Materials Literature
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Single bubble sonoluminescence in an air-water system has been shown to occur along a unique surface in the acoustic pressure-ambient radius-gas concentration parameter space where the bubble is stable both in shape and in (average) size. In this paper, we show how the bubble deviates from the expected path (traced by…
The epitaxial growth of CeO2 films on SrTiO3(001) has been investigated over a wide range of growth parameters using oxygen-plasma-assisted molecular beam epitaxy. The lattice mismatch for CeO2 on SrTiO3(001) is 2.0% (compressive) if the film nucleates with a 45° rotation about [001] relative to the substrate (i.e., C…
A comparison between the Newton-Raphson method and the fixed-point technique in hysteretic magnetic field problems is presented. Four different approaches are studied and contrast between them in terms of the convergence rate and computation time consumption is highlighted. The Newton-Raphson-based approaches are foun…
A series of acceptor-substituted nickel(diimine)(dithiolate) complexes were synthesized and characterized. Both ground-state and excited-state dipole moments were determined. These complexes have ground-state dipole moments (μ g s) in the wide range from 4 to 17 D, in contrast to the near constant μ g s reported earli…
Lamellar diblock copolymers are investigated under large amplitude oscillatory shear (LAOS) at temperatures close to the order–disorder transition temperature (TODT). Increasing strain amplitude leads to a double flip of orientation. The state of orientation depends on an effective shear rate as in similar experiments…
Effects of the naturally occurring compounds azadirachta indica (leaves), punica granatum (shell), and momordica charantia (fruits), on corrosion of mild steel in 3% sodium chloride (NaCl) were assessed using weight loss, electrochemical polarization, and impedance techniques. Extracts of the compounds exhibited excel…
A grazing-incidence spectrograph is designed by use of the flat-field image-focusing property of a spherical varied-line-space grating. Optimum grating parameters for mechanical ruling are selected by application of genetic algorithms. Two gratings, one for 2-5-nm and the other for 5-20-nm spectral regions, are design…
New polymer networks were prepared by free radical initiated copolymerization of crystallizable α,ω-bismethacrylate-terminated poly(octadecyl vinyl ether) (polyODVE) with butyl acrylate (BA). The polyODVE bismacromonomers were obtained by end-capping the bifunctionally living cationic polymerization of ODVE with 2-hyd…
This paper reports on the adsorption of different organic pesticides by hydrotalcite, hydrotalcite heated to 500 degrees C and organo-hydrotalcite in aqueous medium by employing adsorption isotherms, and using X-ray diffraction and infrared spectroscopy techniques. The results suggest that the adsorption capacity of t…
A 96-channel phased array probe for echocardiography using a single-plate, 0.91Pb(Zn 1/3 Nb 2/3 )O 3 –0.09PbTiO 3 (PZNT 91/9) single-crystal transducer with dimensions of 14×20 mm has been fabricated to realize greater sensitivity and broader bandwidth properties. The center frequency of the probe, 3.5 MHz, was select…
The doping mechanism of Sn in In 2 O 3 (ITO) powder was investigated using 119 Sn transmission Mössbauer spectroscopy (TMS) and X-ray diffraction (XRD) in view of the chemical state of Sn. Deconvolution analyses of TMS spectra revealed that there was substitutional Sn 4+ coordinated not only by 6 oxygen atoms [Sn In ·…
Divalent molecular lanthanide complexes are shown to offer promise as tunable light emitting materials in thin film electroluminescent displays for the first time in this study. Bright orange luminescence is obtained from thin film EL device structures containing bis[tris(dimethylpyrazolyl)borate]europium(II) (1), whi…
ZnO whiskers were epitaxially grown by a chemical-vapor deposition technique employed at atmospheric pressure. Highly oriented ZnO whiskers grew at a substrate temperature of 550°C on (0001)α-Al 2 O 3 substrates with a growth rate of 3.7 nm/s. X-ray diffractometry revealed that the epitaxial relationship between the w…
Conformational diversity within unique amino acid sequences is observed in diseases like scrapie and Alzheimer's disease. The molecular basis of such diversity is unknown. Similar phenomena occur in subtilisin, a serine protease homologous with eukaryotic pro-hormone convertases. The subtilisin propeptide functions as…
The spectra of internal ac impedance and fluxmetric and energetically effective circular permeabilities are calculated for infinite slab and cylinder in classical and domain models. The domain models assume transverse bar domains for a slab and transverse circular disk domains for a cylinder, with technical magnetizat…
Desktop studies accurately predict trends in corrosion by‐product release. Utility experiences were examined to assess the reliability of solubility models and decision trees in forecasting control of lead (Pb) and copper (Cu) corrosion by‐products. Such approaches cannot quantitatively predict effectiveness of corros…
The dehydroxylation of boehmite has been studied by the application of infrared emission spectroscopy over the 200 to 750 °C temperature range. The dehydroxylation is followed by the loss of intensity of the hydroxyl stretching frequencies observed at 3478, 3319, and 3129 cm −1 and by the loss of intensity of the hydr…
The electronic, structural, and stability properties of the cubic hydride ${\mathrm{Mg}}_{2}{\mathrm{NiH}}_{4}$ are analyzed based on ab initio total-energy calculations. We evaluate the electronic band structures, density of states, charge-density distributions, and bond character for different hydrogen configuration…
The surface-enhanced Raman scattering (SERS) properties of rhodium films electrodeposited onto a SERS-active gold substrate are examined as a function of overlayer thickness, using carbon monoxide and thiocyanate as chemisorbate probes in aqueous solution. Although the adsorbate Raman signals obtained for ultrathin (≤…
Commercially available cellulose (Avicell PH101) was successfully acylated under homogeneous solution conditions by the following procedure: 2.0 g of cellulose were stirred with 75 mL of N,N-dimethylacetamide for 1 h at 150°C, 3.5 g of LiCl were added, the temperature was raised to 170°C, ca. 18.5 mL of the solvent we…