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Patterning of Electrospun Fibers Using Electroconductive Templates

Dou Zhang、J. Chang2007-11-05Advanced Materials

Electrospun mats with complex ordered architectures are fabricated by using patterned conductive collectors. The effect of the diameter of the web wires and the protrusions on the formation of the patterns of the fibrous materials are elaborated and woven structures that have been generated by a time-dependent control…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Fabrication of Aligned Fibrous Arrays by Magnetic Electrospinning

Dayong Yang、Bo Lu、Yuyun Zhao 等 4 位作者2007-11-05OpenAlex

Electrospinning magnetic-nanoparticle-doped polymers under the influence of a magnetic field produces aligned arrays of fibers over large areas (see figure). These nanofibers can be transferred onto the surfaces of other substrates. They can also be stacked into multilayer grids.

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsAdvanced Sensor and Energy Harvesting Materials

Metallopolymers: New Multifunctional Materials

George R. Whittell、Ian Manners2007-11-05OpenAlex

Abstract Since the mid 1990s soluble, well‐characterized high molecular weight metal‐containing and metallosupramolecular polymers have become readily available for the first time, even in some cases, with narrow molecular weight distributions and controlled architectures such as block copolymers. This has led to a ra…

Organometallic Complex Synthesis and CatalysisConducting polymers and applicationsSynthesis and properties of polymers

Improving mechanical performance of injection molded PLA by controlling crystallinity

A.M.P. Harris、Ellen C. Lee2007-11-05OpenAlex

Abstract Currently, use of poly(lactic acid) (PLA) for injection molded articles is limited for commercial applications because PLA has a slow crystallization rate when compared with many other thermoplastics as well as standard injection molding cycle times. The overall crystallization rate and final crystallinity of…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisPolymer crystallization and properties

Diffuse wave density and directionality in anisotropic solids

Andrew N. Norris2007-11-04arXiv

Several general results are derived for diffuse waves in anisotropic solids, including concise expressions for the modal density per unit volume and for the participation factor matrix G. The latter is a second order tensor which describes the orientational distribution of diffuse wave or reverberant energy, and reduc…

Materials Science

Radiative Recombination Spectra of Heavily p-Type delta-Doped Gaas/Alas MQWs

J. Kundrotas、A. Cerskus、G. Valusis 等 7 位作者2007-11-04arXiv

We present a study of the photoluminescence (PL) properties of heavily Be delta-doped GaAs/AlAs multiple quantum wells measured at room and liquid nitrogen temperatures. Possible mechanisms for photocarriers recombination are discussed, with a particular focus on the peculiarities of the excitonic and free carriers-ac…

Materials Science

Assessment of ecological status in U.K. rivers using diatoms

Martyn Kelly、Steve Juggins、Robin Guthrie 等 8 位作者2007-11-04OpenAlex

Summary 1. The European Union's Water Framework Directive requires all water bodies to achieve ‘good ecological status’ by 2015 and this paper describes a rationale for defining ‘good ecological status’ based on diatoms, a significant component of the biological quality element ‘macrophyte and phytobenthos’. 2. A data…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Carbon Nanomaterial Synthesis from Sucrose Solution without Using Graphite Electrodes

Shinya Aikawa、Takio Kizu、Eiichi Nishikawa 等 4 位作者2007-11-03Chemistry Letters

Abstract Carbon nanomaterials such as carbon nanotubes (CNTs) and carbon nanospheres (CNS) were synthesized from sucrose solution using an arc discharge method without graphite electrodes. In this process, the nanocarbon products were formed from carbon atoms supplied by the sucrose in solution rather than from the gr…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsPorphyrin and Phthalocyanine Chemistry

Rapid and Deep Nitridation of Silica MCM-41 without Loss of Hexagonal Pore Structure

Ken‐ichi Ishizu、Fumitaka Hayashi、Masakazu Iwamoto2007-11-03Chemistry Letters

Abstract The nitridation of mesoporous silica MCM-41 with ammonia was carried out by using a plug flow-type reactor. The degree of nitridation was dependent on the amount of NH3 supplied. Mesoporous silicon oxynitride containing 34 wt % of nitrogen could be prepared at 1273 K for 8 h, and the hexagonal mesoporous stru…

Ammonia Synthesis and Nitrogen ReductionMesoporous Materials and CatalysisCatalytic Processes in Materials Science

Self-assembly and Solvatochromic Fiber Formation of 4,5-Bis(dodecylthio)tetrathiafulvalene-4′-carboxylic Acid and Its Derivatives

Hideo Enozawa、Youhei Honna、Masahiko Iyoda2007-11-03Chemistry Letters

Abstract TTF-carboxylic acid 2 exhibits gelling ability for hexane and cyclohexane to form an orange fibrous material and shows solvatochromism both in solution and in the fiber formation to produce a reddish-purple fibrous material from acetonitrile. Moreover, the corresponding ester 1 forms yellow fibers from aceton…

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchMagnetism in coordination complexes

A Squaraine-based Near-infrared Dye with Bright Fluorescence and Solvatochromic Property

Keitaro Umezawa、Daniel Citterio、Koji Suzuki2007-11-03Chemistry Letters

Abstract We report a newly synthesized squaraine-based fluorescent dye (KSQ-2) with excellent and useful optical characteristics such as a sharp near-infrared (NIR) emission at 751 nm, an extremely high fluorescence quantum yield (φ=0.56 in cyclohexane), and linear positive solvatochromic properties in the spectral re…

Photochemistry and Electron Transfer StudiesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Sizing up the Exciton in Complex-Shaped Semiconductor Nanocrystals

