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Tailoring the physicochemical properties of zeolite catalysts

Jeffrey D. Rimer、Manjesh Kumar、Rui Li 等 5 位作者2014-01-01Catalysis Science & Technology

Here we summarize our recent findings in the area of zeolite synthesis, focusing on pathways to control crystallization in the absence of organics, tailoring crystal habit with growth modifiers, and pioneering techniques in zeolite surface science to elucidate the mechanisms of growth.

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Hydrodesulfurization Studies

Growth of boronic acid based two-dimensional covalent networks on a metal surface under ultrahigh vacuum

Sylvain Clair、Mathieu Abel、L. Porte2014-01-01Chemical Communications

The formation of atomically precise covalent networks directly on a surface is a promising approach to produce single layers of two-dimensional organic materials (2D polymers). In the emerging field of on-surface synthesis, there is an urgent need for finding a rationale to new reaction pathways taking place directly…

Graphene research and applicationsCovalent Organic Framework ApplicationsSurface Chemistry and Catalysis

Synthesis and Characterization of Titanium Oxide Nanomaterials Using Sol-Gel Method

Stotaw Talbachew Hayle2014-01-01American Journal of Nano Research and Applications

This paper reports the effect of temperature on the properties of TiO_2 nanomaterials, synthesis and characterization. TiO2 powders were synthesized by sol-gel method using TiCl4 solution added in deionized water in ice bath under fume hood followed by the addition of ethanol with vigorous stirring for 30 min at room…

TiO2 Photocatalysis and Solar CellsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

A multifunctional perylenediimide derivative (DTPDI) can be used as a recyclable specific Hg 2+ ion sensor and an efficient DNA delivery carrier

Kelan Liu、Zejun Xu、Meizhen Yin 等 7 位作者2014-01-01Journal of Materials Chemistry B

A multifunctional perylenediimide derivative ( DTPDI ) can be used as a recyclable specific Hg 2+ ion sensor and an efficient DNA delivery carrier.

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Effects of CO2 and pH on Growth of the Microalga Dunaliella salina

Kezhen Ying2014-01-01Journal of Microbial & Biochemical Technology

A potentially cost-effective and scalable method to stabilize pH in microalgal batch cultures is proposed in this study. The cultures were supplied with different concentrations of CO 2 enriched gas and controlled amounts of bicarbonate were added. An empirical model correlating the equilibrium pH to bicarbonate and C…

Catalytic Processes in Materials ScienceAlgal biology and biofuel production

Thermally-stable resistive switching with a large ON/OFF ratio achieved in poly(triphenylamine)

Wenbin Zhang、Cheng Wang、Gang Liu 等 12 位作者2014-01-01Chemical Communications

Thermally stable poly(triphenylamine) (PTPA) synthesized by an oxidative coupling reaction is used as the functional layer in memory devices, which exhibit non-volatile bistable resistive switching behavior with a large ON/OFF ratio over 5 × 10(8), a long retention time exceeding 8 × 10(3) s and a wide working tempera…

Advanced Memory and Neural ComputingConducting polymers and applicationsNeuroscience and Neural Engineering

Modulation of upconversion luminescence in Er3+, Yb3+-codoped lanthanide oxyfluoride (YOF, GdOF, LaOF) inverse opals

Tao Li、Wen Xu、Yongsheng Zhu 等 9 位作者2014-01-01Journal of Materials Chemistry C

In this work, novel upconversion lanthanide oxyfluoride (LnOF:Yb3+, Er3+, Ln = La, Y, Gd) inverse opal photonic crystals (IOPCs) were successfully fabricated by the sol–gel method combined with polymethylmethacrylate (PMMA) template technique and the modulation of the photonic stop band (PSB) on the green emissions 2H…

Luminescence Properties of Advanced MaterialsPhotonic Crystals and ApplicationsRandom lasers and scattering media

Effect of Mg and Ca Treatment on Behavior and Particle Size of Inclusions in Bearing Steels

Wenjun Ma、Yanping Bao、Min Wang 等 4 位作者2014-01-01ISIJ International

The effect of Mg and Ca treatment on the behavior and the particle size of inclusions in bearing steels were studied by industrial experiments and thermodynamic calculations. The results showed that the excess addition of Mg wires is not conducive to control the total oxygen content in bearing steel because of the sec…

Metallurgical Processes and ThermodynamicsMetal Alloys Wear and PropertiesMaterials Engineering and Processing

Gate-Bias Stress Stability of P-Type SnO Thin-Film Transistors Fabricated by RF-Sputtering

I-Chung Chiu、I‐Chun Cheng2014-01-01IEEE Electron Device Letters

The gate-bias stress stability of p-type tin monoxide (SnO) thin-film transistors (TFTs) is investigated. The SnO TFT exhibits a threshold voltage of 2.5 V, a field-effect hole mobility of 0.24 cm2V-1s-1, a sub-threshold swing of 2 V/decade, and an ON/OFF current ratio of 103. Under gate-bias stress, the transfer char…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

