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Alteration of Chain Length Substrate Specificity of Aeromonas caviae R -Enantiomer-Specific Enoyl-Coenzyme A Hydratase through Site-Directed Mutagenesis

Takeharu Tsuge、Tamao Hisano、Seiichi Taguchi 等 4 位作者2003-08-01Applied and Environmental Microbiology

Aeromonas caviae R-specific enoyl-coenzyme A (enoyl-CoA) hydratase (PhaJ(Ac)) is capable of providing (R)-3-hydroxyacyl-CoA with a chain length of four to six carbon atoms from the fatty acid beta-oxidation pathway for polyhydroxyalkanoate (PHA) synthesis. In this study, amino acid substitutions were introduced into P…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Consequence of Intermittent Exposure to Moisture and Salt Fog on the High‐Temperature Fatigue Durability of Several Ceramic‐Matrix Composites

Larry P. Zawada、James M. Staehler、Steve Steel2003-08-01Journal of the American Ceramic Society

Fatigue behavior of four ceramic‐matrix composites (CMCs) was documented at 1000°C, and a fifth composite was documented at 1200°C. Additional fatigue specimens were cycled for set blocks of cycles, removed from the fatigue machine, and exposed in a cyclic corrosion tester for 24 h with a fog of deionized water and a…

Advanced ceramic materials synthesisThermal properties of materialsAdvanced materials and composites

Protection of plants from frost using hydrophobic particle film and acrylic polymer

Michael P. Fuller、Faisal Hamed、Michael Wisniewski 等 4 位作者2003-08-01Annals of Applied Biology

Summary Frost damage to potatoes, grapevine and citrus plants was assessed following treatment with either an acrylic polymer (Antistress™) or with a hydrophobic particle film (CM‐96–018). In large freezing tests, the application of the hydrophobic particle film consistently led to less damage whilst the acrylic polym…

Surface Modification and SuperhydrophobicityPlant Surface Properties and TreatmentsTurfgrass Adaptation and Management

Direct observation of confined states in metallic single-walled carbon nanotubes

Theophilos Maltezopoulos、André Kubetzka、Markus Morgenstern 等 6 位作者2003-08-01Applied Physics Letters

We investigated the local density of states (LDOS) of extended individual metallic single-walled carbon nanotubes using low-temperature scanning tunneling spectroscopy. We observed that the LDOS oscillates with energy close to the Fermi level. The oscillation period of about 50 meV varies with position on the nanotube…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Delivery of an anticancer drug and a chemosensitizer to murine breast sarcoma by intratumoral injection of sulfopropyl dextran microspheres

Zhi Liu、James R. Ballinger、Andrew M. Rauth 等 5 位作者2003-08-01Journal of Pharmacy and Pharmacology

Intratumoral injection of controlled-release microsphere formulations of anticancer compounds has the potential to selectively increase tumour exposure to drugs. This work aimed to evaluate the therapeutic effect and toxicity of microsphere formulations containing the anticancer drug, doxorubicin, in a murine tumour m…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsRNA Interference and Gene Delivery

SEM Observations of the Fractured Surfaces of Coir Composites

J. Rout、Manjusri Misra、Amar K. Mohanty 等 5 位作者2003-08-01Journal of Reinforced Plastics and Composites

Coir composites had been prepared using coir fiber (both continuous and short fiber) as reinforcement with both thermosetting and thermoplastics as matrices. The composite specimens were prepared using both untreated and chemically modified such as defatted, PMMA grafted, PAN grafted and cyanoethylated coir fibers. Co…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Chemistry of Mg Smectites in Lacustrine Sediments from the Vicalvaro Sepiolite Deposit, Madrid Neogene Basin (Spain)

Jaime Cuevas、R. Vigil de la Villa、Susana Ramirez 等 6 位作者2003-08-01Clays and Clay Minerals

Abstract The chemical and structural properties of Mg smectites in the Vicálvaro sepiolite deposit have been studied in detail. The characterization was performed on different size-fractions of selected smectitic samples (5−2 µm; 2−1 µm; 1−0.5 µm; <0.5 µm and <0.1 µm). The chemical compositions of individual par…

