions

A bis(terpyridine)iron network polymer was fabricated by electropolymerisation on a glassy carbon electrode. The modified electrode allowed high-speed charging and discharging with a minor capacity decay (only 5% after 3000 cycles at 1 V s(-1)).

Supercapacitor Materials and FabricationConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry

Spectral Investigation of Crystalline (CuHPO4, Cu2P4O12,and Cu2P8O22) and Glassy Copper Phosphates

C Günther、D. Stachel、L.D. Bogomolova2013-01-01Advances in Condensed Matter Physics

Emerald green crystals of the new composition CuHPO 4 were synthesized and compared to (copper metaphosphate) Cu 2 P 4 O 12 and (copper ultraphosphate) Cu 2 P 8 O 22 . Various copper ultraphosphate and metaphosphate glasses of different compositions between pure P 2 O 5 and Cu 2 P 4 O 12 were melted in crucibles or in…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Studies in Effect of Low Concentration of Cenosphere on Mechanical, Thermal, Electrical, Crystallinity, Colorimetric and Morphological Properties of Epoxy Cured with Triethylenetetramine

Pravin Kadam、Bhushan Pawar、S. T. Mhaske2013-01-01Journal of Minerals and Materials Characterization and Engineering

Cenospheres are produced in very large amount in thermal power plants. They are always looked upon as fillers used to reduce the density and cost of the polymer. If cenosphere particles are allowed to remain properly dispersed by taking it in lower concentration, significant improvement in its mechanical, thermal, ele…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsPolymer Nanocomposite Synthesis and Irradiation

Generation and Propagation of Ultrasonic Waves in Piezoelectric Graphene Nanoribbon

Rabiu Musah、S. Y. Mensah、S. S. Abukari 等 6 位作者2013-01-01Open Journal of Acoustics

Generation and propagation of ultrasonic waves in single layer Graphene Nanoribbon is studied using semi-classical approach. When piezoelectric Graphene Nanoribbon (GNR) is exposed to time varying light beam, ultrasonic waves are produced which propagate in the medium. At low frequencies, we observed oscillations of t…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Fluorescence in arthropoda informs ecological studies in anchialine crustaceans, Remipedia, and Atyidae

Dawn Glenn、Roy L. Caldwell、M. Joey Pakes2013-01-01Journal of Crustacean Biology

Autofluorescence is pervasive throughout the natural world and occurs in many animals, plants, and minerals. Fluorescent properties vary predictably over molt cycles of arthropod exoskeletons. This study examines intrinsic fluorescence in scorpions and crustaceans using novel fluorometric analyses and microscopy. Anch…

Protist diversity and phylogenySubterranean biodiversity and taxonomyDiatoms and Algae Research

Report on Carbon Nano Material Workshop: Challenges and Opportunities

S. K. Acharya、Jorge Alvarado、Debjyoti Banerjee 等 28 位作者2013-01-01Nanoscale and Microscale Thermophysical Engineering

The objective of this workshop was to focus on new directions in carbon nanomaterial research, with a particular focus on new frontiers in nanotube alignment and applications of nanofluids. The first Carbon Nano Material Workshop was held at the Radisson Hotel, Rapid City, South Dakota, from October 30 to November 1,…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchNanopore and Nanochannel Transport Studies

Multilevel Tunnelling Systems and Fractal Clustering in the Low‐Temperature Mixed Alkali‐Silicate Glasses

Giancarlo Jug、Maksym Paliienko2013-01-01The Scientific World JOURNAL

The thermal and dielectric anomalies of window-type glasses at low temperatures (T < 1 K) are rather successfully explained by the two-level systems (2LS) standard tunneling model (STM). However, the magnetic effects discovered in the multisilicate glasses in recent times, magnetic effects in the organic glasses, and…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Use of Si-N-Fe and B-N-Fe compositions for formaldehyde degradation in combined heterogeneous and homogeneous catalytic processes

L. N. Skvortsova、Л. Н. Чухломина、Г. М. Мокроусов 等 4 位作者2013-01-01Russian Journal of Applied Chemistry

The catalytic activity of B-N-Fe and Si-N-Fe compositions toward formaldehyde degradation in aqueous solutions by ozonation and UV irradiation was examined in relation to the time of exposure, phase composition and weight of the catalyst, and amount of oxalic acid added. The conditions for complete degradation of form…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsCatalytic Processes in Materials Science

Mechanical Properties of Elastomeric Terpolymer Composites Containing Carbon Nanotubes

Shibiao Zhou、Anguo Xiao、Xiaobing Huang 等 6 位作者2013-01-01Polymer-Plastics Technology and Engineering

Nanocomposites were obtained by mixing terpolymer and carbon nanotubes (CNTs) in a twin-screw extruder at 135–155°C. The results indicated that increasing the amount of PSt, the molecular weight of PSt macromonomer of terpolymers and CNTs charged resulted in improving the tensile strength and modulus at 300% elongatio…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsTribology and Wear Analysis

Absolute Luminous Flux and Quantum Yield of Sm<sup>3+</sup>-Doped Cadmium-Aluminum-Silicate Glasses under the Pumping of Blue Light Emitting Diode

Yu Lei、Fang Fang Fu、Zheng Li 等 6 位作者2013-01-01Applied Mechanics and Materials

Absolute luminous flux and quantum yield for multichannel transition emissions have been determined in samarium ion (Sm 3+ )-doped cadmium-aluminum-silicate (CAS) glasses under the pumping of blue light emitting diode (LED) using an integrating sphere of 30 cm diameter, which connected to a CCD detector with a 400 μm-…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Investigations of g-factor for Ti3+, V4+ and Cr5+ in anatase

Lianxuan Zhu、Minjie Wang2013-01-01Dalton Transactions

The g-factor formulas for d(1) ions in anatase are deduced from the Jahn-Teller effect and contributions of the charge transfer levels. The tetragonal distortions R∥-R⊥ (where R∥ and R⊥ denote the metal-ligand distances parallel with and perpendicular to the tetragonal axis) for Ti(3+), V(4+) and Cr(5+) in anatase are…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesChemical Synthesis and Characterization

The protonation state of trans axial water molecule switches: the reactivity of high-valent manganese-oxo porphyrin

Jérôme Trzcionka、Joris Irvoas、Geneviève Pratviel2013-01-01New Journal of Chemistry

The cationic manganese porphyrin (Mn-TMPyP) was activated by an oxygen atom donor KHSO5 (oxone) to form a high-valent manganese-oxo species (MnVO) in aqueous buffer. The high-valent MnVO mediated oxidative damage of short double-stranded DNA models. The nature of the oxidation products (guanine oxidation DGh, 2Ih, imi…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms