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A fluorescent light-up probe with “AIE + ESIPT” characteristics for specific detection of lysosomal esterase

Meng Gao、Qinglian Hu、Guangxue Feng 等 5 位作者2014-01-01Journal of Materials Chemistry B

We report a fluorescent light-up probe AIE-Lyso-1 for in situ visualization of lysosomal esterase activity. The probe is based on a salicyladazine fluorogen, which is conjugated with esterase reactive acetoxyl groups and lysosome-targeting morpholine moieties. The probe has characteristics of both aggregation-induced…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Electrochemical synthesis of photoluminescent carbon nanodots from glycine for highly sensitive detection of hemoglobin

Chen-I Wang、Wei‐Cheng Wu、Arun Prakash Periasamy 等 4 位作者2014-01-01Green Chemistry

An electrochemical approach has been employed for the preparation of photoluminescent carbon nanodots (C-dots) from glycine under alkaline conditions. The formation of C-dots is through electro-oxidation, electro-polymerization, carbonization, and passivation. The as-prepared C-dots possess excitation-wavelength-depen…

Heavy Metal Exposure and ToxicityCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Preparation of graphene oxide/epoxy nanocomposites with significantly improved mechanical properties

Dilini Galpaya、Mingchao Wang、Graeme A. George 等 6 位作者2014-01-01QUT ePrints (Queensland University of Technology)

The effect of graphene oxide (GO) on the mechanical properties and the curing reaction of Diglycidyl Ether of Bisphenol A/F and Triethylenetetramine epoxy system was investigated. GO was prepared by oxidation of graphite flakes and characterized by spectroscopic and microscopic techniques. Epoxy nanocomposites were fa…

Graphene research and applicationsEpoxy Resin Curing ProcessesFiber-reinforced polymer composites

Polypyrrole derivatives for electrochromic applications

Pınar Çamurlu2014-01-01RSC Advances

This review provides a comprehensive assessment of recent progress in polypyrrole derivatives which are specially designed for electrochromic applications.

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

High throughput electron transfer from carbon dots to chloroplast: a rationale of enhanced photosynthesis

Sourov Chandra、Saheli Pradhan、Shouvik Mitra 等 7 位作者2014-01-01Nanoscale

A biocompatible amine functionalized fluorescent carbon dots were developed and isolated for gram scale applications. Such carbogenic quantum dots can strongly conjugate over the surface of the chloroplast and due to that strong interaction the former can easily transfer electrons towards the latter by assistance of a…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Aggregation induced blue-shifted emission – the molecular picture from a QM/MM study

Qun‐Yan Wu、Tian Zhang、Qian Peng 等 5 位作者2014-01-01Physical Chemistry Chemical Physics

In general, optical emission in the solid-state is red-shifted with respect to the solution phase. A series of recently synthesized compounds exhibits aggregation induced blue-shifted emission (AIBSE) phenomena. By employing a polarizable continuum model (PCM) and a hybrid quantum mechanics/molecular mechanics (QM/MM)…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Sound and Vibration Damping Properties of Flax Fiber Reinforced Composites

S. Prabhakaran、V. Krishnaraj、M Kumar 等 4 位作者2014-01-01Procedia Engineering

In recent days, automobile and construction industries are focus on the light weight, environmental friendly materials with good mechanical properties. Glass fiber reinforced composites have excellent specific properties and are widely used because of reduced mass. However the manufacturing of glass fibers and end of…

Natural Fiber Reinforced CompositesTribology and Wear AnalysisMechanical Engineering and Vibrations Research

Ligands effects on the magnetic anisotropy of tetrahedral cobalt complexes

Mohamed R. Saber、Kim R. Dunbar2014-01-01Chemical Communications

The effect of ligands with heavy donor atoms on the magnetic anisotropy of the pseudo-tetrahedral cobalt complexes, Co(quinoline)2I2 (1) and Co(EPh3)2I2 (2-3) (E = P, As) has been investigated. The axial zero-field splitting parameter D was found to vary from +9.2 cm(-1) in 1 to -36.9 cm(-1) in 2 and -74.7 cm(-1) in 3…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Photolithographic fabrication of high-performance all-solid-state graphene-based planar micro-supercapacitors with different interdigital fingers

Zhong‐Shuai Wu、Khaled Parvez、Xinliang Feng 等 4 位作者2014-01-01Journal of Materials Chemistry A

