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High stable post-spinel NaMn 2 O 4 cathode of sodium ion battery

Xizheng Liu、Xi Wang、Akira Iyo 等 6 位作者2014-01-01Journal of Materials Chemistry A

A CaFe 2 O 4 -type NaMn 2 O 4 has been synthesized at a pressure of 4.5 Gpa, as the cathode of SIBs. It exhibits a smooth voltage profile, limited polarization and good capacity retention both at room temperature and at a higher temperature. The stable battery performance is due to the high barrier of structure rearra…

Advancements in Battery MaterialsFerroelectric and Piezoelectric MaterialsAdvanced Battery Materials and Technologies

Recent advances in wrinkle-based dry adhesion

Yudi Rahmawan、Chi‐Mon Chen、Shu Yang2014-01-01Soft Matter

Surface wrinkles driven by elastic instabilities have attracted significant interest in the field of materials science and engineering. They are simple and readily fabricated with various patterns of tunable size, morphology and surface topography from a wide range of material systems. Recently, they have been investi…

Surface Modification and SuperhydrophobicityAdvanced Materials and MechanicsAdhesion, Friction, and Surface Interactions

Amine end-functionalized poly(2-ethyl-2-oxazoline) as promising coating material for antifouling applications

Lutz Tauhardt、Marion Frant、David Pretzel 等 12 位作者2014-01-01Journal of Materials Chemistry B

H NMR spectroscopy and MALDI-TOF-MS as well as XPS and contact angle measurements. In a next step, the coatings were exposed to the simultaneous attack of five different bacteria in synthetic river water. A clear reduction of the biofilm formation was observed. In addition, the stability of the coatings against therma…

Polymer Surface Interaction StudiesMarine Biology and Environmental ChemistryAntimicrobial agents and applications

In vitro application of Mn-ferrite nanoparticles as novel magnetic hyperthermia agents

Antonios Makridis、Konstantina Topouridou、Magdalini Tziomaki 等 9 位作者2014-01-01Journal of Materials Chemistry B

Manganese ferrite nanoparticles were synthesized by a facile, low-cost, environmentally friendly and high yield methodology based on the aqueous co-precipitation of proper salts. Firstly, structural, morphological and magnetic characterization schemes were performed to determine crucial factors for optimizing their he…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

A model of ideal elastomeric gels for polyelectrolyte gels

Jianyu Li、Zhigang Suo、Joost J. Vlassak2014-01-01Soft Matter

The concept of the ideal elastomeric gel is extended to polyelectrolyte gels and verified using a polyacrylamide-co-acrylic acid hydrogel as a model material system. A comparison between mixing and ion osmosis shows that the mixing osmosis is larger than the ion osmosis for small swelling ratios, while the ion osmosis…

Hydrogels: synthesis, properties, applicationsPolymer Nanocomposites and PropertiesElectrostatics and Colloid Interactions

Construction of muscle-like metallo-supramolecular polymers from a pillar[5]arene-based [c2]daisy chain

Lingyan Gao、Zibin Zhang、Bo Zheng 等 4 位作者2014-01-01Polymer Chemistry

A muscle-like metallo-supramolecular polymer based on a solvent-driven [ c 2]daisy chain has been prepared from an amino-modified pillar[5]arene. The integration of terpyridine moieties on both ends of the [ c 2]daisy chain and the stiff architecture of pillar[5]arene units facilitated the efficient formation of the m…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Unique Characteristics of the Pyrrolysine System in the 7th Order of Methanogens: Implications for the Evolution of a Genetic Code Expansion Cassette

Guillaume Borrel、Nadia Gaci、Pierre Peyret 等 6 位作者2014-01-01Archaea

Pyrrolysine (Pyl), the 22nd proteogenic amino acid, was restricted until recently to few organisms. Its translational use necessitates the presence of enzymes for synthesizing it from lysine, a dedicated amber stop codon suppressor tRNA, and a specific amino-acyl tRNA synthetase. The three genomes of the recently prop…

Genomics and Phylogenetic StudiesRNA and protein synthesis mechanismsEnzyme Structure and Function

Growth of 2D sheets of a MOF on graphene surfaces to yield composites with novel gas adsorption characteristics

Ram Kumar、Kolleboyina Jayaramulu、Tapas Kumar Maji 等 4 位作者2014-01-01Dalton Transactions

Homogeneous graphene-MOF composites based on a 2D pillared-bilayer MOF (Cd-PBM), {[Cd4(azpy)2(pyrdc)4(H2O)2]·9H2O}n (azpy = 4,4'-azopyridine, pyrdc = pyridine-2,3-dicarboxylate), have been synthesized, using both graphene oxide (GO) and benzoic acid functionalized graphene (BFG). The composites GO@Cd-PBM and BFG@Cd-PB…

Graphene research and applicationsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

DNA and aptamer stabilized gold nanoparticles for targeted delivery of anticancer therapeutics

Alfonso Latorre、Christian Posch、Yolanda Garcimartín 等 11 位作者2014-01-01Nanoscale

Gold nanoparticles (GNPs) can be used as carriers of a variety of therapeutics. Ideally, drugs are released in the target cells in response to cell specific intracellular triggers. In this study, GNPs are loaded with doxorubicin or AZD8055, using a self-immolative linker which facilitates the release of anticancer the…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

A 3D scaffold for ultra-sensitive reduced graphene oxide gas sensors

Yong Ju Yun、Won G. Hong、Nak-Jin Choi 等 9 位作者2014-01-01Nanoscale

An ultra-sensitive gas sensor based on a reduced graphene oxide nanofiber mat was successfully fabricated using a combination of an electrospinning method and graphene oxide wrapping through an electrostatic self-assembly, followed by a low-temperature chemical reduction. The sensor showed excellent sensitivity to NO2…

Graphene research and applicationsGas Sensing Nanomaterials and SensorsAnalytical Chemistry and Sensors

Glypican-3 antibody functionalized Prussian blue nanoparticles for targeted MR imaging and photothermal therapy of hepatocellular carcinoma

Zhenglin Li、Yongyi Zeng、Da Zhang 等 9 位作者2014-01-01Journal of Materials Chemistry B

MRI-guided photothermal therapy is becoming a more widely accepted minimally invasive technique. In this study, glypican-3 monoclonal antibody functionalized Prussian blue nanoparticles (antiGPC3-PBNPs) were developed as a novel theranostic agent for the targeted MR imaging and photothermal therapy of hepatocellular c…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsPhotoacoustic and Ultrasonic Imaging

Fractionation of an ECM hydrogel into structural and soluble components reveals distinctive roles in regulating macrophage behavior

Peter F. Slivka、Christopher L. Dearth、Timothy J. Keane 等 8 位作者2014-01-01Biomaterials Science

Extracellular matrix (ECM) derived from mammalian tissues has been utilized to repair damaged or missing tissue and improve healing outcomes. More recently, processing of ECM into hydrogels has expanded the use of these materials to include platforms for 3-dimensional cell culture as well as injectable therapeutics th…

Electrospun Nanofibers in Biomedical ApplicationsUrological Disorders and TreatmentsTissue Engineering and Regenerative Medicine

Enzyme-catalyzed in situ forming gelatin hydrogels as bioactive wound dressings: effects of fibroblast delivery on wound healing efficacy

Yunki Lee、Jin Woo Bae、Jin Woo Lee 等 5 位作者2014-01-01Journal of Materials Chemistry B

) concentrations. The GH-soft hydrogel was capable of facilitating the proliferation of DFBs and the synthesis of extracellular components, as compared to GH-hard hydrogels. In addition, the subcutaneously injected GH-soft hydrogel with bioluminescent reporter cells provided enhanced cell survival and local retention…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments3D Printing in Biomedical Research

Tailoring the physicochemical properties of zeolite catalysts

Jeffrey D. Rimer、Manjesh Kumar、Rui Li 等 5 位作者2014-01-01Catalysis Science & Technology

Here we summarize our recent findings in the area of zeolite synthesis, focusing on pathways to control crystallization in the absence of organics, tailoring crystal habit with growth modifiers, and pioneering techniques in zeolite surface science to elucidate the mechanisms of growth.

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Hydrodesulfurization Studies

Growth of boronic acid based two-dimensional covalent networks on a metal surface under ultrahigh vacuum

Sylvain Clair、Mathieu Abel、L. Porte2014-01-01Chemical Communications

The formation of atomically precise covalent networks directly on a surface is a promising approach to produce single layers of two-dimensional organic materials (2D polymers). In the emerging field of on-surface synthesis, there is an urgent need for finding a rationale to new reaction pathways taking place directly…

Graphene research and applicationsCovalent Organic Framework ApplicationsSurface Chemistry and Catalysis

Synthesis and Characterization of Titanium Oxide Nanomaterials Using Sol-Gel Method

Stotaw Talbachew Hayle2014-01-01American Journal of Nano Research and Applications

This paper reports the effect of temperature on the properties of TiO_2 nanomaterials, synthesis and characterization. TiO2 powders were synthesized by sol-gel method using TiCl4 solution added in deionized water in ice bath under fume hood followed by the addition of ethanol with vigorous stirring for 30 min at room…

TiO2 Photocatalysis and Solar CellsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis