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Avaliação da estimativa de substituição de Fe por Al em hematitas de solos

Nestor Kämpf、U. Schwertmann1998-06-01Revista Brasileira de Ciência do Solo

Hematitas de nove solos e uma de itabirito foram tratadas com NaOH 5 mol L-1 e analisadas por difratometria de raios X (DRX), usando varredura escalonada (0,02°2θ/20 s). Determinaram-se o espaçamento d e as dimensões a0 e c0 da cela unitária. As amostras foram dissolvidas com ditionito-citrato-bicarbonato de sódio (DC…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMine drainage and remediation techniques

/spl gamma/-radiation-induced absorption in pure-silica-core fibers in the visible spectral region: the effect of H/sub 2/-loading

А.Л. Томашук、E. M. Dianov、К.М. Голант 等 4 位作者1998-06-01IEEE Transactions on Nuclear Science

/spl gamma/-radiation-induced absorption in the visible spectral region is studied in H/sub 2/-loaded and untreated optical fibers with high-OH low-Cl KU core and low-OH low-Cl KS-4V core. H/sub 2/-loading is found to suppress the low-dosage transient absorption band centered at 670 nm in KS-4V fibers. After irradiati…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsThin-Film Transistor Technologies

Correlation Between Acoustic Emission Signals and Hydrogen Permeation in High Strength, Low Alloy Steel Cracking in Wet H 2 S

Shu‐Yi Tsai、H.C. Shih1998-06-01Journal of The Electrochemical Society

Plates of high strength, low alloy (HSLA) steel (JIS‐G‐3115 SPV‐50Q) were found to be susceptible to sulfide stress cracking and hydrogen‐induced cracking (HIC) in wet H 2 S . The diffusion coefficient for the hydrogen atom in the SPV‐50Q steel was determined at 25–60°C and the activation energy for diffusion was 24.7…

Hydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing TechniquesMaterial Properties and Failure Mechanisms

Potassium fixation of different soil types and nutrient levels

Katalin Sárdi、Gábor Csitári1998-06-01Communications in Soil Science and Plant Analysis

Potassium (K) fixation plays a significant role in the soil‐plant system influencing the effectiveness of fertilizaiton. Among the factors controlling fixation capacity of soils, clay mineralogy and soil moisture are of primary importance. The objective of this experiment was to study the K fixation capacity of differ…

Soil and Unsaturated FlowClay minerals and soil interactionsSoil Management and Crop Yield

Manufacturing of all‐thermoplastic sandwich systems by a one‐step forming technique

Ulf Breuer、Martin Ostgathe、M. Neitzel1998-06-01Polymer Composites

Abstract Thermoplastic sandwich composite systems offer great potential for future automotive applications. High specific bending stiffness, good insulation properties, high specific energy absorption and impact resistance can be achieved by the use of fabric reinforced sheets as sandwich faces and thermoplastic foam…

Cellular and Composite StructuresAdditive Manufacturing and 3D Printing TechnologiesPolymer Foaming and Composites

Statistical description of model systems of interacting particles and phase transitions accompanied by cluster formation

B. I. Lev、A. Ya. Zhugaevych1998-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We develop an approach to the statistical description of a system of interacting particles in order to describe spatially inhomogeneous structures. A criterion is proposed for selecting system states whose contributions in the partition function are dominant. A nonperturbative calculation of the partition function is…

Material Dynamics and PropertiesTheoretical and Computational Physicsnanoparticles nucleation surface interactions

Magnetic properties, resistivity, and heat capacity of EuMnO3 and Eu0.7A0.3MnO3 (A=Ca, Sr) compounds

Y. M. Mukovskii、G. Hilscher、H. Michor 等 4 位作者1998-06-01Journal of Applied Physics

We present magnetic-, resistivity-, and specific-heat measurements of the title compounds and found that in Eu0.7Sr0.3MnO3 an insulator-metal transition can be induced by an external field below 60 K while Eu0.7Ca0.3MnO3 remains insulating. EuMnO3 exhibits two magnetic transitions at 35 and 47 K which are associated w…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Molecular Dynamics Simulation of V 2 O 5 / Li2SiO3 Interface

Martı́n E. Garcia、Edmund B. Webb、Stephen H. Garofalini1998-06-01Journal of The Electrochemical Society

The molecular dynamics computer simulation technique was used to evaluate the early stages of Li ion migration occurring at the electrolyte/cathode interface applicable to solid‐state oxide thin film batteries. A crystal was oriented such that its (001) planes were parallel to the lithium metasilicate glass surface, a…

Gas Sensing Nanomaterials and SensorsSemiconductor materials and devicesTransition Metal Oxide Nanomaterials

Electrochemical polymerization of poly(o-anisidine) thin films: effect of synthesis temperature studied by cyclic voltammetry

Sharmila Patil、J.R. Mahajan、Mahendra A. More 等 6 位作者1998-06-01Polymer International

The effect of temperature on the electrochemical synthesis of poly(o-anisidine) (POA) thin films has been investigated. The POA films were synthesized electrochemically under cyclic voltammetric conditions in aqueous solutions of H2SO4 at various temperatures between -6°C and 40°C. These films were characterized by cy…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Design of ceramic laminates for structural applications

W.J. Clegg1998-06-01Materials Science and Technology

It has been shown previously that laminated ceramic structures of layers (or fibres) separated by crack deflecting structures give a simple, easy, and general method of enhancing the properties of ceramics, as determined in both the laboratory and under service conditions, particularly in environments of extreme therm…

Advanced ceramic materials synthesisRecycling and utilization of industrial and municipal waste in materials productionAdvanced materials and composites

