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Structure and Stability of Carboxylate Complexes. 20. Diaqua Bis(methoxyacetato) Complexes of Nickel(II), Copper(II), and Zinc(II): A Structural Study of the Dynamic Pseudo-Jahn−Teller Effect

Keith Prout、Alison A. Edwards、Victor S. B. Mtetwa 等 6 位作者1997-06-01Inorganic Chemistry

The crystal structure of trans-diaquabis(methoxyacetato)copper(II), C(6)H(14)O(8)Cu, has been determined by neutron diffraction at 4.2 K (monoclinic, P2(1)/n, a = 6.88(1), b = 7.19(1), c = 9.77(2) Å, gamma = 95.7(1) degrees, (Z = 2)) and by X-ray diffraction at 125, 165, 205, 240, 265, 295, and 325 K. These measuremen…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Vacancy clustering to faulted loop, stacking fault tetrahedron and void in fcc metals

Yoshiharu Shimomura、R. Nishiguchi1997-06-01Radiation effects and defects in solids

An atomistic step of growth to a faulted loop, a stacking fault tetrahedron (sft) and a void by clustering of vacancies in fcc metals was studied by molecular dynamics computer simulation with an isotropic EAM potential due to Daw and Baskes [1]. In aluminum, a tri-vacancy relaxes to the Damask-Dienes-Weizer structure…

Microstructure and mechanical propertiesFusion materials and technologiesCopper Interconnects and Reliability

Volatiles released during the weathering of PVC

D. J. Carlsson、M. E. Krzymien、D. J. Worsfold 等 4 位作者1997-06-01Journal of Vinyl and Additive Technology

Abstract Volatile organic compounds and organochlorine species liberated by UV exposure of poly(vinyl chloride) (PVC) siding samples have been identified and preliminary quantification made. These volatiles included those remaining in a PVC sample after weathering or laboratory UV exposure and which could be released…

Recycling and Waste Management TechniquesPolymer Science and PVC

Anharmonic potentials in supercooled liquids: The soft-potential model

Ulrich Zürcher、T. Keyes1997-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Instantaneous normal modes (INM) are the harmonic approximation to liquid dynamics. This is an extension of the phonon description of lattice dynamics, in which case Bloch's theorem shows that all modes are extended. Long-range order is destroyed in liquids and glasses, and the INM spectrum has contributions from both…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSpectroscopy and Quantum Chemical Studies

The Wetting of Calcite Surfaces

Tsuyoshi Okayama、D. Steven Keller、Philip Luner1997-06-01The Journal of Adhesion

Three established methods for deriving the surface energetic parameters for calcite were studied. These are based on the contact angle in air using various wetting liquids, and submerged systems in water and in alkanes. Two variations of these methods that require less elaborate experimental procedures were also explo…

Surface Modification and SuperhydrophobicityEnhanced Oil Recovery TechniquesCalcium Carbonate Crystallization and Inhibition

A hard sandy‐loam soil from semi‐arid Northern Cameroon: II. Geochemistry and mineralogy of the bonding agent

Mark Lamotte、Ary Bruand、Daniel Ohnenstetter 等 5 位作者1997-06-01European Journal of Soil Science

Summary The hardening of soils containing little clay content has often been related to the cementing of skeleton grains. In sandy‐loam soils from the southern plain of the Chad basin the skeleton grains of the hard horizon are coated and bonded by wall‐shaped bridges. We have studied the bonding agent by X‐ray diffra…

Geological and Geochemical AnalysisClay minerals and soil interactionsMineralogy and Gemology Studies

A stochastic thermodynamic model for the gradual thermal transformation of SMA polycrystals

Abhijit Bhattacharyya、Dimitris C. Lagoudas1997-06-01Smart Materials and Structures

The martensitic - austenitic phase transformation of a polycrystalline shape memory alloys (SMA) occurs gradually over a range of temperatures even though the monocrystal undergoes a first-order transition (at a single temperature). Factors such as material inhomogeneities and internal stresses in a polycrystal are be…

Shape Memory Alloy Transformations

Effects of the Sequence Distribution of Poly(acrylonitrile−butadiene) Copolymers on the Surface Chemical Composition As Determined by XPS and Dynamic Contact Angle Measurements

Lin Li、Chi‐Ming Chan、Lu‐Tao Weng1997-06-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTEffects of the Sequence Distribution of Poly(acrylonitrile−butadiene) Copolymers on the Surface Chemical Composition As Determined by XPS and Dynamic Contact Angle MeasurementsLin Li, Chi-Ming Chan, and Lu Tao WengView Author Inform…

Recycling and Waste Management TechniquesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature

Mark E. Jason、TOAN NGO、Shahidur Rahman1997-06-01Inorganic Chemistry

The oxidation of phosphorus by sulfur at low temperatures (<100 °C) has been shown to produce complex mixtures that include 12 of the 17 known binary phosphorus sulfides. Two of these 17 sulfides have been observed in these mixtures for the first time. The rate-determining and first step in the reaction appears to be…

Thermal and Kinetic Analysis

A Benchmark Study on Crushing and Cutting of Plated Structures

Jeom Kee Paik、Tomasz Wierzbicki1997-06-01Journal of Ship Research

A benchmark study on several closed-form solutions for the mean crushing strength and the cutting resistance of plated structures during collision or grounding is carried out by comparing theoretical solutions with experimental data. Based on expressions which have been derived for unstiffened structures, an extension…

Metal Forming Simulation TechniquesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Effect of Time of Annealing on Gas Permeation through Coextruded Linear Low-Density Polyethylene (LLDPE) Films

