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A wide-angle antireflection surface for the visible spectrum

Birgit Päivänranta、Toni Saastamoinen、Markku Kuittinen2009-08-26Nanotechnology

A surface consisting of periodically arranged nanopyramids producing wide-angle broad-band antireflection properties is presented. The reflectance of silicon dioxide is reduced below 0.45% over the visible spectral range (380-760 nm) for viewing angles from 0 degrees to 40 degrees . The surface is designed by using ri…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Modular Design of Peptide Fibrillar Nano- to Microstructures

Maxim G. Ryadnov、Angelo Bella、Samuel Timson 等 4 位作者2009-08-26Journal of the American Chemical Society

A general concept for designing self-assembling peptide fibrillar nano- to microstructures is described. The approach relies on the use of straightforward alpha-helical one-heptad (approximately 1 nm) modules without the need for more-specific designs. Various combinations of the modules gave a variety of constructs t…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Elucidating the Structure of the Pm $\bar 3$ n Cubic Phase of Supramolecular Dendrimers through the Modification of their Aliphatic to Aromatic Volume Ratio

Virgil Percec、Mihai Peterca、Yusuke Tsuda 等 8 位作者2009-08-26Chemistry - A European Journal

The synthesis, and structural and retrostructural analysis of a library of second-generation conical dendrons that self-assemble into spherical supramolecular dendrimers is reported. This library consists of amphiphilic dendrons with n-alkyl groups containing from 4 to 16 carbon atoms. The dendrons containing 6 to 16…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

Symmetry breaking in smectics and surface models of their singularities

Bryan Gin–ge Chen、Gareth P. Alexander、Randall D. Kamien2009-08-26Proceedings of the National Academy of Sciences

The homotopy theory of topological defects in ordered media fails to completely characterize systems with broken translational symmetry. We argue that the problem can be understood in terms of the lack of rotational Goldstone modes in such systems and provide an alternate approach that correctly accounts for the inter…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsPhotonic Crystals and Applications

Room temperature synthesis of a novel γ-MnO2hollow structure for aerobic oxidation of benzyl alcohol

Xiaobo Fu、Jiyun Feng、Huan Wang 等 4 位作者2009-08-26Nanotechnology

A novel gamma-MnO(2) hollow structure has been synthesized at room temperature using a simple chemical reaction between MnSO(4) and KMnO(4) in aqueous solution without using any templates, surfactants, catalysts, calcination and hydrothermal processes. The synthesized gamma-MnO(2) hollow structure was characterized by…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Criticality of colloids with distinct interaction patches: The limits of linear chains, hyperbranched polymers, and dimers

J. M. Tavares、P. I. C. Teixeira、M. M. Telo da Gama2009-08-26Physical Review E

We use a simple model of associating fluids which consists of spherical particles having a hard-core repulsion, complemented by three short-ranged attractive sites on the surface (sticky spots). Two of the spots are of type A and one is of type B; the bonding interactions between each pair of spots have strengths epsi…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Ligand Strain and the Nature of Spin Crossover in Binuclear Complexes: Two‐Step Spin Crossover in a 4,4′‐Bipyridine‐Bridged Iron(II) Complex [{Fe(dpia)(NCS)2}2(4,4′‐bpy)] (dpia=di(2‐picolyl)amine; 4,4′‐bpy=4,4′‐bipyridine)

A.Yu. Verat、N. Ould-Moussa、Erwann Jeanneau 等 7 位作者2009-08-26Chemistry - A European Journal

The synthesis and detailed characterization of the new spin crossover (SCO) binuclear complex [{Fe(dpia)(NCS)(2)}(2)(4,4'-bpy)] (1; dpia=di(2-picolyl)amine, 4,4'-bpy = 4,4'-bipyridine) are reported. Variable-temperature magnetic susceptibility measurements show a relatively cooperative two-step spin transition suggest…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Effect of Network Concentration on the Performance of Polymer-Stabilized Cholesteric Liquid Crystals with a Double-Handed Circularly Polarized Light Reflection Band

Jinbao Guo、Huai Yang、Rui Li 等 7 位作者2009-08-26The Journal of Physical Chemistry C

Polymer-stabilized cholesteric liquid crystals (PSCLCs) with a double-handed circularly polarized reflection band are fabricated by a wash-out/refill method. By removing the low molar weight LCs from the original PSCLC film, desirable liquid crystals (LCs) can be infiltrated into a prefabricated polymer network. The r…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Materials and Mechanics

Spin-liquid and magnetic phases in the anisotropic triangular lattice: The case ofκ−(ET)2X

Luca F. Tocchio、Alberto Parola、Claudius Gros 等 4 位作者2009-08-26Physical Review B

The two-dimensional Hubbard model on the anisotropic triangular lattice, with two different hopping amplitudes $t$ and ${t}^{\ensuremath{'}}$, is relevant to describe the low-energy physics of $\ensuremath{\kappa}\text{\ensuremath{-}}{(\text{ET})}_{2}\text{X}$, a family of organic salts. The ground-state properties of…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Crystal Structure of Ammonia Monohydrate Phase II

A. Dominic Fortes、Emmanuelle Suard、M. H. Lemée-Cailleau 等 5 位作者2009-08-26Journal of the American Chemical Society

We have determined the crystal structure of ammonia monohydrate phase II (AMH II) employing a combination of ab initio computational structure prediction and structure solution from neutron powder diffraction data using direct space methods. Neutron powder diffraction data were collected from perdeuterated AMH II usin…

