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Effect of Geometry and Flow Conditions on Particulate Fouling in Plate Heat Exchangers

Bernard Thonon1999-08-01Heat Transfer Engineering

This article describes particulate fouling experiments performed on small-scale and full-scale plate heat exchangers for three different corrugation angles (30 deg, 45 deg and 60 deg). The velocity effect has been studied as well as the particle type and concentration effects. The test duration ranges between 20 and 1…

Heat Transfer and OptimizationCalcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic Effects

Effect of Chiral Dopants Molecular Structure on Temperature Dependencies of Induced Cholesteric Helical Pitch

L. A. Kutulya、Valerii V. Vashchenko、G. P. Semenkova 等 4 位作者1999-08-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

Effect of the chiral dopants molecular structure on the kind of the temperature dependencies of the induced cholesteric helical pitch has been studied for LC systems on the base of 4-pentyl-4′-cyanobiphenyl or 4-methoxybenzylidene-4-butylaniline including chiral S,α-phe-nylethylamine and E-1R,4R-2-(4-phenylbenzylidene…

Crystallization and Solubility Studies

Electron microscopic stereological study of collagen fibrils in bovine articular cartilage: volume and surface densities are best obtained indirectly (from length densities and diameters) using isotropic uniform random sampling

Teemu K. Långsjö、Mika M. Hyttinen、Alpo Pelttari 等 6 位作者1999-08-01Journal of Anatomy

Results obtained by the indirect zonal isotropic uniform random (IUR) estimation were compared with those obtained by the direct point and interception counting methods on vertical (VS) or IUR sections in a stereological study of bovine articular cartilage collagen fibrils at the ultrastructural level. Besides compari…

Osteoarthritis Treatment and MechanismsPoint processes and geometric inequalitiesCollagen: Extraction and Characterization

Physical aging of an amorphous polyimide: Enthalpy relaxation and mechanical property changes

Christopher G. Robertson、Jeremy Monat、Garth L. Wilkes1999-08-01Journal of Polymer Science Part B Polymer Physics

The physical aging behavior of an isotropic amorphous polyimide possessing a glass transition temperature of approximately 239°C was investigated for aging temperatures ranging from 174 to 224°C. Enthalpy recovery was evaluated as a function of aging time following sub-Tg annealing in order to assess enthalpy relaxati…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Alkylation and Reduction of Porphyrins andN-Substituted Porphyrins: New Routes to Chlorins and Phlorins

Bénédicte Krattinger、H. J. CALLOT1999-08-01European Journal of Organic Chemistry

On reaction with organolithium compounds, N-substituted metalloporphyrins gave mixtures of mono-β-alkylated chlorins and hydroxychlorins, whereas free-base porphyrins give meso- + β- mono- and dialkylated products. Reduction of N-substituted porphyrins with tosylhydrazine or sodium tetrahydroborate opened new routes t…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

Preliminary Tube Manufacturing of Oxide Dispersion Strengthened Ferritic Steels with Recrystallized Structure

Shigeharu Ukai、Tsunemitsu Yoshitake、Syunji MIZUTA 等 6 位作者1999-08-01Journal of Nuclear Science and Technology

In a prospective cladding material for the long-life core of the Liquid Metal Fast Reactor, our efforts are taken into the oxide dispersion strengthened (ODS) ferritic steels, which have more swelling resistance than austenitic steels and are expected to have superior creep strength at elevated temperature of 973 K.It…

Fusion materials and technologies

On the range of validity of the continuum approach for nonlinear diffusional mixing of multilayers

Zoltán Erdélyi、Dezső L. Beke、Péter Nemes 等 4 位作者1999-08-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Using finite difference calculations in continuum equations and using deterministic kinetic equations for calculations in a discrete lattice, the problem of the asymmetry, related to the strong concentration dependence of the diffusion coefficient in the diffusional mixing of binary multilayers, was investigated assum…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepSolidification and crystal growth phenomena

Green photoluminescence band in γ-irradiated oxygen-surplus silica glass

Yuryo Sakurai、Kaya Nagasawa1999-08-01Journal of Applied Physics

Previous studies have reported the existence of a green photoluminescence (PL) band in oxygen-deficient silica glass when exposed to ultraviolet (UV) light. Oxygen deficient defects (Eδ′) were thought to be the origin of this PL band. In this article, we describe the characteristics of a green PL band in oxygen-surplu…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Effect of Doping and Irradiation on Optical Parameters of Triglycine Sulphate Single Crystals

M.A. Gaffar、A. Abu El‐Fadl1999-08-01Crystal Research and Technology

Crystals of triglycine sulphate (TGS) doped with orthonitroaniline (ONA) irradiated with different doses of gamma-radiation were used to investigate gamma-radiation effect on electrical and optical parameters. The absorption coefficient and the reflectance were measured and hence the extinction coefficient, the optica…

Conducting polymers and applicationsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Varistor Behavior at Twin Boundaries in ZnO

B. A. Haskell、S.J. Souri、Martin A. Helfand1999-08-01Journal of the American Ceramic Society

The electrical behavior of commercial ZnO varistor devices has been examined with voltage contrast microscopy and point contact dc electrical measurements. Nonlinear voltage‐dependent behavior has been observed across both of the major crystalline boundary types present in the system: Bi 2 O 3 layer containing ZnO gra…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Condensation of Pyramidal [AsSe3]3- Anions for the Construction of Polymeric Networks: Solventothermal Synthesis of K3AgAs2Se5·0.25MeOH, K2AgAs3Se6, and Rb2AgAs3Se6