Neutron irradiation effects in fusion or spallation structural materials: Some recent insights related to neutron spectra

F.А. Garner、L.R. Greenwood1998-06-01Radiation effects and defects in solids

A review is presented of recent insights on the role of transmutation in the development of radiation-induced changes in dimension or radiation-induced changes in physical or mechanical properties. It is shown that, in some materials and some neutron spectra, transmutation can significantly affect or even dominate a g…

High-pressure geophysics and materialsFusion materials and technologiesNuclear Materials and Properties

Semiquantitative analysis of magnetic phase transitions in the MnFeP1−xAsx series of compounds

R. Zach、M. Guillot、J. Toboła1998-06-01Journal of Applied Physics

On the basis of the relation T(σ,H) derived within the framework of the Bean–Rodbell model a semiquantitative analysis of (B,T) magnetic phase diagrams in the hexagonal region of the MnFeP1−xAsx (0.15⩽x⩽0.66) series of compounds was carried out. It was found that the first order transition line in the (B,T) plane is t…

Physics of Superconductivity and MagnetismMagnetic Properties and ApplicationsIron-based superconductors research

Morphological and genetic relations between siderite, calcite and goethite in a Low Moor Peat from southern Germany

McMillan、SCHWERTMANN1998-06-01European Journal of Soil Science

Siderite, calcite and goethite occur in a Low Moor Peat near Freising, southern Germany. Siderite is present mainly as microcrystalline ovoids which have a lamellar structure and are less than 5 μm long. Selected area electron diffraction and X‐ray diffraction data suggest a crystal size less than that of the ovoids,…

Geology and Paleoclimatology ResearchClay minerals and soil interactionsIron oxide chemistry and applications

Spectroscopy and Photophysics of Tetraalkyldibenzoporphycenes

Jacek Dobkowski、Victor A. Galievsky、Alexander Starukhin 等 5 位作者1998-06-01The Journal of Physical Chemistry A

Two recently synthesized derivatives of porphycene, 2,7,12,17-tetramethyl-3,6-13,16-dibenzo[ cde, mno ]porphycene and 2,7,12,17-tetra- tert -butyl-3,6-13,16-dibenzo[ cde, mno ]porphycene, were studied by stationary and time-resolved spectroscopy and quantum chemical calculations. Both compounds were found to be nonlum…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

High temperature stability of SmTM magnets

A. S. Kim1998-06-01Journal of Applied Physics

To meet the demand for permanent magnet materials usable up to 450–500 °C, we investigated and reported that a SmTM magnet with a low temperature coefficient of coercivity and a moderately high coercivity has substantially lower irreversible losses at elevated temperatures than conventional Sm2TM17 magnets. We have co…

Magnetic and transport properties of perovskites and related materialsMagnetic Properties of AlloysSuperconducting Materials and Applications

Synthesis and characteristics of polydepsipeptide with pendant thiol groups

Tatsuro Ouchi、Hidenori Seike、Tatsuya Nozaki 等 4 位作者1998-06-01Journal of Polymer Science Part A Polymer Chemistry

To obtain water-soluble oligodepsipeptide with pendant thiol groups, the alternating co-oligomer [oligo(Glc-alt-Cys)], consisting of glycolic acid (Glc) and L-cysteine (Cys) residues as α-hydroxy acid and α-amino acid residues, respectively, was prepared by means of ring-opening homo-oligomerization of cyclo[Glc-Cys(M…

biodegradable polymer synthesis and propertiesSilicone and Siloxane ChemistryBiopolymer Synthesis and Applications

Synthesis and characterization of new diphenylfluorene-based aromatic polyazomethines

Ki Hong Park、Takashi Tani、Masa‐aki Kakimoto 等 4 位作者1998-06-01Macromolecular Chemistry and Physics

New diphenylfluorene-based aromatic polyazomethines were synthesized via polycondensation of aromatic diamines with aromatic dialdehydes. The highest inherent viscosity of polyazomethines was obtained for solution polycondensation in m-cresol at room temperature under reduced pressure. The aromatic polyazomethines hav…

Organic Electronics and PhotovoltaicsMembrane Separation and Gas TransportSynthesis and properties of polymers

Electrical properties of Ga and ZnS doped ZnO prepared by mechanical alloying

B. A. Cook、J. L. Harringa、Cronin B. Vining1998-06-01Journal of Applied Physics

A series of n-type ZnO alloys doped with Ga and ZnS were prepared by mechanical alloying. Densities of 95% to 98% of theoretical density were achieved by hot pressing the milled powders at 1000 and 1200 °C, respectively. The electrical resistivity and Seebeck coefficient of alloys containing 0.25–3.0 at. % Ga were cha…

ZnO doping and propertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO 4 modification

Volker Kahlenberg、H. Böhn1998-06-01American Mineralogist

Boralsilite, the first natural anhydrous Al-B-silicate, is a high-temperature phase in peg­matites cutting granulite-facies metapelitic rocks at Larsemami Hills, Prydz Bay, east Ant­arctica (type locality) and Almgjotheii in the contact aureole of the Rogaland Intrusive Complex, southwestern Norway. Stable assemblages…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Micromagnetic simulation of magnetizability of nanocomposite Nd–Fe–B magnets

T. Schrefl、J. Fidler1998-06-01Journal of Applied Physics

Micromagnetic finite element calculations clearly show that the magnetizability of nanocomposite Nd2Fe14B magnets improves with increasing α-Fe content. The magnetization curves show a steep increase at the domain propagation field in dc demagnetized samples. Thermally demagnetized states store a higher amount of exch…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys