Materials Literature
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A series of hyperbranched alternating copolymers were synthesized by either Suzuki or Grignard coupling polycondensation reactions between two AB 4 -type tetrahedral monomers [tetra(4-bromobiphenyl)silane ( 1) and tetra(2-bromo-9,9-dihexylfluorenyl)silane ( 2 )] with AB 2 -type dibromo or diboronic acid monomers of 9,…
Abstract The H3PO4–WO3–Nb2O5 derived catalyst exhibited excellent activity and reusability in the benzylation of anisole at low temperature. On the basis of the XRD and IR data, the oxide derived from heteropoly acid was ascribed to the active and insoluble species in the reaction. It was found that the calcination te…
Uniaxial deformation behavior of PEN films in the rubbery state is investigated as a function of processing temperature, draw rate, and molecular weight ( M w ). Real-time measurement of true stress−true strain and birefringence of the films during the process of stretching is obtained by using a novel instrumented un…
Three rare-earth ternary sulfates NaM(SO 4 ) 2 ·H 2 O (M = La, Nd, and Gd) have been hydrothermally synthesized, and the crystal structures of the three compounds have been solved by single-crystal X-ray diffraction. The lanthanum and neodymium sulfates show the space group P 3 1 21 while the gadolinium compound prese…
In an effort to gain insight into how optical properties of insulating materials are affected by a change in chemical composition, we investigated the dielectric functions of titanium dioxide, TiO(2), and its fluorine-substituted phases, TiOF(2) and TiF(4), by electron energy loss spectroscopy measurements and density…
alpha,alpha-Linked oligopyrroles are attractive precursors for both expanded porphyrin and conducting polymer chemistry. We demonstrate facile methods for synthesizing quater-, penta-, and sexipyrroles from more readily available bi- and terpyrrole intermediates. These products demonstrate stability in their brightly…
The relationship between the structure of both yttrium-stabilized zirconia (YSZ) and ZrO2 catalysts and their ability to activate N2O and O2 is studied by determination of catalytic properties and characterization with TPD, SEM, and XRD. Furthermore, the role of oxygen species formed via dissociation of either O2 or N…
Well-defined amphiphilic cubic silsesquioxane-poly(ethylene oxide) (CSSQ-PEO) was prepared from octakis (dimethylsiloxy)octasilsesquioxane (Q8M8(H)) and allyl-PEO through a hydrosilylation reaction. The structure of CSSQ-PEO was characterized by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy…
A series of fine copolymer particles from 8-aminoquinoline (AQ) and o -phenetidine (PD) were simply synthesized by a chemical oxidative polymerization in three aqueous media. The potential and temperature of polymerization solution were effectively employed to pursue the polymerization progress. The molecular and morp…
Multilayer thin films were constructed on polystyrene colloidal particles by depositing alternating layers of poly(allylamine hydrochloride) (PAH) at pH 7.5 and varying composition blends of poly(acrylic acid) (PAA) and poly(styrenesulfonate) (PSS) at pH 3.5. Following the deposition of each layer, microelectrophoresi…
The coupling model was applied to describe the alpha-relaxation dynamics of each component in perfectly miscible mixtures A(1-x)B(x) of two different glass-formers A and B. An important element of the model is the change of the coupling parameter of each component with the composition, x, of the mixture. However, this…
Two kinds of highly ordered mesoporous silica materials (FDU-11, FDU-13) with novel three-dimensional (3-D) tetragonal and orthorhombic structures were synthesized by using tetra-headgroup rigid bolaform quaternary ammonium surfactant [(CH(3))(3)NCH(2)CH(2)CH(2)N(CH(3))(2)CH(2)(CH(2))(11)OC(6)H(4)C(6)H(4)O(CH(2))(11)C…
Micrometer and submicrometer diameter fibers of recombinant dragline spider silk analogues, synthesized via protein engineering strategies, have been electrospun from 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) and compared with cast films via Raman spectroscopy in order to assess changes in protein conformation that may…
One simple high-temperature solution phase method has been developed to synthesize large-scale, monodisperse, hexgon beta-Cu2S nanoplates. The hexgon nanoplates have edge lengths of 9 +/- 0.5 nm and thicknesses of 4.5 +/- 0.2 nm and self-assemble closely into three-dimensional superlattices. The present results sugges…
High-performance size exclusion chromatography (HPSEC) is a powerful tool for probing the size and size distribution of complex materials. Here we report its application to the analysis of cadmium selenide nanocrystals produced in organic solvents. If nanocrystal-column interactions are minimized, this method provides…
The reaction of three different 1-phenyl and 1,4-diphenyl substituted S-methylisothiosemicarbazides, H(2)[L(1-6)], with Ni(OAc)(2).4H(2)O in ethanol in the presence of air yields six four-coordinate species [Ni(L(1-6)(*))(2)] (1-6) where (L(1-6)(*))(1-) represent the monoanionic pi-radical forms. The crystal structure…
Water-soluble monolayer-protected gold clusters (MPCs) have been an object of investigation by many research groups since their first syntheses were reported in 1998 and 1999. The basic requirements for a ligand to form a monolayer protecting a gold cluster were established some time ago for alkanethiolate MPCs, but t…
Using measurements of the spectra of microwave-frequency resistance oscillations, we determine the phase diagram of magnetic excitations caused by torques from DC spin-polarized currents in (thin permalloy)/copper/(thick permalloy) multilayer samples. We extend the measurements to larger values of current than have be…
By using a flow channel system for modeling the bloodstream in the circulatory system and by locally creating a magnetic field gradient caused by a permanent magnet, we demonstrate specific trapping of polymer capsules simultaneously functionalized with two types of nanoparticles--magnetic and luminescent nanocrystals…
Hybrid organic/inorganic Wells-Dawson polyoxotungstates have been prepared through addition of functionalized tricholorostannanes to lacunary alpha(2)- and alpha(1)-[P(2)W(17)O(61)](10-). Coupling of amines and alcohols to polyoxotungstate platforms led to new structures in good yields. Coupling of chiral amines to th…