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The relationship between structure and activity of MoO3–CeO2 catalysts for NO removal: influences of acidity and reducibility

Yue Peng、Ruiyang Qu、Xueying Zhang 等 4 位作者2013-01-01Chemical Communications

The SCR activities of MoO3-CeO2 catalysts are enhanced by both Lewis and Brønsted acidities provided by surface cerium atoms and amorphous MoO3 structures, respectively, but are suppressed by stable adsorbed nitrate or nitrite species on the defect sites of CeO2.

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

From tetraphenylethene to tetranaphthylethene: structural evolution in AIE luminogen continues

Jian Zhou、Zhengfeng Chang、Yibin Jiang 等 12 位作者2013-01-01Chemical Communications

Replacement of phenyl ring(s) in tetraphenylethene by naphthalene ring(s) generates a series of new luminogens with aggregation-induced emission (AIE) characteristics, demonstrating that bulky naphthalene rings can serve as a rotor to construct AIE luminogens.

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Development of Nanostructured Tungsten Based Materials Resistant to Recrystallization and/or Radiation Induced Embrittlement

Hiroaki Kurishita、H. Arakawa、S. Matsuo 等 17 位作者2013-01-01MATERIALS TRANSACTIONS

Mitigation of embrittlement caused by recrystallization and radiation is the key issue of tungsten (W) based materials for use in the advanced nuclear system such as fusion reactor applications. In this paper, our nanostructured W materials development performed so far to solve the key issue is reviewed, including new…

Fusion materials and technologiesNuclear Materials and PropertiesAdvanced materials and composites

Disulfide crosslinked PEGylated starch micelles as efficient intracellular drug delivery platforms

Aiping Zhang、Zhe Zhang、Fenghua Shi 等 9 位作者2013-01-01Soft Matter

Novel reduction-responsive disulfide core-crosslinked micelles based on amphiphilic starch-graft-poly(ethylene glycol) (starch-g-PEG) were prepared and used for efficient intracellular drug delivery. The starch-g-PEG copolymers can be conveniently prepared by grafting starch with carboxyl group terminated PEG, and sub…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

Facile synthesis of Ti4+-immobilized Fe3O4@polydopamine core–shell microspheres for highly selective enrichment of phosphopeptides

Yinghua Yan、Zhifang Zheng、Chunhui Deng 等 5 位作者2013-01-01Chemical Communications

In this work, for the first time, Ti(4+)-Fe3O4@polydopamine microspheres were designed and synthesized for efficient and selective enrichment of phosphopeptides in biological samples.

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPolymer Surface Interaction Studies

Superoleophilic and superhydrophobic biodegradable material with porous structures for oil absorption and oil–water separation

Zhongxin Xue、Zhongxue Sun、Yingze Cao 等 9 位作者2013-01-01RSC Advances

In this work, novel biodegradable poly(lactic acid) oil absorption and filtration materials with superhydrophobic and superoleophilic properties were successfully fabricated. The as-prepared materials can separate oil from oil–water mixtures with high selectivity, high separation efficiency, stable performance, and ea…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Core-shell Fibers for Biomedical Applications-A Review

Md. Fazley Elahi、Lu Wang2013-01-01Journal of Bioengineering and Biomedical Sciences

Now is the age of high-tech research and development. Different types of fibers have been produced in the last decades for the benefit of human needs. Core-shell nanofibers are a revolutionary development in the field of science and technology. Preparation of nanoscale fibers in a core-shell configuration, using two d…

Electrospun Nanofibers in Biomedical Applications

Dendrimers and their Applications as Novel Drug Delivery Carriers

作者信息未提供2013-01-01Journal of Applied Pharmaceutical Science

Dendrimers are novel synthetic polymeric systems having improved physical and chemical properties due to their unique three dimensional architecture. Dendrimers have a well defined size, shape, molecular weight and monodispersity. These are compatible with drug moieties as well as bioactive molecules like DNA, heparin…

RNA Interference and Gene DeliveryDendrimers and Hyperbranched PolymersSynthesis and Characterization of Heterocyclic Compounds

Self-healing metallopolymers based on cadmium bis(terpyridine) complex containing polymer networks

Stefan Bode、Ranjita K. Bose、S. Matthes 等 17 位作者2013-01-01Polymer Chemistry

The utilization of metal–ligand interactions within polymers generates materials which are of interest for several applications, including self-healing materials. In this work we use methacrylate copolymers containing terpyridine moieties in the side chain for the formation of self-healing metallopolymer networks. The…

Advanced Polymer Synthesis and CharacterizationFuel Cells and Related MaterialsPolymer composites and self-healing

Folic acid-functionalized mesoporous silica nanospheres hybridized with AIE luminogens for targeted cancer cell imaging

Zilong Wang、Bin Xu、Lei Zhang 等 8 位作者2013-01-01Nanoscale

Fluorescent nanoparticles (FNPs) have been found to be useful as visualization tools for biological sensing, probing, imaging, and monitoring. Applied to targeted cancer cell imaging, FNPs are highly desirable for early stage cancer diagnosis and treatment. However, the light emission from most of the FNPs reported is…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

A bioprobe based on aggregation induced emission (AIE) for cell membrane tracking

Yuhao Li、Yongquan Wu、Jin Chang 等 6 位作者2013-01-01Chemical Communications

A new organic dye (FD-9) derived from 1,8-naphthalimide is synthesized and shows significant aggregation induced emission (AIE) characteristics. The FD-9 dye presents excellent photostability and low toxicity, which can specifically track a cell membrane for 4 days.