Clay minerals and soil interactionsIron oxide chemistry and applicationsTherapeutic Uses of Natural Elements

Titanium coordination in silicate glasses investigated using O K-edge X-ray absorption spectroscopy

Grant S. Henderson、Xiaoyang Liu、Michael E. Fleet2003-08-01Mineralogical Magazine

Abstract A series of titanium silicate glasses along the composition joins TiO 2 -SiO 2 , TiO 2 -Na 2 SiO 3 , TiO 2 -K 2 SiO 3 and TiO 2 -CaSiO 3 , has been examined using oxygen K -edge X-ray absorption near edge structure spectroscopy (XANES) confined to the near-surface region. Sharp pre-edge features in the spectr…

Glass properties and applicationsX-ray Spectroscopy and Fluorescence AnalysisNuclear materials and radiation effects

Geometric and electronic structure ofTi2AlX(X=V,Nb,orTa)

Qing‐Miao Hu、Rong Yang、Dongdong Xu 等 6 位作者2003-08-01Physical review. B, Condensed matter

Using a first-principles plane-wave pseudopotential method, the geometric and electronic structures of ${\mathrm{Ti}}_{2}\mathrm{Al}X$ $(X=V,$ Nb, or Ta) are investigated. The supercells of ${\mathrm{Ti}}_{2}\mathrm{Al}X$ are constructed by replacing certain Ti atoms in ${\ensuremath{\alpha}}_{2}\ensuremath{-}{\mathrm…

Intermetallics and Advanced Alloy PropertiesBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Futile Cycling of Intermediates of Fatty Acid Biosynthesis toward Peroxisomal β-Oxidation in Saccharomyces cerevisiae

Silvia Marchesini、Yves Poirier2003-08-01Journal of Biological Chemistry

The flux of fatty acids toward beta-oxidation was analyzed in Saccharomyces cerevisiae by monitoring polyhydroxyalkanoate synthesis in the peroxisome from the polymerization, by a bacterial polyhydroxyalkanoate synthase, of the beta-oxidation intermediates 3-hydroxyacyl-CoAs. Synthesis of polyhydroxyalkanoate was depe…

biodegradable polymer synthesis and propertiesPeroxisome Proliferator-Activated ReceptorsBiochemical Acid Research Studies

Chemical Resistance and Tensile Properties of Epoxy/Unsaturated Polyester Blend Coated Bamboo Fibers

A. Varada Rajulu、L. Ganga Devi、G. Babu Rao 等 4 位作者2003-08-01Journal of Reinforced Plastics and Composites

The untreated and 2%aqueous NaOH treated bamboo fibers (Dendrocalamus strictus) were coated with epoxy, unsaturated polyester (UP) and their blends. The chemical resistance of these fibers to acetic acid, nitric acid, hydrochloric acid, sodium hydroxide, ammonium hydroxide, sodium carbonate, benzene, toluene, carbon t…

Natural Fiber Reinforced CompositesTextile materials and evaluationsBamboo properties and applications

Structure-mesomorphism relationship in terminally functionalised liquid crystal dendrimers

Mercedes Marcos、Ana Omenat、José Luís Serrano2003-08-01Comptes Rendus Chimie

We have carried out a study on the supramolecular liquid crystal organisation shown by LC dendrimers. This study has allowed us to draw interesting conclusions about the molecular plasticity of this type of dendromesogens and even to predict the mesogenic behaviour of higher generations of homologous dendrimers or sim…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Ohmic Contact Formation for N-Type Diamond by Selective Doping

Tokuyuki Teraji、Masayuki Katagiri、Satoshi Koizumi 等 5 位作者2003-08-01Japanese Journal of Applied Physics

Ohmic contacts with low contact resistivity were formed on phosphorus-doped n -type {111} diamond thin films grown by microwave-plasma chemical-vapor deposition. Heavily-doped diamond layers were selectively grown on a diamond substrate by covering a part of substrate surface with a titanium/gold layer. Gold contacts…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Elevation of Plasma Membrane Permeability on Laser Irradiation of Extracellular Latex Particles

