Materials Literature
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The properties of isomeric azulene derivatives, substituted through the 5-membered ring, were examined using a combination of experimentation and theoretical calculations for a series of well-defined electroactive oligomers.
Cu + -doped MIL-101 was synthesized, and its application in the separation of olefin–paraffin was investigated for the first time.
Light-emitting electrochemical cells (LECs) containing [Cu(POP)(N^N)][PF6] (POP = bis(2-diphenylphosphinophenyl)ether, N^N = 6-methyl- or 6,6'-dimethyl-2,2'-bipyridine) exhibit luminance and efficiency surpassing previous copper(I)-containing LECs.
Electrical properties of TiO 2 /CH 3 NH 3 PbI 3 heterojunction solar cells.
The p K a 1 values and NBO charges of 32 carboxylate ligands and 31 N -heterocyclic ligands were calculated at 298.15 K with the B3LYP/6-31+G(d,p) level of calculations, which are useful to understand the water and thermal stability of Metal–Organic Frameworks (MOFs).
Microfluidics offers great tools to produce highly-controlled dispersions of gas into liquid, from isolated bubbles to organized microfoams. Potential technological applications are manifold, from novel materials to scaffolds for tissue engineering or enhanced oil recovery. More fundamentally, microfluidics makes it p…
The ability to precisely tune the chemical compositions and electronic structures of nanoalloy catalysts is essential to achieve the goals of high activity and selectivity for the oxygen reduction reaction (ORR) on the catalysts by design. In this work, we synthesized carbon-supported Pt-Co alloy nanoparticles with co…
We report an efficient route for the sonochemical synthesis of undoped BiPO4, Ag3PO4 and silver doped BiPO4:Ag(x%) (x = 2, 5, 10 and 20) nanostructures using bismuth/silver nitrate and ammonium dihydrogen phosphate as precursors. The products obtained have been characterized using X-ray diffraction (XRD), scanning ele…
Chemical functionalization can be used to tune optoelectronic properties of indigoids, their stability and semiconductor performance in OFETs.
Plants of Brassica juncea L. var. RLC-1 were exposed for 30 days to different concentrations (0, 0.2, 0.4, and 0.6 mM) of cadmium (Cd) to analyze the Cd uptake, H2O2 content, hormonal profiling, level of photosynthetic pigments (chlorophyll, carotenoid, and flavonoid), gaseous exchange parameters (photosynthetic rate,…
Nanostructured niobium oxide (NO) semiconductors are gaining increasing attention as electronic, optical, and electro-optic materials. However, the preparation of stable NO nanofilms with reproducible morphology and behavior remains a challenge. Here we show a rapid, well-controlled, and efficient way to synthesize NO…
In problems of indentation of an elastic half-space by a rigid sphere, the effects of surface tension outside the contact zone are not accounted for by classical theories of contact mechanics. However surface tension plays a dominant role in determining the mechanics of this adhesive contact when the half-space become…
In-doped Bi2Se3 hierarchical nanostructures have been synthesized by an in situ cation exchange route from their template of In3Se4 nanostructures. Through detailed structural, chemical, and morphological characterizations, it has been found that, after the cation exchange, the In-doped Bi2Se3 hierarchical nanostructu…
We report a new approach of using dispersed water phase gelation as a mode to create oil continuous emulsion gels. Low temperature gelation property of synergistic hydrocolloid combinations was exploited to develop elastic soft solids using only food-grade components.
We have developed a new synthesis strategy to prepare ∼5 nm metallic silver nanoparticles (AgNPs) supported on tungsten oxide (WO3) nanorods with diameters between 40 and 60 nm in the presence of a cationic surfactant, cetyltrimethylammonium bromide (CTAB). The catalyst was characterized by XRD, XPS, ICP-AES, FT-IR, R…
Initial charge–discharge profiles of PTPA and PDDP with two obvious voltage platforms, and the possible electron donating–accepting process during the two charge–discharge stages.
INHIBIT logic gates based on light-driven β-cyclodextrin pseudo[1]rotaxane were conveniently fabricated in aqueous solution utilizing induced circular dichroism (ICD) and photocontrolled reversible room temperature phosphorescence (RTP) as output addresses respectively.
Hybrid NiO–g-C 3 N 4 photocatalyst shows excellent photostability and enhanced visible-light-driven activity for MB degradation. The improved activity is attributed to the effective separation of charge carriers.
The success of waste management requires accurate data on generation and composition of waste which is pivotal for the decisions towards the appropriate waste management system. At present there is no data available on Municipal Solid Waste (MSW) generation and composition collected systematically in Oman. Hence, this…
Platinum (Pt) nanosheets were developed by exfoliating layered platinum oxide. Moreover, we succeeded in synthesizing monolayer Pt nanosheets for the first time by adjusting the conditions for reduction. Monolayer Pt nanosheets were highly active in oxygen reduction reaction.