Materials Literature
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Mesoporous graphitic carbon nitride (mpg-C 3 N 4 ) was synthesized using silica nanoparticles as the hard template, and cobalt modified mpg-C 3 N 4 (Co 3 O 4 /mpg-C 3 N 4 ) was prepared via a facile impregnation method.
The nonlinear optical properties of nonzero-bandgap graphene materials and the corresponding hybrid glasses were strongly affected by the laser duration.
In the preparation of theophylline cocrystals, phenol coformers facilitate water assimilation due to their weaker O–H⋯N(imidazole) synthon. The presence of –COOH prevents water incorporation and provides added physical stability at high humidity. This study shows the feasibility of cocrystal design of an API to tune p…
Sufficient contact, high catalytic activity, free electron transport and ionic diffusion are desired for liquid–solid heterogeneous electrocatalysis.
We demonstrate high-performance sequentially solution-processed organic photovoltaics (OPVs) with a power conversion efficiency (PCE) of 5% for blend films using a donor polymer based on the isoindigo-bithiophene repeat unit (PII2T-C10C8) and a fullerene derivative [6,6]-phenyl-C[71]-butyric acid methyl ester (PC71BM)…
A method for rapid synthesis of 2–40 nm diameter nanocrystal dispersions of the emerging sustainable thin-film solar absorber copper zinc tin sulfide is reported: the average crystals size is controlled by varying the synthesis temperature between 150 °C and 340 °C. Films cast from larger nanocrystals, are crack-free…
The photoactivity of g-C3N4 is greatly limited by its high recombination rate of photogenerated carriers. Coupling g-C3N4 with other materials has been demonstrated to be an effective way to facilitate the separation and transport of charge carriers. Herein we report a composite of conductive carbon black and carbon n…
Two dimensional (2D) square-like bismuth oxyiodine (BiOI) nanosheets with a thickness of about 10 nm and exposed {001} facets are obtained by a facile hydrothermal route without any surfactant and special solvent. The photocatalytic performance of as-prepared 2D square-like BiOI nanosheets is evaluated by the photodeg…
The association of colloidal deposition of magnetorheological fluid in the presence of an external magnetic field with a sintering process facilitates the attainment of hematite photoanodes with high performance for water splitting.
Two new cocrystals of ezetimibe were identified and scale-up. Ezetimibe–proline cocrystal showed improved apparent solubility and physical stability.
Well-ordered meso-macroporous carbon nitride film fabricated via a simple and flexible template replication method by using the P123 block copolymer and polystyrene spheres as dual templates shows selective sensing performance for acetic acid but after treating the surface of the film with UV light and oxygen, the sel…
The recently developed strategies on designed synthesis of porous metal–organic framework catalysts and their interesting catalytic properties are summarized in this short review.
The evaporation process of a sessile drop of water on soft patterned polydimethylsiloxane (PDMS) substrates is investigated in this study. Different softness of a regular pillar-like patterned PDMS substrate can be achieved by controlling the mixing ratio of a PDMS's prepolymer base and a curing agent at 10 : 1, 20 :…
Carbon fiber (CF) was modified by air plasma at 30 Pa and 200 W with different treatment times. Interlaminar shear strength (ILSS) of CF/BMI composites suggested that air plasma-treated CFs showed better adhesion with BMI resins than the untreated resins; the maximum increment was 20.4% after plasma treatment for 900…
A CVD-synthesized SiN x LIB anode material exhibits stable, high capacity performance via two stage electrochemical reactions (conversion and then alloying).
Crystalline materials with large tailor-made channels have been made by an isoreticular synthesis strategy, which includes a successful adjustment of the π-conjugation over a framework skeleton allowing target recognition for aromatic molecules. The selective absorption of benzene over cyclohexane has been achieved, w…
In recent years, nanoscale metal–organic coordination polymers have attracted more and more attention because of their specific properties in gas sorption, sensors, contrast agents, drug delivery, templates and so on. Carboxylate compounds are a large family of O-donor ligands and are studied widely because such ligan…
We synthesize nonionic polymer-based polyrotaxanes in solvent systems based on pillar[5]arene cyclic host liquids. Using a reactive liquid, pillar[5]arene enabled synthesis of a nonionic topological gel.
Carefully designed AIE-active luminogens can be utilized to fabricate metal-free and non-doped low color temperature OLEDs.
Palladium nanoparticles were efficiently prepared in situ by sodium cyanoborohydride reduction of Pd( ii ) at room temperature using calcium-cholate hydrogel fibers as templates. The PdNPs self-organize on the gel fibers, which supports the controlled growth as well as stabilization of PdNPs. The hybrid xerogel was us…