Here we demonstrated the fabrication of ultrahigh rate, all-solid-state, planar interdigital graphene-based micro-supercapacitors (MSCs) manufactured by methane plasma-assisted reduction and photolithographic micro-fabrication of graphene oxide films on silicon wafers. Notably, the electrochemical performance of MSCs…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Self-assembly of colloidal one-dimensional nanocrystals

Shuang‐Yuan Zhang、Michelle D. Regulacio、Ming‐Yong Han2014-01-01Chemical Society Reviews

The ability of nanoscopic materials to self-organize into large-scale assembly structures that exhibit unique collective properties has opened up new and exciting opportunities in the field of nanotechnology. Although earlier work on nanoscale self-assembly has focused on colloidal spherical nanocrystals as building b…

Quantum Dots Synthesis And PropertiesPhotonic Crystals and ApplicationsPickering emulsions and particle stabilization

Optical absorption and scattering spectroscopies of single nano-objects

Aurélien Crut、Paolo Maioli、Natalia Del Fatti 等 4 位作者2014-01-01Chemical Society Reviews

Developments of optical detection and spectroscopy methods for single nano-objects are key advances for applications and fundamental understanding of the novel properties exhibited by nanosize systems. These methods are reviewed, focusing on far-field optical approaches based on light absorption and elastic scattering…

Carbon Nanotubes in CompositesGold and Silver Nanoparticles Synthesis and ApplicationsNear-Field Optical Microscopy

A type-II semiconductor (ZnO/CuS heterostructure) for visible light photocatalysis

Mrinmoyee Basu、Neha Garg、Ashok K. Ganguli2014-01-01Journal of Materials Chemistry A

Formation of ZnO/CuS heterostructure through a simple wet-chemical method leads to a type-II semiconductor. The heterojunction between these two moieties leads to the separation of electron–hole pairs, which further enhances the photocatalytic efficiency of ZnO.

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

A triphenylamine-based benzoxazole derivative as a high-contrast piezofluorochromic material induced by protonation

Pengchong Xue、Peng Chen、Junhui Jia 等 8 位作者2014-01-01Chemical Communications

A triphenylamine-based benzoxazole derivative ( BVDP ) as a typical D–π–A molecule could be used as a low contrast piezofluorochromic material with a spectral red-shift of 29 nm. However, when BVDP bound a proton to form BVDP+H , a high contrast piezofluorochromism (Δ λ = 75 nm) could be observed.

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

Xiang Zhu、Shannon M. Mahurin、Shuhao An 等 13 位作者2014-01-01Chemical Communications

A porous triazine and carbazole bifunctionalized task-specific polymer has been synthesized via a facile Friedel-Crafts reaction. The resultant porous framework exhibits excellent CO2 uptake (18.0 wt%, 273 K and 1 bar) and good adsorption selectivity for CO2 over N2.

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture TechnologiesCovalent Organic Framework Applications

Active Packaging in Food Industry: A Review

Priyanka Prasad、Anita Kochhar2014-01-01IOSR Journal of Environmental Science Toxicology and Food Technology

In response to the dynamic changes in current consumer demand and market trends, the area of Active Packaging is becoming increasingly significant. Unlike traditional packaging, which must be totally inert, active packaging is designed to interact with the contents and/or the surrounding environment. Active packaging…

Meat and Animal Product QualityNanocomposite Films for Food PackagingAdvanced Chemical Sensor Technologies

Two-dimensional heterostructures of V 2 O 5 and reduced graphene oxide as electrodes for high energy density asymmetric supercapacitors

D. H. Nagaraju、Qingxiao Wang、Pierre M. Beaujuge 等 4 位作者2014-01-01Journal of Materials Chemistry A

The 2D layered heterostructures of V 2 O 5 nanosheets and reduced graphene oxide show high conductivity and superior asymmetric supercapacitor properties.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Role of oxygen vacancy and Fe–O–Fe bond angle in compositional, magnetic, and dielectric relaxation on Eu-substituted BiFeO 3 nanoparticles

A. Tamilselvan、S. Balakumar、M. Sakar 等 6 位作者2014-01-01Dalton Transactions

The influence of oxygen vacancies on the dielectric relaxation behavior of pure and Eu-substituted BiFeO3 nanoparticles synthesized by a sol-gel technique has been studied using impedance spectroscopy in the temperature range of 90 °C to 180 °C. The electric relaxation time and activation energy of the oxygen vacancie…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics