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Yttrium and lanthanide complexes of β-dialdehydes: synthesis, characterization and luminescence of coordination compounds with the conjugate base of nitromalonaldehyde

Marco Bortoluzzi、Elena Bianchin、Stefania Roppa 等 5 位作者2014-01-01Dalton Transactions

Coordination compounds having formulae [AsPh4][Ln(NMA)4] (1(Ln)), Ln(NMA)3(tppo)2 (2(Ln)), Ln(NMA)3(bipyO2) (3(Ln)), Ln(NMA)3(phen) (4(Ln)) and Ln(NMA)3(terpy) (5(Ln)) (Ln = Y and some lanthanides; NMA = conjugate base of nitromalonaldehyde; tppo = triphenylphosphine oxide; bipyO2 = 2,2'-bipyridine-N,N'-dioxide; phen…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Atomic Structure and Catalytic Activity of W-Modified Ni2P Surface Alloy by Photoelectron Diffraction and Spectroscopy

H. Matsui、Fumihiko Matsui、Naoyuki Maejima 等 7 位作者2014-01-01e-Journal of Surface Science and Nanotechnology

The surface alloying is the important topics in Ni2P study which is expected for next generation hydrodesulfurization and hydrodenitrogenation catalyst. The atomic structure and catalytic properties of a single crystalline Ni2P surface modified with W (W-Ni2P) was investigated by photoelectron diffraction (PED) and sp…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesAdvanced Materials Characterization Techniques

The Electronic Properties of Graphene Adsorbed on the (111) HfO2 Surface – A First Principles Study

I-Hsuan Chiu、Chin-Lung Kuo2014-01-01Procedia Engineering

Using density functional theory calculations, we have investigated the electronic properties of graphene monolayer adsorbed on the HfO 2 substrate. Our main research interest here is to explore the reason why the HfO 2 substrate can significantly degrade the transport properties of the adsorbed graphene layer as revea…

Graphene research and applicationsSemiconductor materials and devicesAdvancements in Semiconductor Devices and Circuit Design

Effects of Waste Cooking Oil Biodiesel Use on Engine Fuel Consumption and Emissions: A Study on the Impact on Oxidation Catalyst and Particulate Filter

Stefano Cordiner、Vincenzo Mulone、Matteo Alessandro Del Nobile 等 4 位作者2014-01-01Energy Procedia

The wide use of biodiesel has been driven by its reduction potential on greenhouse emissions from diesel engines without significant technological modifications. In this study a diesel engine for non-road applications has been fuelled with Waste Cooking Oil biodiesel blended with commercial fossil fuel at 6% and 30% v…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceBiodiesel Production and Applications

MWCNT causes extensive damage to the ciliated epithelium of the trachea of rodents

Teruya Ohba、Jiegou Xu、David B. Alexander 等 8 位作者2014-01-01The Journal of Toxicological Sciences

The ciliated tracheobronchial epithelium plays an important role in the excretion of inhaled dust. While many reports indicate that inhaled multi-walled carbon nanotubes (MWCNT) induce inflammation and proliferative changes in the lung and pleura, their effects on the upper airway have not been reported. Two different…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsInhalation and Respiratory Drug Delivery

D-Glucosamine Conjugation Accelerates the Labeling Efficiency of Quantum Dots in Osteoblastic Cells

Kazunari Igawa、Ming-Fang Xie、Hideki Ohba 等 5 位作者2014-01-01BioMed Research International

Quantum dots (QDs) are useful imaging tools in the medical and biological fields due to their optical properties, such as a high fluorescence intensity, remarkable resistance to photobleaching, broad absorption spectra, and narrow emission spectra. This is the first study to investigate the uptake of carboxylated QDs…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesRNA Interference and Gene Delivery

Investigation of the temperature dependence for the spectra of supercooled water in the middle infrared

A. V. Khakhalin、Aleksandra V. Koroleva2014-01-01Moscow University Physics Bulletin

The temperature dependence of the bending ν2, combination ν2 + ν L , and stretching (ν1, ν3, 2ν2) absorption bands in the infrared spectra of supercooled water with a temperature-change step Δt from 2 to 2.5°C was studied using an advanced infrared Fourier spectrometer. It was found that the frequency of the maximum o…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical Studiesnanoparticles nucleation surface interactions

Analysis of fragmentation statistics of alumina tubular specimens

I. A. Bannikova、Sergey Uvarov、Олег Наймарк2014-01-01AIP conference proceedings

Fragmentation statistics of shocked Al2O3 tubular specimens are studied. The parameter of the tube k = d/r2 is less than unity, where d is thickness of the tube, r2 is inner radius of the tube. Samples were fractured under electro-explosion shock wave loads initiated in the liquid. The mass of collected fragments in t…

High-Velocity Impact and Material Behavior

Fabrication and degradation characteristic of sputtered iridium oxide neural microelectrodes for FES application

Xiaoyang Kang、Jingquan Liu、Hongchang Tian 等 8 位作者2014-01-01OpenAlex

This paper shows the fabrication process of the reactively sputtered iridium oxide film (SIROF) microelectrodes under different oxygen flows and characters the electrochemical performances of the iridium oxide neural microelectrodes which are suffered from stimulus-evoked degradation. The SIROF microelectrodes prepare…

Advanced Memory and Neural ComputingConducting polymers and applicationsNeuroscience and Neural Engineering

Improvement of Blue Organic Photodiode with Pyrazol-Derivative

Kazuhiko Segi、Shigeki Naka、Hiroyuki Okada2014-01-01Journal of Photopolymer Science and Technology

