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Transition Metal-mediated Fuctionalization and Multiplication of Porphyrins toward Giant Functional Systems

Akiharu Satake2007-01-01Journal of Synthetic Organic Chemistry Japan

Functionalization and multiplication of porphyrins by transition metal-mediated reactions (Sonogashira coupling, Negishi coupling, Stille coupling, Mizoroki-Heck alkenylation, Buchwald-Hartwig reaction, Suzuki-Miyaura coupling, cobalt-mediated [2+2+2] cyclization, Grubbs' metathesis reaction, etc.) are reviewed. When…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsSurface Chemistry and Catalysis

Influence of surface state and thin dielectric coating on the insulation properties of a coaxial electrode arrangement in SF6

Ch. Lederle、J. Kindersberger、E. Kynast2007-01-01mediaTUM – the media and publications repository of the Technical University Munich (Technical University Munich)

The improvement of the dielectric strength of SF6 insulated systems by using a thin dielectric coating to change the surface state of electrodes was studied. The paper deals with the breakdown probability of a coaxial aluminium electrode arrangement with different surface roughness in pressurized SF6. Thin epoxy resin…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationThermal Analysis in Power Transmission

Tribological and mechanical properties of DLC film obtained on metal surface by an enhanced and low-cost pulsed-DC discharge

Vladimir Jesus Trava Airoldi、Lucia Viera Santos、L.F. Bonetti 等 6 位作者2007-01-01International Journal of Surface Science and Engineering

A new, low-cost, enhanced pulsed-DC PACVD deposition system was designed and tested to evaluate its capacity to produce quality DLC films. The main focus of the study was to attain DLC films with low friction coefficients, low total stress, a high degree of hardness, and very good adherence to the substrates on deposi…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Synthesis and cellular uptake of cell delivering 2,6-pyridinediylbisalkanamide submicron-sized sheets in HeLa cells

J. S. Yadav、Manoj K. Gupta、I. Prathap 等 6 位作者2007-01-01Chemical Communications

2,6-Pyridinediylbisalkanamides were synthesized, using diaminopyridine (DAP) as a linker and alkyl chains of varying lengths, that upon self-assembly form submicron-sized sheets and their uptake into the cytoplasm of HeLa cells was studied by confocal microscopy.

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

Anti-inflammatory Effect ofStrychnos potatorum. Seeds on Acute and Subacute Inflammation in Experimental Rat Models

E. Sanmuga Priya、S. Venkataraman2007-01-01Pharmaceutical Biology

The anti-inflammatory effect of seed powder [SPP I (100 mg/kg) and II (200 mg/kg) p.o.] and aqueous extract [SPE I (100 mg/kg) and II (200 mg/kg) p.o.] of Strychnos potatorum. Linn (Loganiaceae) seeds was studied in carrageenin-induced hind paw edema and cotton pellet granuloma models. In carrageenin-induced rat paw e…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Magnetoactive Polymer Composite Fibers and Fabrics -Processing and Mechanical Characterization

M. Farshad、Frank Clemens、Magali Le Roux2007-01-01Journal of Thermoplastic Composite Materials

A new polymer composite material and textile product has been developed. The main constituents of this composite are thermoplastic polymer and embedded carbonyl iron powder. Through an extrusion process, endless flexible fibers having diameters of 200 and 500 mm have been produced. The fibers show a very high degree o…

Electromagnetic wave absorption materialsMagnetic and Electromagnetic Effects

Cross-section TEM investigation of quasicrystalline catalysts prepared by aqueous NaOH leaching

T. Tanabe、Satoshi Kameoka、F. Sato 等 5 位作者2007-01-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The Al–Cu–Fe quasicrystal (QC) has been shown to reveal high catalytic activity and thermal stability for steam reforming of methanol (SRM: CH3OH + H2O → 3H2 + CO2), after leaching with NaOH aqueous solution. To investigate the origin of the high catalytic performance, cross-sectional transmission electron microscopy…

Quasicrystal Structures and PropertiesNanocluster Synthesis and ApplicationsMineralogy and Gemology Studies

Rheological and mechanical properties of wood flour filled polyisoprene/chlorosulphonated polyethylene rubber blends

Gordana Marković、Milena Marinović‐Cincović、Blaga Radovanović 等 4 位作者2007-01-01Chemical Industry and Chemical Engineering Quarterly

The effect of wood flour (WF) on curing behavior and swelling properties of polyisoprene rubber/chlorosulphonated polyethylene (NR/CSM) rubber blends was investigated. The mechanical properties, as well as the equilibrium swelling characteristics of the elastomeric composites filled with WF (particle size from 300 to…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Thermoelectric Properties of the Layered Cobaltite Ca<SUB>3</SUB>Co<SUB>4</SUB>O<SUB>9</SUB> Epitaxial Films Fabricated by Topotactic Ion-Exchange Method

Kenji Sugiura、Hiromichi Ohta、Kenji Nomura 等 8 位作者2007-01-01MATERIALS TRANSACTIONS

To clarify the thermoelectric properties of the layered cobalt oxide Ca3Co4O9 epitaxial film fabricated by the topotactic ion-exchange method [K. Sugiura et al., Appl. Phys. Lett. 89, 032111 (2006)], the electrical resistivity (ρ), Hall coefficient (RH), and Seebeck coefficient (S) of high quality Ca3Co4O9 epitaxial f…

Advanced Thermoelectric Materials and DevicesTransition Metal Oxide NanomaterialsThermal Expansion and Ionic Conductivity

Influence of TiO2 and ZnO on the conductivity and dielectric properties of copper-bismuth glasses

D. K. Shukla、S. Mollah、Ravi Kumar2007-01-01Journal of Applied Physics

Influence of TiO2 and ZnO oxides has been investigated elaborately on the conductivity and dielectric properties of unconventional and technologically important 40CuO–40Bi2O3–20X (where X=TiO2 and ZnO) glasses. The dc electrical conductivity of ZnO containing glass is found to be higher than that of TiO2 containing on…

Luminescence Properties of Advanced MaterialsFerroelectric and Piezoelectric MaterialsGlass properties and applications

Wavelength-multiplexed submicron holograms for disk-compatible data storage

Pengfei Wu、Zhiqiang Liu、Jame J. Yang 等 5 位作者2007-01-01Optics Express

By using a hybrid diffractive and refractive achromat with extended depth of focus, we have successfully recorded a micro-hologram array with diffraction-limited individual spot size maintained throughout the thickness of recording medium. An electrically programmable wavelength combiner was constructed in which a whi…

Liquid Crystal Research AdvancementsPhotorefractive and Nonlinear OpticsAdvanced Optical Imaging Technologies

Gas-phase surface functionalization of multi-walled carbon nanotubes with vacuum UV photo-oxidation

Marie Krysak、B. Parekh、T. Debies 等 7 位作者2007-01-01Journal of Adhesion Science and Technology

For bulk processing of carbon nanotubes, an important first step in adhesion to the nanotubes is often liquid-phase functionalization through chemical oxidation with acids (e.g., nitric and sulfuric), peroxides and/or potassium permanganate. In comparison, gas-phase photo-oxidation can be an alternative to introduce o…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Properties of Bacterial Corrosion of Stainless Steel and Its Inhibition by Protamine Coating

Yoshinobu Matsumura、Kaoru Yamada、Mitsuo Takahashi 等 5 位作者2007-01-01Biocontrol Science

We investigated characteristics of the corrosion of stainless steel specimens by bacteria and the effects of using antimicrobial coating on the surface for inhibiting corrosion. Bacillus sp. 2-A and Staphylococcus sp. 2-1 cells adhered tightly to a stainless steel SUS304 specimen, formed a microcolony or biofilm, and…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Generating small-scale structures from large-scale ones via optical near-field interactions

Makoto Naruse、Takashi Yatsui、Hirokazu Hori 等 5 位作者2007-01-01Optics Express

Optical near-fields, which appear in the vicinity of structures when irradiated with light, exhibit a hierarchical nature, meaning that the degree of localization of optical near-fields at a given point is related to the scale of the structure involved in this process. Therefore, if we could make optically induced fab…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesNear-Field Optical Microscopy

ON THE INTERPRETATION OF THE XPS SPECTRA OF ADSORBED LAYERS OF FLOTATION COLLECTORS − ETHYL XANTHATE ON METALLIC LEAD

Paweł Nowak、K. Laajalehto2007-01-01Physicochemical Problems of Mineral Processing

Ethyl xanthate adsorption on metallic lead was studied by X-ray photoelectron spectroscopy (XPS) after treatment of lead sample at different potentials in aqueous NaNO3 solutions containing ethyl xanthate. Continuous increase of the amount of ethyl xanthate species on the lead surface was observed as the potential was…

Corrosion Behavior and InhibitionElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

The Korea-US Free Trade Agreement: A Summary Assessment

Jeffrey J. Schott2007-01-01RePEc: Research Papers in Economics

The Korea-United States Free Trade Agreement (KORUS FTA) opens up substantial new opportunities for bilateral trade and investment in goods and services and promotes important foreign policy interests of both countries. The FTA quickly removes most tariff barriers to auto trade and substantially reduces tax and regula…

Korean Peninsula Historical and Political StudiesAgriculture, Soil, Plant ScienceMetallurgy and Material Science

Modelling drop dynamics on patterned surfaces

Julia M. Yeomans、Halim Kusumaatmaja2007-01-01Durham Research Online (Durham University)

We present a mesoscopic model able to capture the physics of drops moving across patterned surfaces. In this model, interfaces appear naturally, and both chemical and topological patterning can be incorporated with relative ease, making it particularly suitable to study the behaviour of evolving drops. We summarise re…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferMicro and Nano Robotics

Effects of Aluminum on Delayed Fracture Properties of Ultra High-strength Low Alloy TRIP-aided Steels

Tomohiko Hojo、Koh‐ichi Sugimoto、Youichi Mukai 等 4 位作者2007-01-01鐵と鋼 : 日本鐡鋼協會々誌

To improve the delayed fracture strength of ultra high-strength low alloy TRIP-aided steels with bainitic ferrite matrix (TBF steels), the effects of aluminum content on hydrogen absorption behavior and delayed fracture properties of 0.2%C-0.5∼1.5%Si-1.5%Mn TBF steel were investigated. When aluminum was added to the T…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Compatibilization of recycled high density polyethylene (HDPE)/polyethylene terephthalate (PET) blends

Kasama Jarukumjorn2007-01-01OpenAlex

Immiscible blends of recycled high density polyethylene (HDPE) and polyethylene terephthalate (PET) were compatibilized with maleic anhydride grafted polyethylene (PE-g-MA). The effect of the compatibilizer content on the mechanical, morphological, rheological, and thermal properties of recycled HDPE/PET blends was in…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Passivity of Magnetostrictive Materials

Sina Valadkhan、Kirsten Morris、Amir Khajepour2007-01-01SIAM Journal on Applied Mathematics

Magnetostrictive materials display large force and displacement in response to an applied field, as well as short response time. However, their nonlinear and hysteretic behavior has hindered their use. We prove, using the physics of the material, that these materials are passive. The corresponding energy storage funct…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsPiezoelectric Actuators and Control