Michael Wachhold、Mercouri G. Kanatzidis1999-08-01Inorganic Chemistry

Three novel quaternary selenoarsenates could be synthesized by the solventothermal reaction of [AsSe 3 ] 3 - anions with AgBF 4 in the presence of the respective alkali metal cation. Orange crystals of K 3 AgAs 2 Se 5 ·0.25MeOH ( I ) are formed after reaction in MeOH at 130 °C for ∼2 h. Its structure is built up of ψ-…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Dibenzoannulated 3,5,3″,5″-Tetra(t-butyl)-p-terphenoquinone. A Reversible, Photochemical-Thermal Switching System Involving Restricted Conformational Change

Hiroyuki Kurata、Tomomi Tanaka、Masaji Oda1999-08-01Chemistry Letters

Abstract The title compound, a new terphenoquinone derivative, shows a dynamic redox behavior upon cyclic voltammetry and a reversible, photochemical-thermal isomerization between the quinone and diradical forms, both phenomena involving restricted conformational change.

Photochromic and Fluorescence ChemistryBioactive Compounds and Antitumor AgentsSynthesis of Organic Compounds

Silylated carbodiimides in molecular and extended structures

Peter Kroll、Ralf Riedel、Roald Hoffmann1999-08-01Physical review. B, Condensed matter

This work studies the ternary Si-C-N phases ${\mathrm{SiC}}_{2}{\mathrm{N}}_{4}$ and ${\mathrm{Si}}_{2}{\mathrm{CN}}_{4},$exploiting an analogy between the NCN and O groups. Starting from the molecular model of ${N,N}^{\ensuremath{'}}\ensuremath{-}\mathrm{bis}(\mathrm{trimethylsilyl})\ensuremath{-}\mathrm{carbodiimide…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Preparation of poly(ethylene glycol) grafted poly(3-hydroxyalkanoate) networks

Bakı Hazer、Robert W. Lenz、Birten Çakmaklı 等 5 位作者1999-08-01Macromolecular Chemistry and Physics

Poly(3-hydroxyalkanoate)-g-poly(ethylene glycol) crosslinked graft copolymers are described. Poly(3-hydroxyalkanoate)s containing double bonds in the side chain (PHA-DB) were obtained by co-feeding Pseudomonas oleovorans with a mixture of nonanoic acid and anchovy (hamci) oily acid (in weight ratios of 50/50 and 70/30…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersBiopolymer Synthesis and Applications

Steamrollers, Sports Cars and Security: Phthalocyanine Progress Through the Ages

Peter Gregory1999-08-01Journal of Porphyrins and Phthalocyanines

Serendipity has been a major player in most dye discoveries, and phthalocyanines are no exception. The true account of their discovery in 1928 is given using information provided by one of the individuals involved (Ron Greig). One of the inventors, Drescher, after making a key observation as to the nature of the insol…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Conformational States of the Nuclear GTP-Binding Protein Ran and Its Complexes with the Exchange Factor RCC1 and the Effector Protein RanBP1

Matthias Geyer、Ralf Aßheuer、Christian Klebe 等 7 位作者1999-08-01Biochemistry

It has been shown before by (31)P NMR that Ras bound to the nonhydrolyzable GTP analogue guanosine 5'-O-(beta, gamma-imidotriphosphate) (GppNHp) exists in two conformations which are rapidly interconverting with a rate constant of 3200 s-1 at 30 degrees C [Geyer, M., et al. (1996) Biochemistry 35, 10308-10320]. Here w…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Mechanisms for adsorption of organic bases on hydrated smectite surfaces

David A. Laird、Pierce D. Fleming1999-08-01Environmental Toxicology and Chemistry

Abstract Mechanisms by which organic bases are adsorbed on hydrated smectite surfaces were investigated. Three Ca-saturated reference smectites (Otay, SPV, and Panther Creek) were dispersed in distilled water containing 5 μmol of pyridine or 3-butylpyridine. The pH was adjusted to between 7.5 and 3 using 0.01 M HCl. A…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Charge dynamics in the half-metallic ferromagnetCrO2

E. J. Singley、C. Weber、D. N. Basov 等 5 位作者1999-08-01Physical review. B, Condensed matter

Infrared spectroscopy is used to investigate the electronic structure and charge carrier relaxation in crystalline films of ${\mathrm{CrO}}_{2}$ which is the simplest of all half-metallic ferromagnets. Chromium dioxide is a bad metal at room temperature but it has a remarkably low residual resistivity $(<5 \ensurem…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsHeusler alloys: electronic and magnetic properties

Hyperbranched aramids by direct polyamidation of two reactant systems: Synthesis and properties

Saverio Russo、Alya Boulares、Andrea Da Rin 等 5 位作者1999-08-01Macromolecular Symposia

Abstract Some A 2 + B 3 and A 3 + B 3 reagent pairs have been used for the direct polyamidation reaction leading, besides the network formation, to hyperbranched aramid structures. Depending on the chosen experimental conditions, variable amounts of a sol fraction having close similarities with the hyperbranched arami…

Chemical Synthesis and AnalysisDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Characterization of Recombinant Human Type IX Collagen

Tero Pihlajamaa、Merja Perälä、Mirka M. Vuoristo 等 10 位作者1999-08-01Journal of Biological Chemistry

As type IX collagen is a minor cartilage component, it is difficult to purify sufficient amounts of it from tissues or cultured cells to study its structure and function. Also, the conventional pepsin digestion used for fibrillar collagens cannot be utilized for purifying type IX collagen, because it contains several…

Cell Adhesion Molecules ResearchConnective tissue disorders researchCollagen: Extraction and Characterization