We have investigated improvement in performance of blue sensitive organic photodiodes using a pyrazol derivative. Improved performance was obtained in the device using BBOT as an acceptor material. In addition, insertion of ultra-thin rubrene layer at donor/acceptor interface was effective for improvement of the excit…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Nature of second-order nonlinear optical response in phthalocyanine derivatives: a density functional theory study

Chiming Wang、Chao Chen、Qingqi Zhang 等 5 位作者2014-01-01TURKISH JOURNAL OF CHEMISTRY

Density functional theory was employed to investigate a series of phthalocyanine derivatives, discovering the limitation when the expansion of the conjugated system was employed to improve the hyper-Rayleigh scattering response coefficient. Furthermore, an unusually C_{\infty v}-type octupolar population was found by…

Porphyrin and Phthalocyanine ChemistryPhotorefractive and Nonlinear OpticsPhotochemistry and Electron Transfer Studies

New 2D zinc phosphonates with heptanuclear units, reversible dehydration–hydration and bright luminescence

Ruibiao Fu、Shengmin Hu、Xin‐Tao Wu2014-01-01CrystEngComm

Two new zinc phosphonates with formulas [Zn18(L)12(H2N(CH2)4NH2)2]·25.5H2O (1) and [Zn9(L)6(HN(C2H4NH2)2)2]·10H2O (2) have been synthesized starting from zinc acetate, 1-C10H7-CH2N(CH2COOH)(CH2PO3H2) (H3L) and 1,4-butanediamine (for 1)/diethylenetriamine (for 2). Compounds 1 and 2 are characterized by single-crystal X…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Comparison of High-end Tailored Jackets for Ready-to-wear Produced in Italy and Japan

KyoungOk Kim、Keiko Miyatake、Kimiko Sano 等 5 位作者2014-01-01International Journal of Affective Engineering

We studied differences in production process of garments of Japan and Italy. A jacket which was designed by the same designer was produced in Japan and Italy, respectively. We compared jacket parts before and after assembling. We also compared the front, side, and back styles of jackets and the ironing treatments and…

Textile materials and evaluationsFashion and Cultural TextilesConsumer Perception and Purchasing Behavior

An intriguing pH-triggered FRET-based biosensor emission of a pyrazoline–doxorubicin couple and its application in living cells

Dipak Rana、Sayaree Dhar、Subhash Chandra Bhattacharya2014-01-01Physical Chemistry Chemical Physics

A unique pH-driven Förster resonance energy transfer (FRET) based biosensor emission by a pyrazoline-doxorubicin pair has been deciphered with a bioimaging application in a live HepG2 cell whereas conformational switching of both molecules at elevated pH reveals a fascinating twist (FRET-OFF) via strong fluorescent ex…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Extended Surface of Materials as a Result of Chemical Equilibrium

W. Arabczyk、Rafał Pelka、Izabella Jasińska2014-01-01Journal of Nanomaterials

A system consisting of at least two components was considered. In this system, nanocrystalline material is formed at high temperature, at which diffusion does not limit the mass transport. The structure results from establishing an equilibrium between surface and volume of the crystallites and their surroundings in is…

nanoparticles nucleation surface interactionsChemical and Physical Properties of MaterialsAdvanced Materials Characterization Techniques

Suppression of Cross-sensitivity to Humidity in Pristine, Suspended Single-walled Nanotube NO2 Sensors

Kiran Chikkadia、Matthias Muotha、Niklas Beckmanna 等 5 位作者2014-01-01Procedia Engineering

The humidity response of pristine, suspended single-walled carbon nanotube (SWNT) gas sensors is analyzed. We employ ultraclean, dry-transferred carbon nanotubes, whose surface is not exposed to any resist-based or wet-chemical processes. Thanks to this, the nanotube surface remains pristine before gas exposure. The s…

Carbon Nanotubes in CompositesGas Sensing Nanomaterials and SensorsAdvanced Chemical Sensor Technologies

Oxide Ion Transport in Promising Cobaltites for SOC

Vincent Thoréton、Yang Hu、Ibtissem Kehal 等 12 位作者2014-01-01Procedia Engineering

Two cobaltites were studied as air electrodes for Solid Oxide Cells with a Cerium Gadolinium Oxide electrolyte (CGO): Ca3Co4O9+δ, well known for its thermoelectric properties, and Ba2Co9O14. After optimisation of composition and thickness, a very good ASR of only 0.08 Ω.cm2 was obtained for the 50 wt% Ba2Co9O14 - 50 w…

Advancements in Solid Oxide Fuel CellsAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Effect of Preparation Method on Catalytic Properties of Double Perovskite Oxides LaSrFeMo0.9Co0.1O6 for Methane Combustion

Jiandong Zheng、Xiongfeng Lang、Changjiang Wang2014-01-01Advances in Chemical Engineering and Science

The double perovskite oxides LaSrFeMo0.9Co0.1O6 was prepared by co-precipitation method and sol-gel method. The title catalysts were calcined at 800°C and characterized by XRD H2-TPR, SEM and TG-DTA techniques. The catalytic activity was evaluated for methane combustion. The specific surface area of them was calculate…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

Research on Jacket Patterns and Specifications of Ready-to-wear for High-end in Italy and Japan

KyoungOk Kim、Keiko Miyatake、Kimiko Sano 等 5 位作者2014-01-01International Journal of Affective Engineering

We compared the production processes of ready-to-wear for high-end in Italy and Japan. We specifically took into account the works of modelists from these countries to understand how their differences influenced the resulting characteristics of garments. We report details of each production stage by predicting the jac…

Textile materials and evaluationsFashion and Cultural TextilesCultural and Historical Studies