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Local Isoelectronic Reactivity of Solid Surfaces

Steffen Wilke、Morrel H. Cohen、Matthias Scheffler1996-07-23arXiv

The quantity w^N(r) = ( 1/ k^2 T_el)[partial n(r, T_el) / partial T_el]_(v(r),N) is introduced as a convenient measure of the local isoelectronic reactivity of surfaces. It characterizes the local polarizability of the surface and it can be calculated easily. The quantity w^N(r) supplements the charge transfer reactiv…

Materials Sciencemtrl-th

Polymeric Materials Encyclopedia, Twelve Volume Set

J. C. Salamone1996-07-23OpenAlex

Additives Biodegradable Polymers Biomaterials for the Body Biomimetic Materials Biosensors Blends Block Copolymers Block Copolymer Micelles Comb-like Polymers Commercial Resins, Plastics, Elastomers Composites Compatibilizers Conducting Polymers Contact Lens Materials Controlled Release Dendrictic Polymers Dendrimers…

Silicone and Siloxane Chemistry

The best thermoelectric.

G. D. Mahan、Jorge O. Sofo1996-07-23OpenAlex

What electronic structure provides the largest figure of merit for thermoelectric materials? To answer that question, we write the electrical conductivity, thermopower, and thermal conductivity as integrals of a single function, the transport distribution. Then we derive the mathematical function for the transport dis…

Advanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical Mechanics

Polyimides: Fundamentals and Applications

Malay Ghosh、K. L. Mittal1996-07-23OpenAlex

Introduction History of the Invention and Development of the Polyimides, C. E. Sroog Synthesis Synthesis of Polyimides, Tohru Takekoshi Synthesis of Polyamideimides, Yoshio Imai Synthesis of Fluorinated Polyimides, Shigekuni Sasaki and Shiro Nishi Photosensitive Polyimides, Molecular Design and Synthesis, Toshihiko Om…

Synthesis and properties of polymersSilicone and Siloxane Chemistry

Identity of InSb-II and InSb-III

R. J. Nelmes、M. I. McMahon1996-07-22Physical Review Letters

The well-known phase transition from InSb-IV to InSb-III at $\ensuremath{\sim}10\mathrm{GPa}$ has been studied using angle-dispersive powder-diffraction techniques. It is shown that the transition proceeds through a previously undetected intermediate phase, and that InSb-III is in fact identical with InSb-II. The appa…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Defects and degradation in ZnO varistor

Wei‐I Lee、Ruey-Ling Young Ruey-Ling Young1996-07-22Applied Physics Letters

A systematic study of the defects in ZnO has been performed. The two commonly observed levels (L1, L2), located at around 0.15 and 0.24 eV under the conduction band, have been identified as native defects. The deep level transient spectroscopy depth profiling technique is applied on multilayer-chip-type ZnO varistors…

ZnO doping and propertiesThin-Film Transistor Technologies

Influence of Quantum Confinement on the Critical Points of the Band Structure of Si

M. Ben‐Chorin、B. Averboukh、Dmitry Kovalev 等 5 位作者1996-07-22Physical Review Letters

The photoluminescence excitation technique is used to monitor the absorption characteristics of Si nanocrystals. Contributions from different critical points are identified, and their shift with reduced size is deduced. The enhancement of the oscillator strength of the indirect optical transitions due to the confineme…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Nanocrystallites in tetrahedral amorphous carbon films

S. Ravi、S. Ravi P. Silva、Shi Xu 等 6 位作者1996-07-22Applied Physics Letters

The microstructure of filtered cathodic vacuum arc deposited tetrahedral amorphous carbon films is studied as a function of ion energy. An optimum energy window in the density and C–C sp3 content at an ion energy of ∼90 eV observed in this study. It is shown that the density of the amorphous carbon films are closely r…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Spin Waves throughout the Brillouin Zone of a Double-Exchange Ferromagnet

T. G. Perring、G. Aeppli、S. M. Hayden 等 6 位作者1996-07-22Physical Review Letters

We use inelastic neutron scattering to measure the spin wave dispersion throughout the Brillouin zone of the double-exchange ferromagnet L${\mathrm{a}}_{0.7}$P${\mathrm{b}}_{0.3}$Mn${\mathrm{O}}_{3}$. Magnons with energies as high as 95 meV are directly observed and an unexpectedly simple Heisenberg Hamiltonian, with…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsAtomic and Subatomic Physics Research

Phase separation and resistivity jumps in Co compounds and other materials with low-spin - high-spin transitions

É.L. Nagaev、A.I. Podel'shchikov1996-07-22Journal of Physics Condensed Matter

States of charge carriers in transition metal compounds with low-frequency zero-spin - nonzero-spin transitions (e.g. some Co compounds) are investigated. Such transitions indicate the appearance of magnetic excitons on the transition metal ions. Charge carriers interact strongly with the excitons via exchange forces.…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Neutron Scattering Evidence for Localized Soft Modes in Amorphous Polymers

U. Buchenau、Carlos Pecharromán、Reiner Zorn 等 4 位作者1996-07-22Physical Review Letters

The localization of low-frequency vibrational modes in amorphous solids can be determined from incoherent neutron scattering. Time-of-flight data from polystyrene and polybutadiene show a localization of the boson peak modes to about ten monomers.

