Materials Literature
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Silver nanowire electrodes incorporated with polyethoxysiloxane reveal excellent resistance to oxidation and significantly increase conductivity by 1–2 orders of magnitude.
The Finland trityl radical CT-03 binds to bovine serum albumin, inducing the broadening of its EPR signal.
1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.
Enzyme-mediated injectable hydrogels based on a poly( l -glutamic acid) graft copolymer with tunable physicochemical properties, biodegradability and good biocompatibility were developed.
The present study reports novel cocrystals of telmisartan (TEL) with saccharin and glutaric acid.
The CO2 capture properties of M2CO3 (M = Na, K)-promoted and CaCO3-promoted MgO sorbents are investigated by first-principles density functional theory complemented with lattice phonon calculations. The calculated thermodynamic properties indicate that by forming double salts (M2Mg(CO3)2 and CaMg(CO3)2), compared to p…
p-Type doped La 5 Ti 2 CuS 5 O 7 photoelectrodes fabricated by particle transfer generate photocathodic current at +0.88 V vs. RHE in photoelectrochemical water splitting.
We have studied the geometry and singlet-triplet energy difference of two mono-nuclear Ni(2+) models related to the active site in [NiFe] hydrogenase. Multiconfigurational second-order perturbation theory based on a complete active-space wavefunction with an active space of 12 electrons in 12 orbitals, CASPT2(12,12),…
Classical molecular dynamics simulations of several aqueous alkali halide salt solutions have been used to determine the effect of electrolytes on the structure of water and the hydration properties of calcium ions. Compared with the simulations of Ca(2+) ions in pure liquid water, the frequency of water exchange in t…
Co-crystals assembled from 1,4-diiodotetrafluorobenzene and bent 3-ring-N-heterocyclic hydrocarbons via C–I⋯N and C–I⋯π halogen bonds emit green, orange-yellow and orange phosphorescence.
The selective decomposition of structural nitrate anions in alkaline earth MOFs generates highly dispersed base sites with catalytic applications.
Polymer self-assembly was developed as an epitope imprinting strategy involving facile processes and high recognition site density. As a model, transferrin epitope imprinted polyethersulfone (PES) beads were successfully fabricated using this technique. The imprinted beads demonstrated excellent selectivity toward the…
The unique electronic properties of the surface electrons in a topological insulator [1] are protected by time-reversal symmetry. Circularly polarized light naturally breaks time-reversal symmetry, which may lead to an exotic surface quantum Hall state [2]. Using time- and angle-resolved photoemission spectroscopy [3]…
Flavin-catalysed oxidative hydroxylation of substituted arylboronic acids by molecular oxygen with the assistance of hydrazine or ascorbic acid resulted in phenols in high yields. This mild organocatalytic protocol is compatible with a variety of functional groups and it is alternatively usable for transformation of a…
The surface of PDMS composites containing copper spiky particles was treated using atmospheric pressure plasma to optimize surface tension for PEDOT:PSS inkjet printed electrodes. Quantitative comparison based on image analysis was done.
A novel nanocomposite composed of graphene-like MoS 2 sheets and Zn x Cd 1−x S nanoparticles was used for photocatalytic hydrogen generation under visible light irradiation.
A highly porous and stable acid–base bifunctional metal–organic framework, MIL-101–NH2–SO3H, was prepared by direct solvothermal synthesis using two mixed (–NO2, –SO3H) terephthalate linkers followed by post-synthesis reduction to the NH2 form, which showed excellent performance for a one-pot tandem deacetalization–ni…
High-quality few-layer-thick graphitic carbon nitride (g-C 3 N 4 ) nanosheets (NSs) were fabricated by a simple, highly efficient, and rapid method namely, liquid ammonia (LA)-assisted lithiation.
A three-dimensional graphene/nickel composite electrode with a hierarchical porous structure is developed to simultaneously boost the bio- and electro-catalysis for high-performance microbial fuel cells.
A multifunctional nanomedicine combining magnetic resonance imaging (MRI) and photodynamic therapy (PDT) functionalities is a promising integrated platform that allows for targeted drug delivery, noninvasive monitoring of therapeutic responses, and simultaneous cancer diagnosis and treatment. A hybrid nanoparticle (NP…