Poly(N-isopropylacrylamide) microgels at the oil–water interface: temperature effect

Zifu Li、Walter Richtering、To Ngai2014-01-01Soft Matter

Understanding the interfacial properties of soft poly(N-isopropylacrylamide) (PNIPAM) microgels covering an oil-water interface is essential for engineering stimuli-responsive emulsions stabilized by soft microgel particles. This study presents a systematic study on the interfacial properties of the PNIPAM-microgel-la…

Hydrogels: synthesis, properties, applicationsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

The bioinspired construction of an ordered carbon nitride array for photocatalytic mediated enzymatic reduction

Jian Liu、Rémi Cazelles、Zupeng Chen 等 6 位作者2014-01-01Physical Chemistry Chemical Physics

A carbon nitride array (CNA) material has been constructed using a sacrificial diatom template. A regular carbon nitride nanorod array could be replicated from the periodic and regular nanochannel array of the template. The directional charge transport properties and high light harvesting capability of the CNA gives m…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsAdvanced Nanomaterials in Catalysis

Design of yolk–shell Fe 3 O 4 @PMAA composite microspheres for adsorption of metal ions and pH-controlled drug delivery

Linling Zhao、Huarong Liu、Fengwei Wang 等 4 位作者2014-01-01Journal of Materials Chemistry A

Yolk–shell structured pH-responsive Fe 3 O 4 @PMAA microspheres have been prepared for adsorption of metal ions and drug delivery by combined sol–gel reaction, emulsion polymerization and selective etching methods accompanying hydrolysis of PMMA shells of core–shell–shell Fe 3 O 4 @SiO 2 @PMMA composite microspheres.

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsNanomaterials for catalytic reactions

Wellbore leakage mitigation using engineered biomineralization

Alfred B. Cunningham、A. J. Phillips、E. Troyer 等 7 位作者2014-01-01Energy Procedia

Research on microbially induced calcite precipitation (MICP) is reported. MICP may serve to reduce near-wellbore permeability, reduce CO 2 – related corrosion, and lower the risk of unwanted migration of CO 2 or other fluids. MICP research on the lab scale has demonstrated the ability to seal sandstone cores using inj…

Corrosion Behavior and InhibitionMicrobial Applications in Construction MaterialsGrouting, Rheology, and Soil Mechanics

Development of surfactant coacervation in aqueous solution

Meina Wang、Yilin Wang2014-01-01Soft Matter

Coacervation is a phenomenon in which a colloidal dispersion separates into two immiscible liquid phases: a liquid rich in colloidal phase in equilibrium with another diluted liquid phase. Surfactant coacervation here refers to coacervation whose main components are surfactants with low molecular weights. Over the pas…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Chemically Deposited SnSe Thin Films: Thermal Stability and Solar Cell Application

Enue Barrios‐Salgado、M. T. S. Nair、P. K. Nair2014-01-01ECS Journal of Solid State Science and Technology

Compact and specularly reflective tin(II)selenide (SnSe) thin films 100–310 nm in thickness are deposited on Na 2 S-treated glass substrates from a chemical bath containing tin(II)chloride, triethanolamine, sodium hydroxide, and sodium selenosulfate. These thin films are of orthorhombic crystalline structure, which re…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Challenges in modelling homogeneous catalysis: new answers from ab initio molecular dynamics to the controversy over the Wacker process

András Stirling、Nisanth N. Nair、Agustı́ Lledós 等 4 位作者2014-01-01Chemical Society Reviews

We present here a review of the mechanistic studies of the Wacker process stressing the long controversy about the key reaction steps. We give an overview of the previous experimental and theoretical studies on the topic. Then we describe the importance of the most recent Ab Initio Molecular Dynamics (AIMD) calculatio…

Advanced Chemical Physics StudiesMolecular Junctions and NanostructuresMachine Learning in Materials Science

The Effect of Thickness on Optical Band Gap and N-type Conductivity of CuInS2 Thin Films Annealed in Air Atmosphere

M. Ben Rabeh、Nawel Khedmi、M.A. Fodha 等 4 位作者2014-01-01Energy Procedia

Structural, electrical and optical properties of CuInS2 thin films of various thicknesses, grown on heated glass substrates at 100 °C by thermal evaporation method were studied. These films were annealed in air atmosphere at temperature of 200 °C. The thickness of the CIS films was varied from 436 to 80 nm. It was fou…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Anode modification with capacitive materials for a microbial fuel cell: an increase in transient power or stationary power

Chunhua Feng、Zhisheng Lv、Xiao-Shuang Yang 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

Extensive efforts have been devoted to improve the anode performance of a microbial fuel cell (MFC) by using modified carbon-based anode materials, but most of them did not recognize that the power performance measured by the commonly-used varying circuit resistance (VCR) or linear sweep voltammetry (LSV) method was o…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsMicrobial Fuel Cells and Bioremediation