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesQuantum, superfluid, helium dynamics

4‐O‐Phosphoryl‐l‐threonine, a substrate of the pdxC(serC) gene product involved in vitamin B6 biosynthesis

Christel Drewke、Matthias Klein、Dorothee Clade 等 6 位作者1996-07-22FEBS Letters

The Escherichia coli pdxC(serC) gene codes for a transaminase (EC 2.6.1.52). The gene is involved in both pyridoxine (vitamin B6) and serine biosynthesis and was overexpressed as a MalE/PdxC(SerC) fusion protein. The fusion protein was purified by affinity chromatography on an amylose resin and hydrolyzed in the prese…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionBiochemical and Molecular Research

Theory of binary mixtures of a flexible polymer and a liquid crystal

Akihiko Matsuyama、Tadaya Kato1996-07-22The Journal of Chemical Physics

A simple model is presented to describe the phase behavior in binary mixtures of a flexible polymer and a liquid crystal. By using the incompressible approximation to the Onsager theory which combined both the excluded volume interactions between the liquid crystals and the attractive interaction due to the alignment…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Raman scattering of alternating nanocrystalline silicon/amorphous silicon multilayers

X. L. Wu、G. G. Siu、S. Y. Tong 等 8 位作者1996-07-22Applied Physics Letters

Nanocrystallite size distribution and structural properties in alternating hydrogenated nanocrystalline silicon/amorphous silicon multilayers were investigated by means of Raman scattering. The obtained Raman spectra show a broad peak at ∼480 cm−1 from amorphous Si and some small peaks superposed on the broad peak. Ac…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNonlinear Optical Materials Studies

Scaling of the Dynamic Scattering Function of Concentrated Colloidal Suspensions

P. N. Segrè、P. N. Pusey1996-07-22Physical Review Letters

By dynamic light scattering we have studied concentrated suspensions of ``hard-sphere'' colloidal particles in their equilibrium and metastable fluid states. We have found a simple, as yet unexplained, scaling procedure which collapses the measured intermediate scattering functions describing structural relaxation and…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Near-edge x-ray absorption of carbon materials for determining bond hybridization in mixed sp 2/ sp 3 bonded materials

F. L. Coffman、Rui Cao、P. Pianetta 等 6 位作者1996-07-22Applied Physics Letters

Near-edge x-ray absorption fine structure (NEXAFS) measurements were performed on a variety of carbon materials, covering a range of hybrid bonding character from pure sp3 type to pure sp2 type. Diamond, chemical vapor deposited (CVD) diamond films of varying quality. Diamond-like carbon (DLC) films, and graphite were…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Direct Observation of Lattice Polaron Formation in the Local Structure ofLa1−xCaxMnO3

Simon J. L. Billinge、R. G. Difrancesco、G. H. Kwei 等 5 位作者1996-07-22Physical Review Letters

The local atomic structure of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}{\mathrm{MnO}}_{3}$ ( $x\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}0.12,$ 0.21, and 0.25) has been studied using pair-distribution-function analysis of neutron powder-diffraction data. A change is seen in the local structure which…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Coupled Hartree–Fock calculations of molecular magnetic properties annihilating the transverse paramagnetic current density

Riccardo Zanasi1996-07-22The Journal of Chemical Physics

The reliability of the continuous transformations of origin of the current density method, which makes the transverse paramagnetic current vanish (CTOCD-PZ), for the prediction of nearly gauge-origin independent molecular magnetic susceptibility and gauge-origin independent nuclear magnetic shielding, is proved on the…

Advanced Chemical Physics StudiesMagnetism in coordination complexesAdvanced NMR Techniques and Applications

Metastable nematic hedgehogs

Riccardo Rosso、Epifanio G. Virga1996-07-21Journal of Physics A Mathematical and General

For nematic liquid crystals, we study the local stability of a radial hedgehog against biaxial perturbations. Our analysis employs the Landau - de Gennes functional to describe the free energy stored in a ball, whose radius is a parameter of the model. We find that a radial hedgehog may be either unstable or metastabl…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

TIME DOMAIN MODELING OF BRIDGE DECK FLUTTER

K. Wilde、Yozo Fujino、J. Masukawa1996-07-21Doboku Gakkai Ronbunshu

一様気流中におかれた橋梁断面に作用する動的空気力は桁の状態量 (速度, 変位) で表すことが多い. そのために動的空気力係数は風速, 振動数の関数となり, 周波数領域の解析を強いられる欠点がある. 本研究では, 拡張変数を導入して定数系の微分方提式で空気力を表す有理関数近似法の橋梁断面への適用を検討している. (1) 最小二乗法と最小状態量法を適用し. 後者の方が拡張変数の数が少なくてすむこと, (2) 翼形断面の場合は, 拡張変数が1つ, 偏平箱桁では2つ, トラス断面では3つ程度導入すれば精度よく動的空気力を表現でき, フラッター限界風速も精度よく予測できることを明らかにしている.

High voltage insulation and dielectric phenomenaReal-time simulation and control systemsElevator Systems and Control