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Modulating H 2 sorption in metal–organic frameworks via ordered functional groups

P.V. Dau、Seth M. Cohen2014-01-01Chemical Communications

Herein, we present the use of presynthetic and postsynthetic modification (PSM) approaches to regulate the structural organization of functional groups in the pores of isoreticular metal-organic frameworks (IRMOFs). It has been found that the structural ordering of aryl groups within the IRMOF pores results in hystere…

Metal-Organic Frameworks: Synthesis and ApplicationsSulfur Compounds in BiologyCovalent Organic Framework Applications

Prediction of Optimal Process Parameters for Abrasive Assisted Drilling of SS304

Kapil Kumar Goyal、Vivek Jain、Sudha Kumari2014-01-01Procedia Materials Science

This paper presents the optimization of cutting parameters for improving surface finish of stainless steel SS304 in the abrasive assisted drilling. In the present work, drilling of SS304 with supply of abrasive slurry consisting of silicon carbide abrasives of 1250 mesh size has been studied. The slurry concentration…

Advanced machining processes and optimizationAdvanced Surface Polishing TechniquesMetal Alloys Wear and Properties

Structural evolution of NiAu nanoparticles under ambient conditions directly revealed by atom-resolved imaging combined with DFT simulation

Xia Xiang、Jinlan Nie、Kai Sun 等 10 位作者2014-01-01Nanoscale

From an economic point of view, the structural stability of noble-transition bimetallic catalysts is as significant as their well-studied catalytic efficiency. The structural evolution and corresponding dynamics of NiAu bimetallic nanoparticles under ambient conditions are investigated using in situ Cs-corrected STEM…

Catalytic Processes in Materials ScienceIon-surface interactions and analysisnanoparticles nucleation surface interactions

Microstructure and Texture Evolutions in AISI 1050 Steel by Flow Forming

Vikram Bedekar、Praveen Pauskar、Rajiv Shivpuri 等 4 位作者2014-01-01Procedia Engineering

Abstract Hot rolled and annealed AISI 1050 steel cylindrical coupons were flow formed at different levels of deformation (66% and 90% wall thickness reduction). TEM studies revealed development of ultra-fine (sub)grain cell structure due to severe plastic deformation. The transverse subgrain size changed from 10 μm (b…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesMetallurgy and Material Forming

A New Forming Method of Triple Cup by Plate Forging

Zhigang Wang、Yasuharu Yoshikawa2014-01-01Procedia Engineering

A new forming technique to produce a cup with an upper and lower hollow boss by plate forging is proposed. In this process, the sheet metal is worked into a drawn cup by the deep drawing process and then deformed to the target shape by compressing the cup edge. One-stage edge compression process and two-stage compress…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesMetallurgy and Material Forming

CO2 Mineralisation: Production of CaCO3-type Material in a Continuous Flow Disintegrator-reactor

O. Velts、Merit Kindsigo、Mai Uibu 等 5 位作者2014-01-01Energy Procedia

Current study focused on the production of precipitated calcium carbonate on the basis of oil shale waste ash. The indirect aqueous carbonation of oil shale ash involved 2 main steps: Ca2+ leaching from ash and carbonation of the leachate in a continuous flow disintegrator-reactor accompanied by the crystallization of…

Drilling and Well EngineeringCalcium Carbonate Crystallization and InhibitionCO2 Sequestration and Geologic Interactions

A Structured Approach to Solve the Inverse Eigenvalue Problem for a Beam with Added Mass

Farhad Mir Hosseini、Natalie Baddour2014-01-01Mathematical Problems in Engineering

The problem of determining the eigenvalues of a vibrational system having multiple lumped attachments has been investigated extensively. However, most of the research conducted in this field focuses on determining the natural frequencies of the combined system assuming that the characteristics of the combined vibratio…

Material Properties and ApplicationsElasticity and Wave PropagationAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

Growth Analysis and Numerical Simulation of Cu3BiS3Absorbing Layer Solar Cell through the wxAMPS and Finite Element Method

F. Mesa、V. Ballesteros、A. Dussán2014-01-01Acta Physica Polonica A

The properties and the eciency of a semiconductor thin lm depend on the state of stress and defects in the lm structure. When the lm is growing layer by layer, the elastic energy due to deformation stress between the substrate and the lm is released partly due to the formation of dislocations in the critical thickness…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsSilicon and Solar Cell Technologies

Silver Nanoparticles Dispersed on Silica Glass for Applications as Photothermal Selective Material

Víctor Rentería-Tapia、C. Velásquez-Ordoñez、M. Ojeda Martínez 等 5 位作者2014-01-01Energy Procedia

Silver nanoparticles dispersed into a resin are deposited on silica glasses by the spin coating method and heated around 100 °C. UV-VIS measurements show high stability of the optical spectra after heat treatment, suggesting that the morphology of the silver nanoparticles are stable. The transmission electronic micros…

Gold and Silver Nanoparticles Synthesis and ApplicationsSolar Thermal and Photovoltaic SystemsFluid Dynamics and Thin Films

Diverse silver( i ) sulfobenzoate coordination polymers and their recycling property as homogeneous catalyst in oxygenation of sulfide

Ai-Qing Ma、Long‐Guan Zhu2014-01-01RSC Advances

Four silver sulfobenzoate coordination polymers with bpmb ligands were prepared. The variable positions of sulfonate groups on benzene rings gave rise to different coordination polymers and variable chemical properties.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Facile production of a large-area flexible TiO 2 /carbon cloth for dye removal

Le Yang、Zonghan Hong、Jun Wu 等 4 位作者2014-01-01RSC Advances

We successfully produced a large area, flexible and robust TiO 2 nanofiber/carbon fiber sheet with great convenience for water purification.

TiO2 Photocatalysis and Solar CellsMembrane Separation TechnologiesElectrospun Nanofibers in Biomedical Applications

Control of In-Plane Uniaxial Anisotropy of CoPd-CaF $_{2}$ Nanogranular Films by Tandem-Sputtering Deposition

Masayuki Naoe、N. Kobayashi、Shigehiro Ohnuma 等 6 位作者2014-01-01IEEE Magnetics Letters

In-plane uniaxial anisotropic CoPd-CaF2nanogranular soft magnetic films for gigahertz applications were prepared using RF tandem-sputtering deposition with substrate revolution. Strong anisotropy with a large anisotropy field exceeding 50 kA/m was achieved in the centrifugal-centripetal direction of the substrate revo…

Magnetic properties of thin filmsZnO doping and propertiesMetallic Glasses and Amorphous Alloys

PMMA/PU/CB Composite Bipolar Plate for Direct Methanol Fuel Cell

T. Phuttachart、Narumol Kreua‐ongarjnukool、Rungsima Yeetsorn 等 4 位作者2014-01-01Energy Procedia

This research fabricates bipolar plates for direct methanol fuel cells (DMFC) to improve compressive strength and creep behaviour. The composites comprise of poly (methyl methacrylate) (PMMA), polyurethane (PU) and carbon black (CB) those were fabricated via bulk polymerization in a casting process. The technique can…

Supercapacitor Materials and FabricationFuel Cells and Related MaterialsConducting polymers and applications

Modeling of Heat Transfer in Single Cell of Polymer Electrolyte Fuel Cell by Means of Temperature Data Measured by Thermograph

Akira Nishimura、Kazuhiro Iio、Masashi Baba 等 6 位作者2014-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

The aim of this study is to construct a simple heat-transfer model to present the temperature of the interface between the polymer electrolyte membrane (PEM) and the catalyst layer at the cathode, i.e., the reaction surface, in a single cell of polymer electrolyte fuel cell (PEFC). The model is based on the temperatur…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Study of Constraint Effect on Reference Temperature (T0) of Reactor Pressure Vessel Material (20MnMoNi55 Steel) in the Ductile to Brittle Transition Region

Kushal Bhattacharyya、S.K. Acharyya、J. Chattopadhyay 等 4 位作者2014-01-01Procedia Engineering

The master curve methodology proposed by Kim Wallin (ASTM E1921-02) has been used to evaluate master curve and reference temperature (T0) from TPB specimen for the material 20MnMoNi55 steel using single temperature and multi-temperature method. The effect of test temperature on reference temperature (T0) has been stud…

Fusion materials and technologiesNuclear reactor physics and engineeringThermodynamic and Structural Properties of Metals and Alloys

Polyacryloyl hydrazide based injectable & stimuli responsive hydrogels with tunable properties

Anuj Kumar、Sabindra K. Samal、Rupesh Dash 等 4 位作者2014-01-01Journal of Materials Chemistry B

The synthesis and characterization of a series of injectable and stimuli responsive hydrogels based on polyacryloyl hydrazide have been accomplished using dimethyl 2,2′-thiodiacetate, acrylic acid, diethyl malonate and polyethylene glycol diacrylate as cross-linkers through a chemical or dual cross-linking pathway.

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPickering emulsions and particle stabilization

Characterization of Moroccan coal waste: valorization in the elaboration of the Portland clinker

D. Belkheiri、М. Тайбі、A. Diouri 等 6 位作者2014-01-01MATEC Web of Conferences

Coal exploited in the mine of Jerada (northeast of Morocco) was accompanied by large quantities of waste. The purpose of this work is to characterize this waste with the aim of its use as a material for civil engineering. Mineral and chemical investigations on this waste in the raw state, and at different temperature…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactions

Ability of bone graft substitutes to support the osteoprogenitor cells: Anin-vitrostudy

Ziad Dahabreh2014-01-01World Journal of Stem Cells

AIM: To compare seven commercially available bone graft substitutes (BGS) in terms of these properties and without using any additional biological growth factors. METHODS: Porcine osteoprogenitor cells were loaded on seven commercially available BGS and allowed to proliferate for one week followed by osteogenic induct…

Bone Tissue Engineering MaterialsDental Implant Techniques and OutcomesSilk-based biomaterials and applications