Jeongho Kim、P. Sreekumari Nair、C. Wong 等 4 位作者2007-11-03Nano Letters

We report a spectroscopic study of how nanocrystal shape influences exciton size. The effective exciton size in complex-shaped nanocrystals is examined by comparing exciton fine structure relaxation rates, measured by the ultrafast polarization transient grating method, to an extensive empirical calibration curve that…

Quantum Dots Synthesis And PropertiesSemiconductor Quantum Structures and DevicesChalcogenide Semiconductor Thin Films

Synthesis of BaTiO3 Nanowires at Low Temperature

Changlong Jiang、Kiyofumi Katagiri、Yifeng Wang 等 4 位作者2007-11-03Crystal Growth & Design

In this paper, we report the facile synthesis of single-crystalline BaTiO 3 nanowires at low temperature (50 °C) in ethanol solution by using inorganic raw materials. The nanowires have a uniform diameter of 100 nm and a length up to 10 μm. X-ray diffraction patterns confirmed that it is the tetragonal phase of BaTiO…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesTransition Metal Oxide Nanomaterials

Novel Fluorescein Hierarchical Structures Fabricated by Recrystallization under Control of Polyelectrolytes

Tie-Kai Zhang、Jianhua Zhu、Hong‐Bin Yao 等 4 位作者2007-11-03Crystal Growth & Design

Complex porous fluorescein microspheres with hierarchical superstructures and relievo-like complex fluorescein crystals can be easily generated by a recrystallization/reprecipitation method using poly(allylamine hydrochloride) (PAH) and poly(sodium 4-styrenesulfonate) (PSS) as structure directing agents at room temper…

Polymer Surface Interaction StudiesLuminescence and Fluorescent MaterialsAdvanced Sensor and Energy Harvesting Materials

Preparation of Monodispersed Eu3+:CaMoO4 Nanocrystals with Single Quasihexagon

Sheng Yu、Zhoubin Lin、Lizhen Zhang 等 4 位作者2007-11-03Crystal Growth & Design

This paper reports the preparation of Eu 3+:CaMoO 4 nanocrystals by the microemulsion-mediated hydrothermal method. The synthesized Eu 3+:CaMoO 4 nanocrystals were characterized by XRD, transmission electron microscopy, high-resolution transmission electron microscopy, excitation, and emission spectra. The result show…

Catalytic Processes in Materials ScienceQuantum Dots Synthesis And PropertiesLuminescence Properties of Advanced Materials

Layer-by-Layer Assembly of Bioengineered Flagella Protein Nanotubes

Mudalige Thilak Kumara、Brian C. Tripp、Subra Muralidharan2007-11-03Biomacromolecules

Flagella nanotubes present on the surface of E. coli bacteria were bioengineered to display arginine-lysine and glutamic acid-aspartic acid peptide loops. These protein bionanotubes were demonstrated to self-assemble, layer-by-layer, by atomic force microscopy (AFM) on gold-coated mica and quartz surfaces. Flagella wi…

Advanced biosensing and bioanalysis techniquesMolecular Junctions and NanostructuresPolymer Surface Interaction Studies

Controllable Synthesis of PbO Nano/Microstructures Using a Porous Alumina Template

Qiang Wang、Xun Sun、Shengjun Luo 等 7 位作者2007-11-03Crystal Growth & Design

Porous anodic aluminum oxide (AAO) templates were prepared by a two-step aluminum anodic oxidation process. Nanowires, microspheres, and hexagonal nanoplates of PbO were successfully prepared by an improved sol–gel method combined with AAO templates. On the anodized external surface and the surface-dissolved barrier l…

ZnO doping and propertiesAnodic Oxide Films and NanostructuresAdvanced Photocatalysis Techniques

Germania Nanoparticles and Nanocrystals at Room Temperature in Water and Aqueous Lysine Sols

Tracy M. Davis、Mark A. Snyder、Michael Tsapatsis2007-11-03Langmuir

Facile synthesis of nanometer-sized germania crystals and amorphous germania nanoparticles (ca. 1 nm) is investigated through hydrolysis of germanium tetraethoxide and subsequent condensation of germania in both pure water and aqueous lysine solutions. Germanium tetraethoxide rapidly hydrolyzes in pure water, leading…

Diatoms and Algae ResearchPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Evaluation and Modeling Runaway Reaction of Methyl Ethyl Ketone Peroxide Mixed with Nitric Acid

Jo‐Ming Tseng、Chi‐Min Shu、Jai Prakash Gupta 等 4 位作者2007-11-03Industrial & Engineering Chemistry Research

The thermal stability of solutions of methyl ethyl ketone peroxide (MEKPO) dissolved in dimethyl phthalate (DMP), in the presence of nitric acid (HNO 3 ) and sodium nitrate (NaNO 3 ) as contaminants, was studied. MEKPO is extensively employed in the chemical industries, but despite its large use several severe acciden…

Energetic Materials and CombustionChemistry and Chemical EngineeringThermal and Kinetic Analysis

PhaP Is Involved in the Formation of a Network on the Surface of Polyhydroxyalkanoate Inclusions in Cupriavidus necator H16

Douglas Dennis、Vicki Sein、Edgar Martinez 等 4 位作者2007-11-03Journal of Bacteriology

Polyhydroxyalkanoate (PHA) inclusions are polymeric storage inclusions formed in some bacterial species when carbon levels are high but levels of another essential nutrient, such as nitrogen, are low. Though much is known about PHA synthesis, little is known about inclusion structure. In this study, atomic force micro…

Microplastics and Plastic PollutionGraphene and Nanomaterials Applicationsbiodegradable polymer synthesis and properties