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

From adhesion to wetting of a soft particle

Thomas Salez、Michael Benzaquen、Élie Raphaël2013-01-01Soft Matter

Using a thermodynamical approach, we calculate the deformation of a spherical elastic particle placed on a rigid substrate, under zero external load, and including an ingredient of importance in soft matter: the interfacial tension of the cap. In a first part, we limit the study to small deformation. In contrast with…

Material Dynamics and PropertiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

The Mechanics of a Chain or Ring of Spherical Magnets

Cameron L. Hall、Dominic Vella、Alain Goriely2013-01-01SIAM Journal on Applied Mathematics

Strong magnets, such as neodymium-iron-boron magnets, are increasingly being manufactured as spheres. Because of their dipolar characters, these spheres can easily be arranged into long chains that exhibit mechanical properties reminiscent of elastic strings or rods. While simple formulations exist for the energy of a…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Near-field electrospinning of light-emitting conjugated polymer nanofibers

Daniela Di Camillo、Vito Fasano、Fabrizio Ruggieri 等 7 位作者2013-01-01Nanoscale

The authors report on the realization of ordered arrays of light-emitting conjugated polymer nanofibers by near-field electrospinning. The fibers, made from poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene], have diameters of a few hundreds of nanometers and their emission peaked at 560 nm. The observed blue-s…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

A first-principles investigation of the thermodynamic and mechanical properties of Ni–Ti–Sn Heusler and half-Heusler materials

P. Hermet、K. Niedziolka、P. Jund2013-01-01RSC Advances

First principles calculations of the vibrational, thermodynamic and mechanical properties of the Ni–Ti–Sn Heusler and half-Heusler compounds have been performed. First, we have calculated the Raman and infrared spectra of NiTiSn, providing benchmark theoretical data directly useful for the assignments of its experimen…

Intermetallics and Advanced Alloy PropertiesMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Properties of spatial arrangement of V-type defects in irradiated materials: 3D-modelling

Харченко、Dmitrii O. Kharchenko2013-01-01Condensed Matter Physics

We consider the dynamics of pattern formation in a system of point defects under sustained irradiation within the framework of the rate theory. In our study we generalize the standard approach taking into account a production of defects by elastic fields and a stochastic production representing internal multiplicative…

Microstructure and mechanical propertiesSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Approaches to modelling irradiation-induced processes in transmission electron microscopy

Stephen T. Skowron、Irina V. Lebedeva、А. М. Попов 等 4 位作者2013-01-01Nanoscale

The recent progress in high-resolution transmission electron microscopy (HRTEM) has given rise to the possibility of in situ observations of nanostructure transformations and chemical reactions induced by electron irradiation. In this article we briefly summarise experimental observations and discuss in detail atomist…

Carbon Nanotubes in CompositesAdvanced Electron Microscopy Techniques and ApplicationsFullerene Chemistry and Applications

Chemical capacitance proposed for manganite-based ceramics

A. Molak2013-01-01Condensed Matter Physics

The measured value of effective electric permittivity eff of several compounds, e.g., (BiNa)(MnNb)O 3 , (BiPb)(MnNb)O 3 , and BiMnO 3 increases from a value 10 100 at the low temperature range (100 300 K) up to the high value reaching the value 10 5 at high temperature range, e.g., 500 800 K. Such features suggest the…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Phase transformation B1 to B2 in TiC, TiN, ZrC and ZrN under pressure

Ivashchenko、Turchi、Shevchenko2013-01-01Condensed Matter Physics

Phase stability of various phases of MX (M = Ti, Zr; X = C, N) at equilibrium and under pressure is examined based on first-principles calculations of the electronic and phonon structures. The results reveal that all B1 (NaCltype) MX structures undergo a phase transition to the B2-structures under high pressure in agr…

Metal and Thin Film MechanicsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Dielectric properties of PLZT-x/65/35 (2≤x≤13) under mechanical stress, electric field and temperature loading

Pytel、J. Suchanicz、Livinsh 等 4 位作者2013-01-01Condensed Matter Physics

We investigated the effect of uniaxial pressure (0 1000 bars) applied parallely to the ac electric field on dielectric properties of PLZT-x/65/35 (2 x 13) ceramics. There was revealed a significant effect of the external stress on these properties. The application of uniaxial pressure leads to the change of the peak i…

Ferroelectric and Piezoelectric MaterialsSolid-state spectroscopy and crystallographyGeophysics and Sensor Technology