Materials Literature
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Today, organic dyes are one of the largest groups of pollutants release into environment especially from textile industry. It is highly toxic and hazardous to the living organism; thus, the removal of these dyes prior to discharge into the environment is essential. Varieties of techniques have been employed to degrade…
Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconversions to be underst…
The evolution of electronic structures, properties and stabilities of neutral and cationic molybdenum encapsulated germanium clusters (Mo@Ge n , n = 1 to 20) has been investigated.
BACKGROUND: Bacteria of the genus Sulfobacillus are found worldwide as members of microbial communities that accelerate sulfide mineral dissolution in acid mine drainage environments (AMD), acid-rock drainage environments (ARD), as well as in industrial bioleaching operations. Despite their frequent identification in…
Herein, both experimental evidence and density functional theory analysis are used to explore the interactions between IL and chitosan.
Reports of molecular and cellular imaging using computed tomography (CT) are rapidly increasing. Many of these reports use gold nanoparticles. Bismuth has similar CT contrast properties to gold while being approximately 1000-fold less expensive. Herein we report the design, fabrication, characterization, and CT and fl…
A new highly selective colorimetric chemosensor 1 shows exclusive response toward cyanide by a color change in aqueous solution.
Sheetlike tin disulfide (SnS2) single crystal exposed with well-defined {001} facets and flowerlike SnS2mainly exposed with {010} facets were prepared through a surfactant-free solvothermal process. Photocatalytic degradation of methyl orange (MO) under visible light irradiation indicated that the sheetlike SnS2showed…
A novel series of photobase generators (PBGs), which are quaternary ammonium salts of phenylglyoxylic acid (PA) having the ability to generate strong bases such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) or 1,1,3,3-tetramethylguanidine (TMG), was synthesized.
We report here a joint experimental and theoretical study of a quadrupolar, two-branched pyridinium derivative of interest as a potential non-linear optical material. The spectral and photophysical behaviour of this symmetric system is greatly affected by the polarity of the medium. A very efficient photoinduced intra…
Amine functionalization of multiwall carbon nanotubes improves mechanical properties, enhances ostoeblast proliferation and mineralization, and imparts bactericidal properties in polycaprolactone composites.
Si/TiO 2 heterojunction photocatalyst was synthesized via a facile hydrothermal reaction and exhibits high photocatalytic activity towards conversion of CO 2 to methanol.
Visible light induced photocatalytic mechanism of Au@Ag@ZnO core–shell nanostructure and kinetics of methyl orange (MO) photo degradation by ZnO, Au@ZnO, Au@Ag@ZnO and TiO 2 .
We have developed a 40-MHz, 64-element phased-array transducer packaged in a 2.5 x 3.1 mm endoscopic form factor. The array is a forward-looking semi-kerfed design based on a 0.68Pb(Mg(1/3)Nb(2/3))O(3) - 0.32PbTiO3 (PMN-32%PT) single-crystal wafer with an element-to-element pitch of 38 µm. To achieve a miniaturized fo…
In bulk materials, defects are usually considered to be unwanted since deviations from perfect lattices may degrade device performance. Interestingly, the presence of defects throws open new possibilities in the case of nanostructures due to the properties related to their limited size scale. Defects and disorders whi…
A new, simple and scalable synthesis methodology is invented for an N-self-doped graphene-based non-precious Fe catalyst (Fe–N-graphene) for the oxygen reduction reaction (ORR) both in acidic and alkaline media. The electrochemical characterization shows that this Fe–N-graphene catalyst possesses outstanding electroca…
A series of thiophene/phenylene co-oligomers containing π-conjugated anthracene, naphthalene, and biphenyl central cores have been developed as new organic laser active materials. Light-emitting organic field-effect transistors (LE-OFETs) based on 2,6-bis(5-phenylthiophen-2-yl)anthracene (BPTA), 2,6-bis(5-phenylthioph…
To enhance the uniformity of correlated color temperature (CCT) and luminous flux, we integrated ZrO2 nanoparticles into white light-emitting diodes. This novel packaging scheme led to a more than 12% increase in luminous flux as compared to that in conventional dispensing structures. This was attributed to the scatte…
Herein, we report a rapid route for the synthesis of AlPO4-5. By combining fast heating in a tubular reactor with a seed-assisted method, both of which were found to be crucial, the preparation of AlPO4-5 was completed in one minute, making this route the fastest known for the preparation of the crystalline microporou…
Au–Ag alloy nanoparticles on titania exhibit superior photocatalytic performance in selective oxidation of methanol to methyl formate.