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Synthesis and Properties of Liquid-Crystalline Semi-Rigid Polyesters Based on Isophthalates of Nitro- or Methoxyazobenzene and Dioxydiundecanols of Biphenyl or 2,5-Diphenyl-1,3,4-Thiadiazole

Moriyuki Sato、Miyuki Mizoi、Yuko Uemoto2001-12-01Macromolecular Chemistry and Physics

Semi-rigid polyesters having nitro- or methoxyazobenzene unit in the side chain and calamitic mesogen (biphenyl or 2,5-diphenyl-1,3,4-thiadiazole unit) in the main chain were prepared by melt polycondensation of diethyl isophthalates composed of the azobenzene units with three dioxydiundecanol derivatives of the mesog…

Liquid Crystal Research AdvancementsEpoxy Resin Curing ProcessesSynthesis and properties of polymers

O–Cu(001) II: VLEED QUANTIFICATION OF THE FOUR-STAGE Cu 3 O 2 BONDING KINETICS

Chang Q. Sun2001-12-01Surface Review and Letters

Further to the previous part [Surf. Rev. Lett.8(3/4), 367 (2001)], this part deals with VLEED numerical quantification of the Cu 3 O 2 bond-forming kinetics on the Cu(001) surface. Besides the solution-number certainty that has been ensured, the modeling exercises have enabled the full capacity of VLEED to be explored…

Semiconductor materials and devicesCopper Interconnects and ReliabilityCopper-based nanomaterials and applications

Effects of dendritic arm coarsening on macroscopic modelling of solidification of binary alloys

Subhadeep Chakraborty、Pradip Dutta2001-12-01Materials Science and Technology

A pure macroscopic two-dimensional numerical model has been developed, capable of capturing the effects of dendritic arm coarsening on the transport phenomena occurring during a binary alloy solidification process. The general continuum conservation equations are aptly modified to take into account shrinkage induced f…

Aluminum Alloy Microstructure PropertiesPhase Change Materials ResearchSolidification and crystal growth phenomena

Carrier Injection/Transport Characteristics of Photochromic Diarylethene Film

Akira Taniguchi、Tsuyoshi Tsujioka、Yuji Hamada 等 5 位作者2001-12-01Japanese Journal of Applied Physics

Photochromic diarylethenes with electric carrier (hole) controlling ability for nondestructive readout were investigated. The ionization potential of the photostationary colored diarylethene films was around 5.7–5.8 eV, irrespective of differences in their molecular structures. Good hole injection/transport characteri…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Real Structure of LiB3O5 (LBO) Crystals Grown in Li2O-B2O3-MoO3 System

Ninel A. Pylneva、V. I. Kosyakov、A. M. Yurkin 等 8 位作者2001-12-01Crystal Research and Technology

The liquidus surface structure and field of LiB3O5 (LBO) primary crystallization have been revealed in Li2O-B2O3 -MoO3 ternary system. The optimization of charge composition and growth conditions results in large volume optical quality LBO single crystals yielding. Crystallographic properties and real defect structure…

Crystal Structures and PropertiesX-ray Diffraction in Crystallography

Achievements and research tasks for poly(vinyl chloride) aging and stabilization

K.S. Minsker、Г. Е. Заиков2001-12-01Journal of Vinyl and Additive Technology

Abstract Perspectives for the manufacture of PVC that does not contain liable groups in the backbone are considered. If achieved, such manufacture will provide a drastic increase in the intrinsic stability of the polymeric products, the possibility of processing PVC with minimal contents or in the total absence of sta…

Thermal and Kinetic AnalysisPolymer Science and PVCPolymer Synthesis and Characterization

Current switching of resistive states in normal-metal-manganite single-crystal point contacts

N. A. Tulina、S.A. Zver’kov、Y. M. Mukovskii 等 4 位作者2001-12-01Europhysics Letters (EPL)

Resistive properties of point contacts in normal-metal-manganite heterojunctions have been investigated on the base of La 0.7 Sr 0.3 MnO 3 , La 0.8 Sr 0.2 MnO 3 , La 0.8 Ca 0.2 MnO 3 single crystals. At considerable current levels the current-voltage characteristics of point contacts exhibit features in the form of re…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsElectronic and Structural Properties of Oxides

Enthalpies of Chromium Oxide Solution in Soda Lime Borosilicate Glass Systems

C.H. Kim、Kwansik Choi、Jong‐Kil Park 等 5 位作者2001-12-01Journal of the American Ceramic Society

Chromium oxide (Cr 2 O 3 ) solubility was measured in soda lime borosilicate glass from 1400 to 1500 K. The temperature dependence of the solubility increased with increased sodium oxide concentration. The enthalpies of solution for the equilibrium phases were calculated from the solubility data in the temperature ran…

Glass properties and applicationsPigment Synthesis and PropertiesMineralogy and Gemology Studies

Calorimetric and Dielectric Study of the Segmented Biodegradable Poly(ester-urethane)s Based on Bacterial Poly[(R)-3-hydroxybutyrate]

Gamal R. Saad2001-12-01Macromolecular Bioscience

Two series of segmented poly(ester-urethane)s were synthesized from bacterial poly[(R)-3-hydroxybutyrate]-diol (PHB-diol), as hard segments, and either poly(ε-caprolactone)-diol (PCL-diol) or poly(butylene adipate)-diol (PBA-diol), as soft segments, using 1,6-hexamethylene diisocyanate as a chain extender. The hard-se…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolymer composites and self-healing

HIGH VOLUME/HIGH SPEED ASPHALT ROADWAY PREVENTIVE MAINTENANCE SURFACE TREATMENTS

M J Wade、R DeSombre、D G Peshkin2001-12-01OpenAlex

The South Dakota Department of Transportation (SDDOT) has made extensive use of chip seal and sand seal surface treatments in the maintenance of their asphaltic concrete (AC) pavements. Such surface treatments have been found to provide a cost-effective means of extending the life of AC pavements in South Dakota. Alth…

