Materials Literature
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Reductive coupling of adventitious CO2 by CuI has afforded the title compound, μ-oxalato-1κ2O1,O2:2κ2O1′,O2′-bis[bis(1-benzyl-1H-pyrazole-κN2)(trifluoromethanesulfonato-κO)copper(II)], [Cu2(CF3O3S)2(C2O4)(C10H10N2)4], which contains centrosymmetric molecules in which the CuII ions, bridged by a planar oxalate lig…
Glass substrates modified with 3‐mercaptopropyltrimethoxysilane (MPS) were used to deposit CdS thin films in the process of successive ionic layer adsorption and reaction (SILAR). The films were characterized by X‐ray diffraction, optical absorption, and atomic force microscopy (AFM). AFM showed that the modified subs…
The crystallization of amorphous NiTi thin films was studied using in situ transmission electron microscopy (TEM) methods. Samples were subjected to heating conditions within the microscope and the microstructural development was monitored and recorded. The nucleation rate and the growth rate were determined experimen…
We have fabricated CoNiFeGa single crystals with excellent superelasticity. The superelastic strains of 4% and 6.7% in compression have been obtained along the [001] and [110] directions, respectively. These single crystals show strong anisotropy in strains, superelastic parameters, and even transformation path relate…
The structure and electronic properties of vanadium oxide nanotubes have been studied using optical, photoemission, and electron energy-loss spectroscopies. Electron diffraction indicates the tubular structure with an interlayer distance of about $26.1\phantom{\rule{0.3em}{0ex}}\mathrm{\AA{}}$. Photoemission spectrosc…
Theoretical and experimental studies on the two-photon photoemission excited by femtosecond laser pulses from the $sp$-band of Ag(111) in normal direction are reported. At low temperatures, the two-photon photoemission spectrum is found to consist mainly of nonresonant direct transitions from the lower to the upper $s…
Chemically modified biomaterial surfaces (titanium and glass) covered with polyelectrolyte self-assembled films formed by the alternating adsorption of cationic poly-L-lysine (PLL) and anionic poly-L-glutamic acid (PGA) were structurally characterized by atomic force microscopy. Complementary information concerning th…
The dielectric and electrical properties of a BaTi4O9 film were investigated in order to evaluate its potential use in metal-insulator-metal (MIM) capacitors for rf/mixed signal integrated circuits. A high capacitance density of 4.62fF∕μm2 along with a low tanδ of 0.0025 were obtained at 100 kHz. A high capacitance de…
Abstract We consider the influence of a local, or effective, composition on dynamics in the miscible polymer blend PEO/PMMA. Quasielastic neutron scattering in combination with deuterium labeling is employed to determine characteristic relaxation times of the PEO component over spatial scales from 3 to 10 Å. Informati…
The adsorption of atoms and molecules of several gases of the Si(100)2x1 silicon reconstructed surface is investigated by surface differential reflectance spectroscopy. This UV-visible optical spectroscopy makes possible the discrimination between two adsorption modes, depending on whether or not the adsorption leads…
The magnetoresistance of high-quality epitaxial doped ZnO(:Ga) thin films with various electron concentrations ranging from 3.2×1018 to 1.3×1020cm−3 has been measured. All samples investigated exhibit a negative magnetoresistance at low magnetic fields. Its magnitude systematically depends on carrier concentration and…
Structural perfection up to the fifth generation of a polyphenylene dendrimer has been achieved by inserting p-terphenyl spacers into the arms of each branching unit (see picture). The stiff, monodisperse macromolecules with diameters up to 22 nm were synthesized in a stepwise manner, during which the topology of the…
Reciprocity between the power scattered by nested metamaterial shells and the power radiated by an antenna centered within those nested shells has been investigated. Resonant scattering caused by an incident, fundamental transverse-magnetic mode was found to be reciprocal to the power resonantly radiated by an electri…
Calcium metabolism in oysters is a very complicated and highly controlled physiological and biochemical process. However, the regulation of calcium metabolism in oyster is poorly understood. Our previous study showed that calmodulin (CaM) seemed to play a regulatory role in the process of oyster calcium metabolism. In…
When provoked, Notaden bennetti frogs secrete an exudate which rapidly forms a tacky elastic solid ("frog glue"). This protein-based material acts as a promiscuous pressure-sensitive adhesive that functions even in wet conditions. We conducted macroscopic tests in air to assess the tensile strength of moist glue (up t…
Surface doping of oxide nanoparticles is important in fields ranging from heterogeneous catalysis to optoelectronics. Here, we report the solvent-free synthesis of mixed calcium-magnesium oxide nanocrystals in the size range between 5 and 40 nm. Although CaMgO mixtures are thermodynamically forbidden on a macroscopic…
Single-walled carbon nanotubes (SWNTs) were successfully grown on SiO 2 /Si substrates at 450 °C by remote plasma enhanced chemical vapor deposition with a plasma power of 15 W. The ratio of D-band (disorder-induced mode) to G-band (tangential stretching mode) in the Raman spectra, an indicator of nanotube quality, is…
Characterization of a Zn0.7Mg0.3O∕ZnO heterostructure field-effect transistor (HFET) is reported. The HFET was based on a Zn0.7Mg0.3O∕ZnO∕Zn0.7Mg0.3O single quantum well (SQW) grown on an a-plane sapphire substrate by molecular-beam epitaxy, and was fabricated by a conventional photolithography technique combined with…
The electronic structure of monodispersed, hydrogen-passivated diamond clusters (diamondoids) in the gas phase has been studied with x-ray absorption spectroscopy. The data show that the bulk-related unoccupied states do not exhibit any quantum confinement. Additionally, density of states below the bulk absorption edg…
The adsorption of a biologically important glycoprotein, mucin, and mucin-chitosan complex layer formation on negatively charged surfaces, silica and mica, have been investigated employing ellipsometry, the interferometric surface apparatus, and atomic force microscopy techniques. Particular attention has been paid to…