Y. Umebayashi2003-08-01The Journal of Biochemistry

In this report, we describe a laser-latex combination system that enables membrane-impermeable molecules to penetrate cell membranes. Laser light (Q-switched Nd:YAG laser, 532.5 nm) was used to irradiate a mixture of commercial latex particles (blue dyed, 1 micro m in diameter) and mouse fibrosarcoma (Meth-A) cells. A…

Photochromic and Fluorescence ChemistryElectrohydrodynamics and Fluid DynamicsSlime Mold and Myxomycetes Research

ONIOM Studies of Chemical Reactions on Carbon Nanotube Tips: Effects of the Lower Theoretical Level and Mutual Orientation of the Reactants

Vladimir A. Basiuk2003-08-01The Journal of Physical Chemistry B

We studied theoretically the interaction of simple aliphatic amines with carboxylated zigzag and armchair single-walled carbon nanotube (SWNT) models. We used single-level MM+ molecular mechanics and the AM1 semiempirical method to study noncovalent interactions. To study the model amidation reaction with methylamine,…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsQuantum, superfluid, helium dynamics

Formation Conditions, Water‐vapor Permeability, and Solubility of Compression‐molded Whey Protein Films

Rungsinee Sothornvit、Carl W. Olsen、Tara H. McHugh 等 4 位作者2003-08-01Journal of Food Science

ABSTRACT: Films based on whey protein isolate (WPI) were formed using compression molding. Compression molded films could be formed using 30% to 50% moisture content or glycerol content WPI at 104 °C to 160 °C for 2 min. Films made from water‐WPI mixtures were brittle and insoluble and had water‐vapor permeability val…

Advanced Sensor and Energy Harvesting MaterialsNanocomposite Films for Food Packagingbiodegradable polymer synthesis and properties

Sequential Assembly of Homogeneous Magnetic Prussian Blue Films on Templated Surfaces

Jeffrey T. Culp、Ju‐Hyun Park、Isa O. Benítez 等 6 位作者2003-08-01Chemistry of Materials

Thin homogeneous films of the Prussian blue analogues with idealized formulas KFe III [Fe II (CN) 6 ], KNi II [Fe III (CN) 6 ], CsNi II [Cr III (CN) 6 ], and KCr II [Cr III (CN) 6 ] have been prepared through the sequential adsorption of the appropriate metal ions and hexacyanometalate complexes onto hydrophobic surfa…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Nanocrystals: fabrication, organization and collective properties

Marie‐Paule Pileni2003-08-01Comptes Rendus Chimie

In this review, the control of size and shape of inorganic nanocrystals via colloidal solution is discussed. The nanocrystals are organized in 2D and 3D superlattices with formation of ‘supra’ crystals in fcc structure. Physical properties of nanocrystals organized in mesoscopic scale are neither those of the isolated…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Fully Dense, Fine‐Grained, Doped Zinc Oxide Varistors with Improved Nonlinear Properties by Thermal Processing Optimization

P. Durän、J. Tartaj、C. Moure2003-08-01Journal of the American Ceramic Society

Fully dense, doped ZnO varistors were prepared using an easy two‐stage pressureless‐sintering method at temperatures as low as 825°C, with a grain size of ∼0.5 μm. After the highly nonohmic ZnO varistors were sintered, their fine microstructure consisted of uniformly sized grains, small spinel grains with partially di…

ZnO doping and propertiesThin-Film Transistor TechnologiesGa2O3 and related materials

Synthesis of Nanocrystalline α‐Al 2 O 3 Powders from Nanometric Ammonium Aluminum Carbonate Hydroxide

Xudong Sun、Ji‐Guang Li、Fang Zhang 等 7 位作者2003-08-01Journal of the American Ceramic Society

Nanometric ammonium aluminum carbonate hydroxide (AACH) with a particle size less than 5 nm was produced from ammonium aluminum sulfate and ammonium hydrocarbonate under an optimized adding condition, and phase transformations of the AACH on heating and the effect of α‐Al 2 O 3 seeding on the transformation kinetics w…

Advanced ceramic materials synthesisLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications