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Optical and electrical properties of layer semiconductor p-GaSe doped with Zn

S. Shigetomi、Tetsuo Ikari、Hiroshi Nakashima1993-09-15Journal of Applied Physics

Zinc (Zn) is doped into GaSe single crystals grown by the Bridgman technique in a wide range from 0.005 to 0.5 at. % to the stoichiometric melt. Radiative recombination mechanisms have been investigated by using photoluminescence (PL) measurements. The PL spectra in Zn-doped samples at 77 K are dominated by three emis…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Critical temperature and concentration versus molecular weight in polymer blends: Conformations, fluctuations, and the Ginzburg criterion

Robert Hołyst、Thomas A. Vilgis1993-09-15The Journal of Chemical Physics

We use the field-theoretical methods to derive the self-consistent one-loop equations (Hartree approximation) for the location of the critical point in binary mixtures of polymers. The small parameter in the loop expansion is the inverse of the square root of the number of segments (monomers) in a polymer chain 1/√N.…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Magnetic order in nanocrystalline Cr and suppression of antiferromagnetism in bcc Cr

M. R. Fitzsimmons、J. A. Eastman、R. A. Robinson 等 7 位作者1993-09-15Physical review. B, Condensed matter

Neutron-diffraction data and magnetization measurements of compacted nanophase Cr are presented. Two crystalline Cr phases were found, the majority phase having a bcc structure and the minority phase having an A15 structure. The 100 Bragg reflection seen in antiferromagnetically ordered coarse-grained bcc-Cr polycryst…

Magnetic properties of thin filmsMicrostructure and mechanical propertiesTheoretical and Computational Physics

Time-resolved small-angle neutron scattering study of spinodal decomposition in deuterated and protonated polybutadiene blends. I. Effect of initial thermal fluctuations

Hiroshi Jinnai、Hirokazu Hasegawa、Takeji Hashimoto 等 4 位作者1993-09-15The Journal of Chemical Physics

Time-resolved small-angle neutron scattering (SANS) experiments have been performed on the self-assembling process of a binary mixture of deuterated polybutadiene and protonated polybutadiene at the critical composition. This mixture has an upper critical solution temperature type of phase diagram with the spinodal te…

Advanced Chemical Physics StudiesMaterial Dynamics and PropertiesAdvanced Physical and Chemical Molecular Interactions

First-principles molecular-dynamics study of carbon clusters

Madhu Menon、K. R. Subbaswamy、Majid Sawtarie1993-09-15Physical review. B, Condensed matter

A universal-parameter tight-binding molecular-dynamics technique that correctly treats interactions in nontetrahedral as well as multicoordinated covalent systems is used to obtain equilibrium geometries for carbon clusters of arbitrary size. For N\ensuremath{\le}10 the ground states are determined to be linear chains…

Advanced Chemical Physics StudiesGraphene research and applicationsDiamond and Carbon-based Materials Research

Concentric-shell algorithm for Auger and core-level photoelectron diffraction: Theory and applications

D. K. Saldin、G. R. Harp、X. Chen1993-09-15Physical review. B, Condensed matter

A full multiple-scattering method is described for the calculation of angle-resolved photoelectron, Auger-electron, and Kikuchi-electron diffraction patterns. The method is particularly useful for the range of electron kinetic energies from about 50 eV to a few thousand eV. Approximations that take advantage of the fi…

Advanced Electron Microscopy Techniques and ApplicationsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Long-lived photoexcited states in symmetrical polydicarbazolyldiacetylene

G. Dellepiane、C. Cuniberti、Davide Comoretto 等 7 位作者1993-09-15Physical review. B, Condensed matter

Photoinduced absorption is observed for the polydicarbazolyldiacetylene in the microcrystalline state. The absorption spectrum shows well-defined excitonic features, very similar to those observed for the same polymer in the single-crystal form. Photoexcitation at 2.54 eV gives rise to a structured luminescence emissi…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsPhotoreceptor and optogenetics research

Complex dielectric function of amorphous diamond films deposited by pulsed-excimer-laser ablation of graphite

Fulin Xiong、Y. Y. Wang、Robert P. H. Chang1993-09-15Physical review. B, Condensed matter

Amorphous diamond films have been synthesized by pulsed excimer- (ArF) -laser ablation of graphite at room temperature. Detailed studies of the energy-dependent complex dielectric function in the energy range up to 40 eV have been carried out by Kramers-Kronig dispersion analysis of transmission electron-energy-loss s…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced Surface Polishing Techniques

Energetics, bonding mechanism, and electronic structure of metal-ceramic interfaces: Ag/MgO(001)

Chun Li、Ruqian Wu、A. J. Freeman 等 4 位作者1993-09-15Physical review. B, Condensed matter

Electronic-structure total-energy investigations for the metal-ceramic interface system Ag/MgO(001) show that the preferred adsorption site for the overlayer Ag atom is above the O site of the clean MgO(001) surface. The binding energy of the overlayer Ag atom on the MgO(001) surface is 0.3 eV/atom (0.64 J/${\mathrm{m…

Semiconductor materials and devicesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

On the applicability of the Lennard‐Jones potential function to amorphous high polymers

