Materials Literature
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A sensor for nitric oxide is reported that uses a novel redox matching mechanism to induce a resistance change upon binding this important ligand to cobalt.
Long-term creep-deformation and shrinkage characteristics of improved ultrathin polymeric films for magnetic tapes are presented. These films include poly(ethylene terephthalate) (PET), poly(ethylene naphthalate) (PEN), and aromatic polyamide (ARAMID). PET film is currently the standard substrate used for magnetic tap…
The reduction of calcium sulfate to produce calcium sulfide is not only a part of the cyclic process for converting sulfur dioxide to elemental sulfur described in part 1 of this series but also of interest as a means of producing elemental sulfur from gypsum. This reaction was investigated using a thermogravimetric a…
Abstract A new method of chemical bonding analysis in crystalline solids is suggested. Wannier functions centered on atoms and related to upper valence and lower conduction bands of a crystal [Wannier‐type atomic orbitals (WTAO)] are proposed to play a part of atom‐like functions in population analysis. A straightforw…
[reaction] A self-complementary V-shaped bis-porphyrin cavity has been synthesized that is capable of dimerization to form a capsule structure. Self-assembly of the dimer occurs via metal ion coordination and produces an internal volume for guest encapsulation.
Star-shaped stilbenoid zinc phthalocyanines with π-conjugated oligo( p -phenylenevinylene)s (OPVs) have been prepared for fine-tuning of absorption and fluorescence bands. The direct introduction of OPV segments at β-positions of Zn phthalocyanines induced shifts in the Q-band and emission band compared to the complex…
We explain the origin of the high-energy mode in the first-order Raman spectra of single-walled carbon nanotubes by double-resonant scattering. Following this interpretation, we calculate the multiple-peak structure as found in Raman experiments. The highest peak is above the graphite $\ensuremath{\Gamma}$-point frequ…
A method is presented for the determination of physical discharge parameters for partial discharges (PDs) of voids in solid insulation. Based on a recently developed stochastic theory of PD processes, a statistical analysis of a measured phase-resolved partial discharge (PRPD) pattern allows the determination of the r…
Abstract X‐ray photoelectron spectroscopy analysis of Cu 2p peaks is able to discriminate between Cu(II) and Cu(I). This is particularly useful when copper is supported in a zeolite matrix, as in heterogeneous catalysts. The preparation route, the Si/Al ratio and the kind of zeolite all contribute to determine the fin…
Maxwell-Wagner piezoelectric, dielectric and elastic relaxations in two-layer or multilayer serial piezoactive media are considered. As distinct from the oversimple model, described in literature, we derive exact solutions by taking into account mechanical boundary conditions, transversal piezoelectric response and el…
[reaction: see text] 5,10,15,20-Tetrakis(m-hydroxyphenyl)porphyrin (m-THPP) yielded novel quinonoid porphyrins upon irradiation in aqueous methanol. True photobleaching was observed for 5,10,15,20-tetrakis(m-hydroxyphenyl)chlorin (m-THPC) and 5,10,15,20-tetrakis(m-hydroxyphenyl)bacteriochlorin (m-THPBC) under the same…
Abstract Core–shell latex with polyacrylate rich in core and fluoropolymer rich in shell was prepared by semicontinuous emulsion polymerization in the presence of mixed emulsifiers. The solids content of the latex was about 25 wt %. The polymerization conditions for the latex were discussed. The morphology of latex pa…
Abstract Metal salts of mono(hydroxypentyl)phthalate [M(HPP) 2 , where M is Ca 2+ , Cd 2+ , Pb 2+ , or Zn 2+ ] were synthesized by the reaction of 1,5‐pentane diol, phthalic anhydride, and metal acetate. A new series of metal‐containing polyurethanes containing ionic links in the main chain were synthesized by the rea…
Three derivatives of the biocompatible polymer poly(styrene-co-maleic anhydride) (SMA) were obtained with 1-amino-1-deoxy-beta-D-galactose, 1-amino-1-deoxy-beta-D-glucose, and 1-amino-1-deoxy-beta-D-lactose, respectively. The amino sugars were chemically conjugated via formation of an amide bond between the anomeric a…
Adsorption of surfactant molecules, cationic as well as anionic, has been carried out on nanocrystals of magnesium oxide, prepared by an aerogel route (AP-MgO). Aerosil OT (AOT) and didodecyl dimethylammonium bromide (DDAB) have been chosen as examples of anionic surfactant and cationic surfactant, respectively. The a…
The structure of the growth lines in the shell of the red abalone, Haliotis rufescens, has been characterized by X-ray diffraction analysis and by scanning and transmission electron microscopy. The growth lines consist of a blocklike microstructure and a spherulitic microstructure, separated by a green organic matrix…
Abstract A novel phosphorus‐containing aralkyl novolac (Ar‐DOPO‐N) was prepared from the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) first with terephthaldicarboxaldehyde and subsequently with phenol. The chemical structures of the synthesized compounds were characterized with Fourier transfo…
Vigorous stirring of a biphasic mixture containing hexadecylaniline in chloroform and aqueous chloroauric acid results in the formation of gold nanoparticles of controllable size in the organic phase.
Many naturally occurring biomaterials are composed of laminated structures in which layers of beta-sheet proteins alternate with layers of inorganic mineral. These ordered laminates often have structural and mechanical properties that differ significantly from those of nonbiological materials. An important step in the…
Human phenylalanine hydroxylase (hPAH) is a tetrameric enzyme that catalyzes the hydroxylation of L-phenylalanine (L-Phe) to L-tyrosine; a dysfunction of this enzyme causes phenylketonuria. Each subunit in hPAH contains an N-terminal regulatory domain (Ser2-Ser110), a catalytic domain (Asp112-Arg410), and an oligomeri…