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High-order vibration modes of bimetallic Ag-Au nanoparticles embedded in glass

S. V. Adichtchev、Sergey Sirotkin、Guillaume Bachelier 等 8 位作者2009-05-18Physical Review B

High-resolution low-frequency Raman scattering measurements from embedded AgAu nanoparticles unveil efficient scattering by harmonics of both the quadrupolar and the spherical modes. Comparing the experimental data with theoretical calculations that account for both the embedding medium and the resonant Raman process…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials StudiesProtein Interaction Studies and Fluorescence Analysis

Facile Fabrication and Superparamagnetism of Silica‐Shielded Magnetite Nanoparticles on Carbon Nitride Nanotubes

Jung Woo Lee、Ravindranath Viswan、Yoon Jeong Choi 等 8 位作者2009-05-18Advanced Functional Materials

Abstract Using conventional methods to synthesize magnetic nanoparticles (NPs) with uniform size is a challenging task. Moreover, the degradation of magnetic NPs is an obstacle to practical applications. The fabrication of silica‐shielded magnetite NPs on carbon nitride nanotubes (CNNTs) provides a possible route to o…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Thin film evolution: Dewetting dynamics of a bimodal molecular system

Jessica M. Topple、Sarah A. Burke、Shawn Fostner 等 4 位作者2009-05-18Physical Review B

Deposition of submonolayer coverages of 3,4,9,10-perylenetetracarboxylic diimide onto NaCl(001) results in the bimodal growth of coexisting square and needle-shaped islands. The epitaxy of each island type was determined from molecular and atomic resolution noncontact atomic force microscopy images. Postdeposition, th…

Molecular Junctions and NanostructuresBlock Copolymer Self-AssemblySurface and Thin Film Phenomena

Toward Electrochromic Device Using Solid Electrolyte with Polar Polymer Host

Anh Chien Nguyen、Shanxin Xiong、Jan Ma 等 5 位作者2009-05-18The Journal of Physical Chemistry B

Polymer electrolyte is an important component in many multilayer devices such as batteries, fuel cells, and electrochromic devices. The effects of polymer electrolyte solidification on the ionic movement and device performance are presented based on near-infrared (IR) (860-2500 nm) electrochromic (EC) devices using th…

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications

Synthesis of Visible Light-Sensitive ZnO Nanostructures: Subwavelength Waveguides

Jooran Lee、Minjoong Yoon2009-05-18The Journal of Physical Chemistry C

Single crystalline ZnO nanowires and nanorods were synthesized by a new sol−gel method carried out through formation of liposome−ZnO nanocomposites with or without hydrothermal reaction, respectively, and they were characterized to be hexagonal wurtzite structure by measurements of XRD patterns and SEM and TEM images.…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Correlation Between Wettability and Cleanability of Polyester Fabrics Modified by a Soil Release Polymer and Their Topographic Structure

Mir Mohammad Badrul Hasan、Alfredo Calvimontes、Victoria Dutschk2009-05-18Journal of Surfactants and Detergents

Abstract In this study, it was found that images scanned by a non‐contact optical instrument for topographic characterisation based on the principle of chromatic aberration give sufficient information to know the exact location of soil release polymer (SRP) deposition over fabrics. Through the comparison of reflected…

Surface Modification and SuperhydrophobicityMicroplastics and Plastic PollutionTextile materials and evaluations

UV‐activated hydrosilylation: a facile approach for synthesis of hyperbranched polycarbosilanes

Guobin Zhang、Jie Kong、Xiaodong Fan 等 6 位作者2009-05-18Applied Organometallic Chemistry

Abstract A facile approach for synthesis of hyperbranched polycarbosilane from AB 2 monomer via UV‐activated hydrosilylation is presented in this communication. The polymerization process was monitored using real‐time FTIR spectroscopy and the resulting hyperbranched polycarbosilanes were characterized using 1 H‐NMR,…

Synthetic Organic Chemistry MethodsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

A Nanodot Array Modulates Cell Adhesion and Induces an Apoptosis-Like Abnormality in NIH-3T3 Cells

Hsu-An Pan、Yao‐Ching Hung、Chia-Wei Su 等 7 位作者2009-05-18Nanoscale Research Letters

Micro-structures that mimic the extracellular substratum promote cell growth and differentiation, while the cellular reaction to a nanostructure is poorly defined. To evaluate the cellular response to a nanoscaled surface, NIH 3T3 cells were grown on nanodot arrays with dot diameters ranging from 10 to 200 nm. The nan…

Cellular Mechanics and InteractionsPolymer Surface Interaction StudiesAnodic Oxide Films and Nanostructures

Photoalignment effect in a liquid-crystal film doped with nanoparticles and azo-dye

Wen-Zheng Chen、Yi‐Tai Tsai、Tsung‐Hsien Lin2009-05-18Applied Physics Letters

This study discusses the photoalignment effect in a liquid-crystal (LC) film that is doped with nanoparticles and azo-dye. The vertical alignment induced by nanoparticles of polyhedral oligomeric silsesquioxanes can be changed into homogeneous alignment by the absorption of photoexcited azo-dye. An electrically tunabl…

Liquid Crystal Research AdvancementsOptical Coatings and GratingsSilicone and Siloxane Chemistry

Polymer Vesicles as Robust Scaffolds for the Directed Assembly of Highly Crystalline Nanocrystals

Mingfeng Wang、Meng Zhang、Conrad Siegers 等 5 位作者2009-05-18Langmuir

We report the incorporation of various inorganic nanoparticles (NPs) (PbS, LaOF, LaF(3), and TiO(2), each capped by oleic acid, and CdSe/ZnS core/shell QDs capped by trioctylphosphine oxide) into vesicles (d = 70-150 nm) formed by a sample of poly(styrene-b-acrylic acid) (PS(404)-b-PAA(62), where the subscripts refer…

Quantum Dots Synthesis And PropertiesAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Evolution of ferromagneticlike order inFe2V1−xCrxAlHeusler alloys

Ritwik Saha、V. Srinivas、T. V. Chandrasekhar Rao2009-05-18Physical Review B

Structural, magnetic, and magnetotransport behaviors of ${\text{Fe}}_{2}{\text{V}}_{1\ensuremath{-}x}{\text{Cr}}_{x}\text{Al}$ Heusler-type alloys have been investigated in the present work. From the detailed analysis of data it is observed that increasing Cr content promotes site disorder of Fe and Al, which in turn…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsHeusler alloys: electronic and magnetic properties

Construction of Two Discrete Molecular High‐Nuclearity Copper(II) Complexes as Heterogeneous Catalysts for Oxidative Coupling Polymerisation of 2,6‐Dimethylphenol

Jie Wu、Hongwei Hou、Yuexin Guo 等 5 位作者2009-05-18European Journal of Inorganic Chemistry

Abstract Reaction of a rigid conjugated clamp‐like multi‐pyridineligand N , N ′‐bis(pyridin‐3‐yl)‐2,6‐pyridinedicarboxamide (H 2 L) with CuSO 4 · 5H 2 O or Cu(OAc) 2 resulted in the formation of two high‐nuclearity, discrete molecular copper(II) complexes, namely [Cu 10 (H 2 L) 5 (SO 4 ) 8 (μ 3 ‐OH) 4 (H 2 O) 2 ] · 4C…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

The influence of tin and silver as microstructure modifiers on the corrosion rate of Pb–Ca alloys in sulfuric acid solutions

Milan Čekerevac、Endre Romhanji、Z. Cvijović 等 4 位作者2009-05-18Materials and Corrosion

Abstract The effect of microstructure modifiers, Sn and Ag, on the corrosion rate of commercial Pb–Ca alloy in H 2 SO 4 electrolyte was investigated by the potentiodynamic polarization and by the weight loss corrosion rate measurement at the open circuit potential. The effect of microstructure modification of the Pb–C…

