Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT4,6-Dimethoxy-1,3-phenylenebis(N-tert-butyl nitroxide) with a singlet ground state. Formal violation of a rule that m-phenylene serves as a robust ferromagnetic coupling unitFumio Kanno, Katsuya Inoue, Noboru Koga, and Hiizu IwamuraCite this: J. Am. Chem. Soc. 1993, 115, 3,…
We used transposon (Tn) mutagenesis to study the role of capsular polysaccharide/adhesin (PS/A) and slime in adherence of Staphylococcus epidermidis to catheters. pLTV1, containing Tn917-LTV1, was transformed into S. epidermidis M187 by protoplast fusion with S. aureus RN4220(pLTV1), creating M187(pLTV1). Tn mutants w…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanistic studies of copper thin-film growth from CuI and CuII .beta.-diketonatesGregory S. Girolami, Patrick M. Jeffries, and Lawrence H. DuboisCite this: J. Am. Chem. Soc. 1993, 115, 3, 1015–1024Publication Date (Print):February 1, 1993Publication History Published onlin…
The sedimentation of monodisperse suspensions of rigid spheres has been studied by dynamical simulation; computational techniques are described and numerical results are reported. It has been found that there is a slow relaxation of the suspension microstructure during sedimentation, so that compared with the initial…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMorphology transition from cylindrical to lamellar microdomains of block copolymersShinichi Sakurai, Toshikazu Momii, Kazuhiro Taie, Mitsuhiro Shibayama, Shunji Nomura, and Takeji HashimotoCite this: Macromolecules 1993, 26, 3, 485–491Publication Date (Print):February 1, 199…
It appears that, under suitable conditions, diatom assemblages can respond very quickly to a toxic event. The data suggest an inoculum of cells from the water column can multiply rapidly. Sediment-inhabiting macrofauna are more seriously affected, reducing grazing restrictions on the developing diatom assemblages. The…
The beginning–or the end—of the metallic state is attained in ligand‐stabilized Au 55 clusters. As quantum dots with two last “switchable” electrons they are the nonpareils of electronic miniaturization and can be used as microelectronic quantum devices.
Using proteolytic susceptibility as a probe, we have identified four regions of the actin polypeptide chain where structural rearrangements, dependent on the nature of the tightly bound metal ion and/or nucleotide, take place. Replacement of the tightly bound Ca2+ by Mg2+ in ATP-actin strongly affected the regions aro…
The melting transition of particles interacting via a Yukawa potential is determined from the evolution of systems containing coexisting solid and fluid phases. There is no nucleation barrier, and the stable phase expands rapidly to fill the system. Results for the phase boundary agree with recent free energy calculat…
A systematic investigation of the intrinsic magnetic properties of R${\mathrm{Fe}}_{11}$Ti compounds with R=Y, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, and Tm has been performed by means of ac-susceptibility measurements, singular-point-detection techniques, and high-field magnetization measurements. Spin-reorientation transit…
A drop-tube-processed Al-3.6wt.%Fe representative droplet of about 500 μm diameter shows the two-zone fine cellular-coarse cellular α-Al structure, hitherto reported only in as-atomized hypereutectic AlFe powder particles of less than 50 μm diameter. The origin of the transitional microstructure is analysed in terms…
Five selected S-alkylisothisothiouronium iodides have been studied as acid corrosion inhibitors at 30°C for steel in 0.5 M H2SO4 using gasometry, mass loss, and direct current (DC) polarization techniques. All of the data reveal that the compounds act as inhibitors in the acid environments; furthermore, polarization c…
Theoretical calculation shows that suitable approximations of the line-shape asymmetry in powder diffraction profiles should be represented by functions having limited codomains.
Abstract Triblock copolymers were prepared from L‐lactide and a poly(ethylene glycol) of M̄ n = 1020. With GeO 2 and SnO 2 only low conversions were obtained, regardless of the reaction temperature. Sb 2 O 3 caused partial racemization, and only SnO gave satisfactory results. When other samples of poly(ethylene glycol…
Macromolecular structure determination by X-ray crystallography and solution NMR spectroscopy has experienced unprecedented growth during the past decade.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRigid bowlic liquid crystals based on tungsten-oxo calix[4]arenes: host-guest effects and head-to-tail organizationBing Xu and Timothy M. SwagerCite this: J. Am. Chem. Soc. 1993, 115, 3, 1159–1160Publication Date (Print):February 1, 1993Publication History Published online1…
In the strong versus fragile classification of simple liquids near their glass transition, a simple model is used to quantify this distinction, which sheds light on mechanisms in glass-forming liquids near freezing. From this model it is shown that the fragility parameter, one of the most important material constants,…
Arc discharging carbon rods containing 8.8 wt% La 2 O 3 produces a carbonaceous deposit containing nano-particles (nm-size particles) consisting of graphite shells around core nano-crystals averaging 10-30 nm in diameter but sometimes 3-4 nm. Transmission electron microscopy, nm-size electron diffraction and electron…
The structure of n-fold rings in vitreous ${\mathrm{SiO}}_{2}$ is investigated using molecular-dynamics configurations. A recently developed interaction potential for ${\mathrm{SiO}}_{2}$ consisting of long-range Coulomb interactions, the effect of electronic polarizability, and three-body covalent forces is used in t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron correlation effects in hyperpolarizabilities of p-nitroanilineFiona Sim, Steven Chin, Michel Dupuis, and Julia E. RiceCite this: J. Phys. Chem. 1993, 97, 6, 1158–1163Publication Date (Print):February 1, 1993Publication History Published online1 May 2002Published ini…