Vicente Compañ、Andreu Andrio、M. Lidón López 等 5 位作者1997-06-01Macromolecules

The effect of annealing on the permeation of oxygen, nitrogen, and carbon dioxide through coextruded linear low-density polyethylene (LLDPE) films is studied. The results indicate that the permeability coefficient P of nitrogen does not show a definite dependence on the time of annealing, t a, whereas for the other ga…

Asphalt Pavement Performance EvaluationPolymer crystallization and propertiesPolymer Foaming and Composites

Conformational polymorphism of oligothiophenes: X‐ray structure of the monoclinic form of 3, 3′, 4″, 3″′‐Tetrakis(methylsulfany‐l)2, 2′:5′, 2″:5″, 2″′‐Quaterthiophene

Giovanna Barbarella、Massimo Zambianchi、Montserrat del Fresno I Marimon 等 5 位作者1997-06-01Advanced Materials

Conformational polymorphism of an oligothiophene the title compound (T4S), is reported for the first time. Efficient synthesis of T4S produced, in addition to the triclinic, deep orange crystals reported previously, a second (yellow, monoclinic) form of T4S, whose structure as revealed by single‐crystal X‐ray diffract…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryOrganic Chemistry Cycloaddition Reactions

Strain‐Dependent Electrical Conduction in the System NiO–CaO

Yoshinobu Nakamura、Hiroshi Ogawa、Tetsuya Nakashima 等 5 位作者1997-06-01Journal of the American Ceramic Society

Strain‐dependent electrical conduction has been observed in the system NiO–CaO. x NiO·(1 ‐ x )CaO solid solutions are fabricated by a traditional solid‐reaction method. When the 0.03NiO·0.97CaO solid solution is annealed at 1000°C, excess NiO is excluded and precipitates on the surface or intergrain layers. When compr…

Ferroelectric and Piezoelectric MaterialsTransition Metal Oxide NanomaterialsElectrical and Thermal Properties of Materials

A new method of developing ultralow-loss glasses

Kazuya Saito、Akira J. Ikushima、T. Ito 等 4 位作者1997-06-01Journal of Applied Physics

A new and effective method for developing ultralow-loss glasses for long-distance optical fiber systems is presented. The idea is based on the observed strong effect of a very small amount of alkaline or alkaline-earth impurities on structural relaxation of “frozen-in” density fluctuations. Efficiency of this method i…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsSemiconductor Lasers and Optical Devices

On a modeling of voltage-application to metallic electrodes using density functional theory

Christophe Bureau、G. Lécayon1997-06-01The Journal of Chemical Physics

With the ultimate purpose of designing molecule/surface interaction potentials for the dynamical study of electropolymerization reactions, a theoretical framework, based on density functional theory (DFT), is proposed to obtain in a self-consistent manner the true electronic density of a metallic surface set under an…

Ionic liquids properties and applicationsConducting polymers and applicationsElectrochemical Analysis and Applications

Fracto-Luminescence of Rare Earth Element-Doped Hexacelsian (BaAl2Si2O8)

Tsuguo Ishihara、Katsuhisa Tanaka、Kazuyuki Hirao 等 4 位作者1997-06-01Japanese Journal of Applied Physics

Luminescence induced by fracture has been observed in rare earth element-doped hexacelsian ( BaAl 2 Si 2 O 8 ). The color of the luminescence varies depending on the kinds of doped rare earth element. Eu 2+ -doped hexacelsian exhibits a luminescence of blue or green color. Sm 2+ - and Sm 3+ -doped hexacelsians exhibit…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Simulation of Electroless Deposition of Cu Thin Films for Very Large Scale Integration Metallization

T. Smy、Lijian Tan、S. K. Dew 等 6 位作者1997-06-01Journal of The Electrochemical Society

Electroless copper deposition has been shown to be a viable technique for the fabrication of very large scale integration (VLSI) interconnections. In particular, electroless deposition was found to be able to fill the high aspect ratio features in submicron VLSI technologies. In this work one‐ and two‐dimensional mode…

Microstructure and mechanical propertiesElectronic Packaging and Soldering TechnologiesCopper Interconnects and Reliability

Anomalous Hall effect in thin films ofPr0.5Sr0.5MnO3

Patrick Wagner、Dumitru Mazilu、Lieven Trappeniers 等 5 位作者1997-06-01Physical review. B, Condensed matter

We report on the type and density of charge carriers obtained from Hall-effect measurements in the three different magnetic phases of ${\mathrm{Pr}}_{0.5}$${\mathrm{Sr}}_{0.5}$${\mathrm{MnO}}_{3}$ . The field dependence of the Hall resistivity has two contributions of opposite sign: one is related to skew scattering a…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsMagnetic Field Sensors Techniques

Physical Modeling of Intumescent Fire Retardant Polymers

Kathryn M. Butler1997-06-01ACS symposium series

Intumescent chemical systems are designed to swell into a thick, robust foam upon exposure to heat, protecting the underlying material from fire by providing a physical barrier to heat and mass transfer. The mechanisms determining the fire-resistant properties of these materials are not well understood. Various approa…

Fire dynamics and safety researchFlame retardant materials and propertiesPickering emulsions and particle stabilization

High repetition rate compact source of nanosecond pulses of 5–100 keV x-ray photons

Ahmed Khacef、R. Viladrosa、C. Cachoncinlle 等 5 位作者1997-06-01Review of Scientific Instruments

A powerful, compact, and repetitive flash x-ray system based on a cable transformer technology powered by ceramic capacitors in a Blumlein-like configuration has been developed. Open circuit voltages in excess of 100 kV can be achieved while commutation occurs at low voltage (&amp;lt;20 kV). The x-ray emission from a…

Laser-Plasma Interactions and DiagnosticsDiamond and Carbon-based Materials ResearchLaser Design and Applications