C. B. Arends1993-09-15Journal of Applied Polymer Science

Abstract Pressure‐volume‐temperature measurements were performed on five amorphous thermoplastics. From these data, first derivatives of internal energy with respect to volume were calculated. These derivatives were cast into the Lennard‐Jones form and the two defining parameters were evaluated for each polymer. It wa…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesGlass properties and applications

Charge and energy transport by tunneling thermoelectric effect

Jochen Marschall、Arun Majumdar1993-09-15Journal of Applied Physics

Computational predictions, based upon conventional one-dimensional tunneling theory, are presented for charge and energy transport by electron tunneling thermoelectric effect. It is shown that a temperature difference across a tunnel junction connected in an open electrical circuit produces a thermopower S and a heat…

Advanced Thermoelectric Materials and DevicesForce Microscopy Techniques and ApplicationsThermal properties of materials

Mechanical and thermal properties of UV‐curable polyurethane and polyurea acrylates

Xuehai Yu、Brian P. Grady、Richard Reiner 等 4 位作者1993-09-15Journal of Applied Polymer Science

Abstract Soft‐segment molecular weight, soft‐segment crystallization, hard‐segment‐type, and reactive diluent level were examined in urea and urethane acrylates. Increasing soft‐segment molecular weight led to a decreased tensile modulus, increased strength, and increased elongation at break. Soft‐segment crystallizat…

Polymer composites and self-healingBuilding materials and conservationPhotopolymerization techniques and applications

Final-state screening effect in the 3sphotoemission spectra of Mn and Fe insulating compounds

G.-H. Gweon、Je‐Geun Park、S.-J. Oh1993-09-15Physical review. B, Condensed matter

The satellite structures of 3s core-level photoemission spectra of Mn and Fe dihalides and mono-oxides have been studied systematically. We found that exchange splitting between 3s holes and 3d electrons, intrashell electron correlation, and final-state screening (charge-transfer satellite) effects all contribute to t…

ZnO doping and propertiesIron oxide chemistry and applicationsElectron and X-Ray Spectroscopy Techniques

Trace elemental analysis at nanometer spatial resolution by parallel-detection electron energy loss spectroscopy

Richard D. Leapman、Dale E. Newbury1993-09-15Analytical Chemistry

Parallel-detection electron energy loss spectroscopy (EELS) combined with scanning transmission electron microscopy (STEM) and a field emission source provides an unprecedented sensitivity for elemental microanalysis. By deflecting the energy loss spectrum across a parallel detector and computing the difference spectr…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Forced translational vibrations of 90° domain walls and the dielectric dispersion in ferroelectric ceramics

N. A. Pertsev、G. Arlt1993-09-15Journal of Applied Physics

A theory of collective translational vibrations of 90° domain walls (DWs) in ferroelectric ceramics is presented. Vibrational motions of DWs forming a regular domain structure of a representative grain are assumed to be completely correlated but independent of DW oscillations in other grains. A dynamic mechanical stre…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

The initial permeability of polycrystalline MnZn ferrites: The influence of domain and microstructure

P. J. van der Zaag、J.J.M. Ruigrok、A. Noordermeer 等 8 位作者1993-09-15Journal of Applied Physics

The validity of nonmagnetic grain-boundary (NMGB) models for the initial permeability of polycrystalline ferrites is examined. The domain size in a series of wet-chemically prepared polycrystalline MnZn ferrites, in the demagnetized state, has been determined by neutron depolarization. A transition in the intragranula…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Phase-only modulation of a twisted nematic liquid-crystal TV by use of the eigenpolarization states

J. Larry Pezzaniti、Russell A. Chipman1993-09-15Optics Letters

We present the eigenpolarization states of a commercially available liquid-crystal television display and show that phase-only modulation can be achieved over a large dynamic range of video voltages for several bias voltage settings if the eigenpolarization states are used. A set of operating curves using these polari…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced Optical Imaging Technologies

Tribological properties of polished diamond films

Bharat Bhushan、V. V. Subramaniam、Ajay P. Malshe 等 5 位作者1993-09-15Journal of Applied Physics

Despite the rapid progress being made in the synthesis of diamond films and recent interest in polishing of diamond films, no systematic measurements of friction and wear on polished diamond films have been reported. In the present study, chemomechanical and laser polishing techniques are used, and friction and wear d…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Effect of the chemical nature of transition-metal substrates on chemical-vapor deposition of diamond

X. Chen、J. Narayan1993-09-15Journal of Applied Physics

Chemical-vapor deposition of diamond on transition-metal substrates of Cu, Ni, Fe, and their alloys NiAl, Ni3Al, FeSi2, and FeSi has been investigated. It is shown that diamond grows easily on Cu with a very small amount of graphite, while on Ni and Fe there is rapid growth of the graphite layer before diamond deposit…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Toroidal forms of graphitic carbon. II. Elongated tori

Satoshi Itoh、Sigeo Ihara1993-09-15Physical review. B, Condensed matter

An elongated toroidal cage form of graphitic carbon ${\mathrm{C}}_{240}$ that has an elliptical cross section is proposed. The elongated toroidal form consists of pairs of pentagons and heptagons among the hexagons of carbon atoms. The rotational symmetry, the cohesive energies, and thermal stabilities of the elongate…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications