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Morphological effect on swelling behaviour of hydrogel

Norzita Yacob、Kamaruddin Hashim2014-01-01AIP conference proceedings

Hydrogels are hydrophilic polymer networks that are capable of imbibing large amounts of water. In this work, hydrogels prepared from natural and synthetic polymers were irradiated by using electron beam irradiation. The morphology of hydrogel inter-polymeric network (IPN) was investigated using Scanning Electron Micr…

Hydrogels: synthesis, properties, applicationsTextile materials and evaluationsPolymer Nanocomposite Synthesis and Irradiation

Adaptive Finite Element Approximations for Kohn--Sham Models

Huajie Chen、Xiaoying Dai、Xingao Gong 等 5 位作者2014-01-01Multiscale Modeling and Simulation

The Kohn--Sham model is a powerful, widely used approach for computation of ground state electronic energies and densities in chemistry, materials science, biology, and nanoscience. In this paper, we study adaptive finite element approximations for the Kohn--Sham model. Based on the residual-type a posteriori error es…

Advanced Chemical Physics StudiesMagnetism in coordination complexesGas Dynamics and Kinetic Theory

Temperature-dependent reaction between trimethylaluminum and poly(methyl methacrylate) during sequential vapor infiltration: experimental and ab initio analysis

Erinn C. Dandley、Craig D. Needham、Philip S. Williams 等 6 位作者2014-01-01Journal of Materials Chemistry C

We propose a temperature dependent reaction scheme between trimethylaluminum and poly(methyl methacrylate) for enhanced control of vapor phase polymer modification.

Semiconductor materials and devicesOrganic Light-Emitting Diodes ResearchSynthesis and properties of polymers

pH-responsive hydrogel cubes for release of doxorubicin in cancer cells

Veronika Kozlovskaya、Jun Chen、Chrysanty Tedjo 等 9 位作者2014-01-01Journal of Materials Chemistry B

We report on a novel type of shaped hydrogel microparticles which undergo large, rapid, and reversible volume changes in response to solution pH. The cubic hydrogels are produced as interconnected poly(methacrylic acid) (PMAA) network replicas of mesoporous manganese oxide templates by sequential infiltration of (PMAA…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsPolymer Surface Interaction Studies

High-performance hydrogen evolution electrocatalysis by layer-controlled MoS 2 nanosheets

Jiao Deng、Wentao Yuan、Pengju Ren 等 7 位作者2014-01-01RSC Advances

Layer-controlled MoS 2 nanosheets, directly prepared through a facile and scalable chemical method, exhibit a significant layer number effect on the hydrogen evolution reaction (HER).

Electrocatalysts for Energy ConversionAdvanced Photocatalysis Techniques2D Materials and Applications

The enhanced catalytic performance of cobalt catalysts towards butadiene polymerization by introducing a labile donor in a salen ligand

Dirong Gong、Baolin Wang、Xiaoyu Jia 等 4 位作者2014-01-01Dalton Transactions

A family of cobalt complexes supported by a tridentate Schiff base ligand with a labile donor (O, S, N) as a pendant arm (Co1-Co12, formulated as CoL2) were synthesized by the treatment of the corresponding ligands with cobalt acetate tetrahydrate. The resultant complexes were well characterized by elemental analysis,…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Structural limitations for optimizing garnet-type solid electrolytes: a perspective

Wolfgang G. Zeier2014-01-01Dalton Transactions

Lithium ion batteries exhibit the highest energy densities of all battery types and are therefore an important technology for energy storage in every day life. Today's commercially available batteries employ organic polymer lithium conducting electrolytes, leading to multiple challenges and safety issues such as poor…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Phase transition of a perovskite strongly coupled to the vacuum field

Shaojun Wang、Arkadiusz Mika、James A. Hutchison 等 7 位作者2014-01-01Nanoscale

The hysteresis and dynamics of the phase transition of the perovskite salt [Pb(II)I4(2-),(C12H25NH3(+))2] is shown to be significantly modified when strongly coupled to the vacuum field inside a micro-cavity. The transition barrier is increased and the hysteresis loop is enlarged, demonstrating the potential of contro…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesStrong Light-Matter Interactions

Experimental and Mathematical Studies on the Drug Release Properties of Aspirin Loaded Chitosan Nanoparticles

Yixiang Shi、Ajun Wan、Yifei Shi 等 5 位作者2014-01-01BioMed Research International

The study of drug release dynamic is aiming at understanding the process that drugs release in human body and its dynamic characteristics. It is of great significance since these characteristics are closely related to the dose, dosage form, and effect of the drugs. The Noyes-Whitney function is used to represent how t…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsAdvanced Drug Delivery Systems

One-pot controllable synthesis of oligo(carbonate-ether) triol using a Zn-Co-DMC catalyst: the special role of trimesic acid as an initiation-transfer agent

Shunjie Liu、Yusheng Qin、Xuesi Chen 等 5 位作者2014-01-01Polymer Chemistry

Oligo(carbonate-ether) triol with controllable M n and CU was synthesized by using TMA as a novel chain initiation-transfer agent catalyzed by Zn-Co-DMC.

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisChemical Synthesis and Reactions

Influence of interfacial rheology on drainage from curved surfaces

M. Saad Bhamla、Caroline E. Giacomin、Caroline Balemans 等 4 位作者2014-01-01Soft Matter

Thin lubrication flows accompanying drainage from curved surfaces surround us (e.g., the drainage of the tear film on our eyes). These draining aqueous layers are normally covered with surface-active molecules that render the free surface viscoelastic. The non-Newtonian character of these surfaces fundamentally alters…

Surfactants and Colloidal SystemsBlood properties and coagulationPickering emulsions and particle stabilization

Synthesis of poly(2-hydroxyethyl methacrylate-co-acrylic acid)-grafted graphene oxide nanosheets via reversible addition–fragmentation chain transfer polymerization

Masoumeh Nikdel、Mehdi Salami‐Kalajahi、Mahdi Hosseini2014-01-01RSC Advances

Natural graphite was oxidized via the Hummer's method and sonicated to obtain graphene oxide (GO). A three-step modification process was performed to attach a reversible addition–fragmentation chain transfer (RAFT)-agent onto the GO surface and obtain GO-RAFT nanosheets. RAFT polymerization of 2-hydroxyethyl methacryl…

Graphene research and applicationsPolymer Nanocomposite Synthesis and IrradiationGraphene and Nanomaterials Applications

Structure inherited synthesis of N-doped highly ordered mesoporous Nb 2 O 5 as robust catalysts for improved visible light photoactivity

Hui Huang、Chao Wang、Jie Huang 等 6 位作者2014-01-01Nanoscale

Highly ordered N-doped mesoporous niobium oxide (NMNb) was prepared via a facile solid state reaction method using urea as a nitrogen source. The mesoporous structure of niobium oxide (MNb) is beneficial to the N dopant that is effectively incorporated into the lattice of MNb, resulting in a significantly enhanced vis…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsAdvanced Nanomaterials in Catalysis

Organo-mineral interactions in contrasting soils under natural vegetation

Edward J. Jones、Balwant Singh2014-01-01Frontiers in Environmental Science

Organo-mineral interactions are important for the cycling and preservation of organic carbon (OC) in soils. To understand the role of soil mineral surfaces in organo-mineral interactions, we used a sequential density fractionation procedure to isolate 2.6 g cm-3 density fractions from topsoils (0-10 cm) of contrasting…

Soil Carbon and Nitrogen DynamicsSoil and Water Nutrient DynamicsClay minerals and soil interactions

A facile and efficient preparation of anatase titania nanoparticles in micelle nanoreactors: morphology, structure, and their high photocatalytic activity under UV light illumination

Reza Abazari、Ali Reza Mahjoub、Soheila Sanati2014-01-01RSC Advances

Comparative photocatalysis degradation of MB dye under ultraviolet light irradiation: (a) without photocatalyst; (b) commercial P25 TiO 2 powder; and (c) TiO 2 nanoparticles.

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Investigation of ionic liquids for efficient removal and reliable storage of radioactive iodine: a halogen-bonding case

Chuanyu Yan、Tiancheng Mu2014-01-01Physical Chemistry Chemical Physics

A series of ionic liquids (ILs) were investigated for removal and storage of radioactive iodine (I2) waste released by nuclear power plants. The I2 removal efficiency of ILs was dependent upon the anion species while cation species seemed to have little influence. Particularly, the I2 removal efficiency of [Bmim][Br]…

Ionic liquids properties and applicationsRadioactive element chemistry and processingCovalent Organic Framework Applications