Crystallography and molecular interactionsX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds

Tunable Injection Barrier in Organic Resistive Switches Based on Phase‐Separated Ferroelectric–Semiconductor Blends

Kamal Asadi、Tom G. de Boer、Paul W. M. Blom 等 4 位作者2009-08-26Advanced Functional Materials

Abstract Organic non‐volatile resistive bistable diodes based on phase‐separated blends of ferroelectric and semiconducting polymers are fabricated. The polarization field of the ferroelectric modulates the injection barrier at the semiconductor–electrode contact and, hence, the resistance of the comprising diodes. Co…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications

Design of pheromone releasing nanofibers for plant protection

Christoph Hellmann、Andreas Greiner、Joachim H. Wendorff2009-08-26Polymers for Advanced Technologies

Abstract Plants tend to attract diseases quite similar to human beings. Pesticides tend to be used to control such diseases. An alternative route, at least as far as damages from insects is concerned, envisions the application of pheromones. These cause a disorientation of male insects so that they are no longer able…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Stress-induced large Curie temperature enhancement inFe64Ni36Invar alloy

P. Gorría、David Martínez‐Blanco、M.J. Pérez 等 21 位作者2009-08-26Physical Review B

We have succeeded in increasing up to 150 K the Curie temperature in the ${\text{Fe}}_{64}{\text{Ni}}_{36}$ invar alloy by means of a severe mechanical treatment followed by a heating up to 1073 K. The invar behavior is still present as revealed by the combination of magnetic measurements with neutron and x-ray techni…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

On the importance of incorporating dipole reradiation in the modeling of surface enhanced Raman scattering from spheres

Logan K. Ausman、George C. Schatz2009-08-26The Journal of Chemical Physics

Surface enhanced Raman scattering (SERS) enhancement factors G for nanoparticles consisting of a single Ag sphere or a dimer of Ag nanospheres are calculated using a T-matrix method that rigorously incorporates dipole reradiation (DR) effects. A comparison with the commonly used plane wave (PW) approximation, /E(loc)(…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

Gyrotropy of a Metamolecule: Wire on a Torus

Nikitas Papasimakis、V.A. Fedotov、K. Marinov 等 4 位作者2009-08-26Physical Review Letters

Sharing topology with numerous organic molecules, a wire helix bend into a torus gives a curious object with a gyrotropic behavior which is far from obvious. While a continuous constant current in opposite sections of the torus would create mutually cancelling contributions to its gyrotropic response, an array of tori…

Metamaterials and Metasurfaces ApplicationsAcoustic Wave Resonator TechnologiesGyrotron and Vacuum Electronics Research

Zero loss magnetic metamaterials using powered active unit cells

Yuan Yu、Bogdan‐Ioan Popa、Steven A. Cummer2009-08-26Optics Express

We report the design and experimental measurement of a powered active magnetic metamaterial with tunable permeability. The unit cell is based on the combination of an embedded radiofrequency amplifier and a tunable phase shifter, which together control the response of the medium. The measurements show that a negative…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesEnergy Harvesting in Wireless Networks

Thermoelectric power and Hall coefficient measurements onBa(Fe1−xTx)2As2(T=Coand Cu)

E. D. Mun、Sergey L. Bud’ko、Ni Ni 等 5 位作者2009-08-26Physical Review B

Temperature-dependent thermoelectric power (TEP) data on $\text{Ba}{({\text{Fe}}_{1\ensuremath{-}x}T{M}_{x})}_{2}{\text{As}}_{2}$ ($TM=\text{Co}$ and Cu), complemented by the Hall coefficient data on the samples from the same batches, have been measured. For Co doping we clearly see a change in the temperature-depende…

Rare-earth and actinide compoundsIron-based superconductors researchIntellectual Capital and Performance Analysis

The structural and electrical evolution of graphene by oxygen plasma-induced disorder

Dong Chul Kim、Dae‐Young Jeon、Hyun‐Jong Chung 等 6 位作者2009-08-26Nanotechnology

Evolution of a single graphene layer with disorder generated by remote oxygen plasma irradiation is investigated using atomic force microscopy, Raman spectroscopy and electrical measurement. Gradual changes of surface morphology from planar graphene to isolated granular structure associated with a decrease of transcon…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Versatile Synthesis and Rational Design of Caged Morpholinos

Xiaohu Ouyang、Ilya Shestopalov、Surajit Sinha 等 8 位作者2009-08-26Journal of the American Chemical Society

Embryogenesis is regulated by genetic programs that are dynamically executed in a stereotypic manner, and deciphering these molecular mechanisms requires the ability to control embryonic gene function with similar spatial and temporal precision. Chemical technologies can enable such genetic manipulations, as exemplifi…

Advanced biosensing and bioanalysis techniquesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

An Experimental Approach to Evaluate the Critical Damage

Mehdi Amiri、Mehdi Naderi、M. M. Khonsari2009-08-26International Journal of Damage Mechanics

An experimental study has been carried out to determine the critical damage parameter based on the concept of entropy flow. The fatigue damage is either a cumulative process that progresses toward a maximum tolerable damage, or is an irreversible progression of cyclic plastic strain energy that reaches its critical va…

Microstructure and Mechanical Properties of SteelsFatigue and fracture mechanicsHigh-Velocity Impact and Material Behavior