Corrosion Behavior and InhibitionAdvanced Thermoelectric Materials and DevicesThermodynamic and Structural Properties of Metals and Alloys

Compact tuneable single and dual mode ferrite left-handed coplanar waveguide coupled line couplers

Mahmoud A. Abdalla、Zhirun Hu2009-05-18IET Microwaves Antennas & Propagation

For the first time, single and dual mode novel left-handed coupled line couplers implemented on ferrite substrates are reported. Both of the proposed couplers demonstrate novel characteristics of coupler operation with properties of tunability and non-reciprocity, which have not been demonstrated before. The proposed…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAdvanced Antenna and Metasurface Technologies

Surface plasmon polaritons on deep, narrow-ridged rectangular gratings

M. R. Gadsdon、Ian R. Hooper、Alastair P. Hibbins 等 4 位作者2009-05-18Journal of the Optical Society of America B

The dispersion diagrams of surface plasmon polaritons have been calculated for rectangular gratings, with very narrow wires, of varying depths. For gratings with a moderate height a family of vertical-standing-wave resonances may be excited, which consist of surface plasmons, oscillating on either vertical surface, co…

Plasmonic and Surface Plasmon ResearchPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Unusual doping dependence of superconductivity inNayFeAs

Kalyan Sasmal、Bing Lv、Z.J. Tang 等 8 位作者2009-05-18Physical Review B

Superconductivity and phase relationships were explored in the Na-Fe-As system. The PbFCl-type 111 phase is stable only within a Na stoichiometry range of 1.00 to $\ensuremath{\sim}0.85$, and exhibits bulk superconductivity within an even narrower range around 0.90 in ${\text{Na}}_{0.9}\text{FeAs}$. In particular, sto…

Corporate Taxation and AvoidanceIron-based superconductors research

Peroxide‐controlled degradation of polypropylene using a tetra‐functional initiator

M. J. Scorah、Shuihan Zhu、Alexander Psarreas 等 7 位作者2009-05-18Polymer Engineering and Science

Abstract The purpose of this work is to evaluate a new tetra‐functional peroxide initiator and offer comparisons with a di‐functional peroxide commonly used in the production of controlled‐rheology polypropylene (CRPP) resins. CRPP resins have been produced by reactive processing in a batch mixer by using various equi…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

An Examination of the Solution Chemistry, Nucleation Kinetics, Crystal Morphology, and Polymorphic Behavior of Aqueous phase Batch Crystallized l-Isoleucine at the 250 mL Scale Size

Nornizar Anuar、Wan Ramli Wan Daud、Kevin J. Roberts 等 5 位作者2009-05-18Crystal Growth & Design

An examination of the aqueous solution solubility and batch crystallization kinetics of l -isoleucine at the 250 mL scale size under a poly- and isothermal process condition is presented. Solubility data determined are consistent with the existence of two l -isoleucine polymorphic forms, in which both forms have diffe…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Long-lived blue phosphorescence of oxidized and annealed nanocrystalline silicon

Bernard Gelloz、Nobuyoshi Koshida2009-05-18Applied Physics Letters

It is shown that an appropriate combination of thermal oxidation and high-pressure water vapor annealing for nanosilicon leads to efficient blue-band phosphorescence with a lifetime of several seconds. Based on spectroscopic analyses on both the temperature dependence of decay dynamics and the change in the peak wavel…

Photonic Crystals and ApplicationsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Physisorption of adenine DNA nucleosides on zigzag and armchair single-walled carbon nanotubes: A first-principles study

Hongming Wang、Arnout Ceulemans2009-05-18Physical Review B

Using first-principles calculations, we report the adsorption of adenine dinucleoside on single-walled carbon nanotubes (CNTs) with various diameters and chiral angles. The calculations indicate that in addition to noncovalent $\ensuremath{\pi}\text{\ensuremath{-}}\ensuremath{\pi}$ interactions between the adenine bas…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies