Materials Literature
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Complex dielectric permittivities, for two orientations of the director n, parallel (E || n) and perpendicular (E ⊥ n) to the probing electric field E, of the weakly polar liquid crystals (LCs) 4,4′-dihexylazoxybenzene (D6AOB) and 4,4′-diheptylazoxybenzene (D7AOB) as well as the non-polar LC diheptylazobenzene (D7AB)…
Supercritical was used to facilitate silylation in repairing oxygen plasma-induced damage during photoresist stripping in porous organosilicate films. Samples with open and closed-pore morphologies prepared by sacrificial-porogen approach were exposed to plasma to simulate damage. These samples were pretreated with 10…
Coating of extracorporeal circuits may be a solution to prevent adverse effects induced by the contact of blood elements and proteins with foreign surfaces. This paper reviews the recent novel coating technologies and compares their documented in vitro and ex vivo advantages under the clinical setting. Data presented…
Nucleophilic substitution reactions on hexadecafluorophthalocyaninato zinc(II) with a variety of O, N, C, and S nucleophiles led to narrowly defined mixtures of polysubstituted phthalocyanines, some of which are completely inaccessible by classical phthalonitrile condensation reactions.
Pulsed neutron and high energy X-ray diffraction experiments on single- and two-phase Al2O3–Y2O3 and single-phase Al2O3–La2O3 glasses suggest that a polyamorphic phase transition occurs via changes in the Y–O coordination and connectivity. The transformation from a high temperature to a low temperature amorphous phase…
Abstract Bismuth sodium titanate (abbreviated as BNT) based solid solution, [Bi 0.5 (Na 1‐x‐y K x Li y ) 0.5 ]TiO 3 (0 < x + y < 1) ceramics, was invented in our group. These ceramics, which are considered as new candidates for lead‐free piezoelectric materials, were prepared by conventional ceramic sintering te…
A comparative Raman study of (Ba,Sr)TiO3 bulk ceramics, sol-gel derived polycrystalline thin film, and heteroepitaxial thin film deposited by rf sputtering onto (001) MgO substrate is reported. It is found that phase transition sequence in the heteroepitaxial thin film is markedly different from those observed in the…
The intramolecular addition of benzylic radicals, generated from benzyl phenyl selenides by the action of tris(trimethylsilyl)silane and AIBN or AIBMe, onto neighbouring ketenimine functions is studied. The persistent α-(indol-2-yl)benzyl radicals, resulting from such cyclization processes, undergo cross-coupling with…
The Effect of Mn incorporation into perovskite B-site lattice of SrTiO3 ceramics on structural and low frequency dielectric properties is studied in this work. Lattice parameter and grain size decreases with Mn content increasing. Mn doping reduces dielectric permittivity value and drives the system away from ferroele…
With the emergence of commercial hyper-branched (HB) and dendritic polymers, having a three-dimensional (3D) morphology with high peripheral functionality, new opportunities have been created for formulating dental adhesives and composites with enhanced mechanical and physical properties. The objective of the present…
Dextran-polyethylene glycol (PEG) conjugates were synthesized by activating dextran hydroxy groups with carbonyldiimidazole, introducing amino groups by attaching ethylenediamine, and reacting amino groups with a succinimidyl-activated derivative of PEG. Conjugates with an average of 12 and 21 PEG (5 kDa) residues per…
This analysis was conducted to investigate the influence that dispersion in crystal grain sizes has upon the yield behavior of nanocrystalline materials. In the model proposed for this purpose, the distribution of crystal grains was expressed in a log-normal manner. It was assumed that the yield stress of each crystal…
A vanadia-titania mesoporous xerogel (10.5 wt% V(2)O(5)) was prepared from chloride precursors using a one-step non-hydrolytic sol-gel route and subsequent drying at ambient pressure; after calcination at 773 K for 5 h no crystalline V(2)O(5) was detected and the resulting mixed oxide exhibited remarkable activity in…
A processable polyborazine was synthesised by an original method under mild conditions and then converted into high performances boron nitride fibres.
The ground state electronic properties of metal-exchanged Preyssler heteropolyoxoanions [M(n+)P(5)W(30)O(110)](n-15), in which the encapsulated M(n+) ions are the spherical, diamagnetic ions Na(+), Ca(2+), Sr(2+), Y(3+), La(3+) and Th(4+), are studied using a combination of electrochemical, optical, and NMR experiment…
Electronic phase separation is increasingly getting recognized as a phenomenon of importance in understanding the magnetic and electron transport properties of transition metal oxides. The phenomenon dominates the rare-earth manganates of the formula Ln(1-x)A(x)MnO(3)(Ln = rare earth and A = alkaline earth) which exhi…
A comprehensive understanding of the design, synthesis, characterization, and properties of boron carbonitride nanotubes (BCN) is presented in this review. Distinctive structural and electronic properties are revealed in theoretical studies of the BCN nanotubes and compared with the properties of carbon nanotubes. In…
Hexadehydro[12]annulenes annelated with one or two TTF units have been synthesized to investigate their pi-amphoteric properties based on the TTF and [12]annulene moieties; these compounds show multi-redox potentials, solvatochromism and the formation of large sandwich complexes.
Sonication of nanoparticle suspensions confined within aqueous droplets of drug molecules in toluene produces drug-loaded silica or titania porous microspheres with complex morphology and storage/release properties.
An octanuclear copper(II) complex possessing a dimer-of-tetramers structure self-assembles from a binuclear oxamatocopper(II) metallacryptand of the meso-helicate type; its magnetic behaviour is consistent with its unique double-propeller molecular topology.