Materials Literature
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Cu 4 Te 3 substituted (Cu4Te3)x–(Bi0.5Sb1.5Te3)1−x (x=0–0.2) alloys were prepared using spark plasma sintering technique and their thermoelectric properties were evaluated. Measurements show that the alloy with x=0.025 reveals very high electrical conductivity and low lattice thermal conductivity, the Seebeck coeffici…
The electronic structure of ultralow density nanoporous chromia monoliths (aerogels) is studied by soft x-ray absorption near-edge structure (XANES) spectroscopy. These aerogels are prepared by the epoxide sol-gel method. High-resolution O K edge and Cr L2,3 edge XANES spectra of aerogels (before and after thermal ann…
A new inorganic/organic (I/O) nanocomposite (ZnS/NaSCH 2 COONa) with a ribbon-like structure was synthesized by using Zn(NO 3 ) 2 ·7H 2 O and thioglycolic acid as reactants under hydrothermal conditions at 160 °C. SEM, TEM, XRD, XPS, IR and XAFS were used to characterize and analyse the morphology, microstructure and…
The stress dependence of the Raman spectrum of polycrystalline barium titanate (BaTiO3, BT) ceramics has been examined with microprobe polarized Raman spectroscopy. The angular dependence of the Raman spectrum of the tetragonal BT crystal has been theoretically established, enabling us to assess the stress dependence…
We report a detailed study of magnetic and transport properties in perovskite manganites Nd0.55Sr0.45Mn1−xGaxO3 (0.00⩽x⩽0.20). The Ga substitution induces the B-site disorder together with a distinct suppression of the metal-insulator transition and ferromagnetic-paramagnetic transition. Due to an appearance of inhomo…
A method of dual-space molecular-replacement model completion has been proposed which involves the programs ARP/wARP, REFMAC, OASIS and DM. OASIS is used in reciprocal space for phase refinement based on models built by ARP/wARP. For this purpose, the direct-method probability formula of breaking SAD/SIR phase ambigui…
Radiation damage in macromolecular crystals is not suppressed even at 90 K. This is particularly true for covalent bonds involving an anomalous scatterer (such as bromine) at the 'peak wavelength'. It is shown that a series of absorption spectra recorded on a brominated RNA faithfully monitor the extent of cleavage. T…
Mixed ferrite nanoparticles of Ni0.65Zn0.35Fe2O4 using metal nitrates were prepared by three different low temperature methods of sol gel in polyvinyl alcohol matrix, coprecipitation with NaOH as coprecipitating base, and sol gel in citric acid matrix, separately to estimate the influence of synthesis on the structura…
Abstract Fracture behavior of amorphous poly(ethylene terephthalate) (PET) films added multiwalled carbon nanotube (MWCNT) has been compared with that of the PET films added with carbon black (CB) to elucidate the effects of the large aspect ratio of MWCNT. Fracture toughness has been evaluated using the essential wor…
We report on the application of a static (dc) electric field in the plume region during the pulsed Nd doped yttrium aluminum garnet laser deposition (PLD) of tetrahedral amorphous carbon (ta-C) films in vacuum ambient (pressure=10−4–10−3Pa), where the working pressure is exclusively due to ablation vapor. This approac…
Plastic deformation behavior of iPP homopolymer crystallized exclusively in the γ modification was studied. Samples of γ-iPP were obtained by isothermal crystallization under pressure of 200 MPa. Deformation experiments in plane−strain compression were performed in the temperature range of 55−100 °C. Samples of γ-iPP…
The adhesion of wet regenerated cellulose to colloidal complexes formed between carboxymethyl cellulose (CMC) and polyvinylamine (PVAm) was evaluated by measuring the force to delaminate pairs of regenerated cellulose membranes bound together with polyelectrolyte complex. The most important parameter was the surface c…
Erbium (Er)-doped ZnO thin films were grown on fused silica (SiO 2 ) substrates by pulsed electron-beam deposition (PED) and analysed by Rutherford backscattering spectrometry (RBS), ultraviolet–visible absorption, and photoluminescence (PL). Subsequent annealing at 700 °C produces remarkable effects on the optical pr…
Abstract Melt mixed composites based on polyamide 12 (PA12) were prepared using single wall carbon nanotubes (SWNT), which were encapsulated by styrene maleic anhydride copolymer (SMA). The aim was to achieve a reactive coupling between the maleic anhydride functionality of SMA at the surface of the SWNT and the amine…
We present the results of magnetization and AC susceptibility measurements performed on ferrimagnetic Mn(3)(2+)[Cr(III)(CN)(6)](2)·12H(2)O and ferromagnetic Ni(3)(2+)[Cr(III)(CN)(6)](2)·12H(2)O systems under pressures up to 0.9 GPa in a commercial SQUID magnetometer. The magnetization process is affected by pressure:…
ZnO powders were synthesized by a precipitation method and annealed with carbon black. Electron paramagnetic resonance (EPR) and photoluminescence spectroscopies were conducted to study the characteristics of the ZnO powders. The g factor of the EPR signal shifted to lower value for the samples annealed with carbon bl…
The temperature-dependent lifetime of the green emission from Er 3+ ions in 40−50 nm Gd 2 O 3 nanocrystals has been measured and analyzed. The luminescence decay from the 4 S 3/2 state of Er 3+ shows nonexponential characteristics when excited directly to the thermally coupled 2 H 11/2 from 10 to 300 K, indicating ene…
A magnetomechanical model based on continuum thermodynamics is presented which describes the sensing effect in single-crystal ferromagnetic shape memory Ni–Mn–Ga. The model quantifies the stress and magnetization dependence on strain at different values of bias fields under isothermal conditions. A magnetic Gibbs ener…
Rare earth carbonate hydroxides, RE(CO 3 )OH, were hydrothermally synthesized from formic acid and the hydroxide gels of Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Y. An orthorhombic phase with a kozoite-type structure was obtained for RE = Nd and Sm. Another orthorhombic modification of the kozoite-type structure wa…
In this paper we report polyelectrolyte multilayer films containing gold nanoparticles (AuNPs) whose spectroscopic properties can be controlled by post-treatment. When building multilayers from hydrogen-bonded poly(ethylene oxide) and polyacrylic acid-decorated AuNPs, a commonly observed red-shift of the nanoparticles…