Asphalt Pavement Performance EvaluationEngineering and Material Science ResearchTransportation Safety and Impact Analysis

Effects of Activator Ion Concentration on the Upconversion Processes in Er3+-Doped TeO2-ZnO Glass

A. Kanoun、Nejeh Jaba、H. Mejri 等 5 位作者2001-12-01physica status solidi (a)

Photoluminescence properties of Er3+-doped 70TeO2–30ZnO glasses are investigated. Infrared to visible upconversion has been observed at room temperature in this tellurite glass using a 797 nm excitation laser. A study of the 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2 transitions versus excitation laser power shows evidence for…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsOptical properties and cooling technologies in crystalline materials

A REVIEW OF FUNGAL INFLUENCED CORROSION

Brenda J. Little、Richard I. Ray2001-12-01Corrosion Reviews

Fungal influenced corrosion is reviewed for carbon steel and aluminum fuel tanks; carbon steel cables; and painted and unpainted ship holds containing wet and dry cargos, including wood, molasses, fatty oils and cereal. Deterioration of fiber-reinforced composites and glass has also been attributed to fungal species.

Corrosion Behavior and InhibitionBuilding materials and conservationMarine Biology and Environmental Chemistry

Docetaxel : Solid state characterization by X-ray powder diffraction and thermogravimetry

L. Zaske、M.-A. Perrin、F. Leveiller2001-12-01Journal de Physique IV (Proceedings)

Docetaxel, a stoichiometric hydrate containing three water molecules per molecule of drug substance, is thermodynamically stable under ambient conditions of pressure, temperature and relative humidity. Dehydration of this form was subjected to X-ray powder diffraction (XRPD) and thermogravimetric experiments. To obtai…

Crystallography and molecular interactionsThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Coarsening of Lamellar Microstructures in Directionally Solidified Yttrium Aluminate/Alumina Eutectic Fiber

D.-Y. Park、Jenn‐Ming Yang、Joseph M. Collins2001-12-01Journal of the American Ceramic Society

Coarsening of the fine lamellar structure of a directionally solidified Y 3 Al 5 O 12 (yttrium aluminum garnet, YAG)/Al 2 O 3 eutectic fiber at elevated temperatures was investigated. The fibers were grown continuously by an edge‐defined film‐fed growth (EFG) technique. To study the thermal stability of the lamellar s…

Advanced ceramic materials synthesisHigh-Temperature Coating BehaviorsMetallic Glasses and Amorphous Alloys

Spontaneous strain in synthetic titanite, CaTiOSiO4

Thomas Malcherek2001-12-01Mineralogical Magazine

Abstract Lattice parameters of synthetic titanite powder, CaTiOSiO 4 , have been determined between room temperature and 1023 K. Only the e 11 and e 13 components contribute significantly to the strain tensor associated with the antiferroelectric-paraelectric phase transition at T c = 487 K. A finite strain component…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsSolid-state spectroscopy and crystallography

Surface Conditioning of Nickel–titanium Alloy Stents for Improving Biocompatibility

Hui Zhao、J. Van Humbeeck、Ivan De Scheerder2001-12-01Surface Engineering

It has been shown that the surface quality of cardiovascular stents has a significant influence on the biocompatibility. In particular, a smooth surface is required. The major objective of the present study is to explore the optimal methods for polishing NiTi stents. Electrochemical polishing was mainly explored, in w…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsAdvanced Machining and Optimization Techniques

5,15-Diaryl-β-substituted-porphyrinato-manganese(III) chlorides as probes for structure–activity relationships in porphyrin-based epoxidation catalysts

A.J.F.N. Sobral、Α. Μ. d’A. Rocha Gonsalves2001-12-01Journal of Porphyrins and Phthalocyanines

Manganese complexes of 5,15-diaryl-β-substituted-porphyrins were prepared and their behaviour as oxidation catalysts was studied. The role of the pyrrolic and meso-substituents on the activity and selectivity of these catalysts was studied to reveal new structure–activity relationships in these porphyrin-based epoxida…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Fatigue behavior of textile composite materials subjected to tension‐tension loads

Yasser Gowayed、Hong Fan2001-12-01Polymer Composites

Abstract A model was constructed to evaluate the fatigue behavior of textile composite materials under tension‐tension loads. First, traditional FEA was used to evaluate the stiffness reduction and energy release rate due to crack propagation. Results obtained from this study were coupled with data on strength degrada…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesTextile materials and evaluations

Kinetics of the reactions of ethylene oxide with water and ethylene glycols

G. A. Melhem、Arturo Gianetto、M.E. Levin 等 7 位作者2001-12-01Process Safety Progress

Abstract This study of the water‐contamination reactions of ethylene oxide was conducted by Arthur D. Little, Inc. with funding from, and under the auspices of, the Ethylene Oxide Industry Council, part of the American Chemistry Council. Significant experimental and technical contributions were also made by staff from…

Petroleum Processing and AnalysisCatalysis and Oxidation ReactionsThermal and Kinetic Analysis

Textural and structural modifications of saponite from Cerro del Aguila by acid treatment

M. Suárez Barrios、Cristina de Santiago Buey、Emilia García Romero 等 4 位作者2001-12-01Clay Minerals

Abstract The physicochemical properties of clays can be modified by acid treatment with inorganic acids. This treatment is usually referred to as ‘acid activation’, because it increases the specific surface area and the number of active sites of the solids. In the present study, the acid activation of saponite from Ce…

Soil and Unsaturated FlowClay minerals and soil interactionsTherapeutic Uses of Natural Elements