Materials Literature
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Oxidovanadium( iv ), cis -dioxidomolybdenum( vi ) amide complexes and cobalt( iii ) imine complex of an o -phenylenediamine derivatives are reported.
The biological intracellular vesicles, formed from the cell membrane or from different cell organelles, play a main role in the intracellular transport, transfer and exchange of molecules and information. Extracellular vesicles are also detected in organisms belonging to any of the three main branches of evolution, Ar…
New heteroleptic ruthenium(II) complex was formulated as [Ru(L1)2(NCS)2], where L1= 9-anthracenyl-10-(2-methyl-2-butenoic acid)-1,10-phenanthroline was synthesized and its photophysical properties were studied and compared to previously reported analogue complex containing no anthracene moiety [Ru(L2)2(NCS)2], L2= (2-…
Dye-sensitized solar cells (DSSCs) are a promising alternative to conventional semiconductor solar cells due to their ease of fabrication and low manufacturing cost. Ru-based dyes, particularly N719, are the typical dye for DSSC applications. However, N719-based DSSCs have weak absorbance at a wavelength around 440 nm…
The functionalized Cahn--Hilliard (FCH) free energy models phase separation in amphiphilic systems, which possess a component with both hydrophilic and hydrophobic tendencies. We establish the existence of a family of bilayer structures, described by homoclinic solutions of a fourth-order dynamical system arising from…
Structural properties and energetics of silicon and phosphorus doped hexagonal boron nitride sheets were investigated by performing density functional theory calculations. The dopant atoms were substituted in a neutral charge state at either the B or the N site in the system as an impurity. All the systems under consi…
The removal of sulfur dioxide (SO2) contained in the combustion exhaust gas from medium-scale facilities is necessary because of its role as an air pollutant. In this study, we focus on dry DeSOx filters that use simple desulfurization materials to capture SO2; in particular, we used manganese dioxide (MnO2) that take…
We consider the problem of minimizing the Willmore energy connected surfaces with prescribed surface area which are confined to a finite container. To this end, we approximate the surface by a phase field function $u$ taking values close to +1 on the inside of the surface and -1 on its outside. The confinement of the…
A model of photolysis of PbS 2 O 3 aqueous solutions has been proposed on the basis of identified photolysis products and semiempirical quantum-chemical calculations. The degradation of PbS 2 O 3 starts with the dissociation of the sulfur-sulfur bond in the thiosulfate group via photochemical excitation and transition…
Abstract A photo-alignment method for micro capillaries based on the SD-1 azo-dye is demonstrated. In this work a liquid-crystal molecules aligning layer is created by point-by-point irradiation of the azo-dye film by using an UV laser light. The method opens up new possibilities for an improved molecules’ orientation…
Vehicles consist of a large number of products of different shapes and sizes. These products can be manufactured very efficiently by metalworking. Products manufactured by metalworking also have superior mechanical properties, such as strength and elongation; these are useful in reducing vehicle weight which leads to…
1-D ZnO NAs with controllable density and diameter have successfully been synthesized and found potential applications in silver trap construction.
The influence of the short alkyl-chain ionic surfactant OTAB on the dynamic behavior of an inverse block copolymer-rich lamellar phase was investigated by neutron spin-echo spectroscopy (NSE). The observed intermediate scattering function can be described by a sum of two contributions. For high scattering vectors the…
The surface of mesocellular silica foam (MCF) was modified by grafting 3-aminopropyl-triethoxysilane (APTES) to have a positive charge, and thus to provide sites for the immobilization of H_3PW_{12}O_{40} (PW_{12}). This modified nanosized mesoporous silica (PW_{12}-APTES@MCF) was characterized by FTIR, XRD, BET, and…
Magnetic magnesium alloys have an inherent load-sensitive behavior. These alloys are manufactured by casting of magnesium alloyed with the ferromagnetic element cobalt. In this context, the magnetoelastic effect can be used in order to measure mechanical loads during the component's service by means of a harmonic anal…
We reveal the hydrothermal conversion rule for amorphous U( vi ) to large-size UO 2 .
We present a simple chain model for ballistic-diffusive heat transfer in heterogeneous nanostructures connected by atomistic interfaces, which are under extensive investigation for nanoscale heat transfer control. Heat transfer in typical heterogeneous nanostructures, including junctions with a single interface, multi…
In this study, the CuIn(Ga)Se2(CIGS) crystalline quality and MoSe2thickness of films produced by the rapid thermal selenization process under various selenization pressures were investigated. When the selenization pressure increased from 48 Pa to 1.45 × 104 Pa, the CIGS films were smooth and uniform with large crystal…
Localized surface plasmon resonance (LSPR) based fiber optic sensor probe is fabricated and is used to detect α-Synuclein, a marker for Parkinson’s disease. The preliminary studies show the Limit of detection of 70nM.
Acyclic diene metathesis (ADMET) polymerisation and nucleophilic aromatic substitution polycondensation are used to synthesize alternating copolymers based on polyetherethersulfone (PEES) blocks. ADMET results in incorporation of trans-allyl groups with more than 94 to 98% selectivity. The resulting polymers have a Mw…