Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Oligodeoxynucleotides containing an alkylporphyrin linked to the phosphate groups of DNA via oxypropyl chains have been synthesized. To our knowledge, these are the first porphyrin−nucleic acid conjugates bearing the porphyrin embedded in the backbone of DNA. Chain assembly was achieved by automated solid-phase synthe…
The structure and thermal decomposition of unsupported and titania-supported 12-phosphoromolybdic acid (HPMo) and its Co and Ni salts have been studied by different techniques including X-ray diffraction, thermogravimetric analysis, FT-infrared, Raman, and X-ray spectroscopic techniques. The transformation of heteropo…
Describing the theoretical aspects of chemistry and microstructure that affect mechanical properties, this work offers coverage of ceramic mechanical property measurement techniques for use in component design as well as lifetime and reliability predictions. It presents procedures from both room- and elevated-temperat…
The photoluminescence behavior of single crystals of Tl[Ag(CN) 2 ] has been studied as a function of temperature. The 10 K spectra show a broad emission centered at about 420 nm and two excitation maxima at 301 and 314 nm. Exciting with each of these maxima gives a different temperature dependence for the correspondin…
There are many clinical situations in which a large tissue mass is required to replace tissue lost to surgical resection (e.g., mastectomy). It is possible that autologous cell transplantation on biodegradable polymer matrices may provide a new therapy to engineer large tissue which can be used to treat these patients…
We propose a new method for (global) Hurst exponent determination based on wavelets. Using this method, we analyze synthetic data with predefined Hurst exponents, fracture surfaces and data from economy. The results are compared with those obtained from Fourier spectral analysis. When many samples are available, the w…
“Naked” colloidal gold solutions have been prepared in toluene using a two-phase system. The phase-transfer reagent used, a quaternary ammonium bromide salt (R 4 N + Br - ), is specifically adsorbed on the clusters through the formation of surface ion pairs, probably with the Br - ion attached to the Au surface. The s…
An unusual luminescent inorganic oxide, Sr2CeO4, was identified by parallel screening techniques from within a combinatorial library of more than 25,000 members prepared by automated thin-film synthesis. A bulk sample of single-phase Sr2CeO4 was prepared, and its structure, determined from powder x-ray diffraction dat…
X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) have been used to characterize a series of Cu/Cr/Al 2 O 3 catalysts prepared by stepwise incipient wetness impregnation of first chromium followed by copper (designated “CuCr y ”). The copper loading was held constant at 8 wt % CuO, and chromium loadin…
Catalytic epoxidation of olefins with H2O2 and t-BuOOH has been studied in the presence of a water-soluble iron(III) porphyrin complex, (5,10,15,20-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinato)iron(III) [Fe(TDCPPS)], in buffered aqueous solutions. Epoxides are the predominant products at low pH values, and the f…
The X-ray structures of the two monodimensional systems of formula [Mn(L) 2 (N 3 ) 2 ] n in which L = 3-ethylpyridine ( 1 ) or 2-hydroxypyridine ( 2 ) have been determined. Crystal data: 1, formula C 14 H 18 MnN 8, monoclinic P 2 1 / n, a = 10.210(5) Å, b = 15.460(6) Å, c = 10.880(4) Å, β = 95.86(3)°, Z = 4; 2, formul…
Mono- and multilayers of cadmium sulfide (CdS) nanoparticles were fabricated on a gold substrate covered with alkanedithiol self-assembled monolayers (SAMs) by an alternate immersion of the substrate into ethanolic solutions of dithiol, i.e., 1,6-hexanedithiol or 1,10-decanedithiol, and dispersion of CdS nanoparticles…
The magnetic properties of spinel nanoparticles are determined by crystal chemistry issues such as cation distribution and oxidation states. The cation distribution and oxidation state of Mn−Fe spinel nanoparticles have been systematically studied at various temperatures by using neutron diffraction and electron energ…
Abstract The cyclopalladation of 1,1′‐azonaphthalene (= di(naphthalen‐1‐yl)diazene; 2 ) with bis(hexafluoroacetyl‐acetonato)palladium(II) (3; [Pd(hfa) 2 ]) yields the ortho ‐palladated complex (1,1,1,5,5,5‐hexafluoropentane‐2,4‐dionato‐κ 2 O , O ′)[1‐(naphthalen‐1‐ylazo‐κ N 2 )naphthalen‐2‐yl‐κ C 2 ]palladium(II) ( 4…
Three different types of polynuclear Mn II complexes with carboxylate bridges were obtained from the reaction of Mn(RCOO) 2 with 2,2‘-bipyridine (bpy). Dinuclear complexes [Mn 2 (μ-RCOO) 2 (bpy) 4 ](ClO 4 ) 2 with R = 2-ClPh, 3-ClPh, 4-ClPh, Ph ( 1 − 4 ); trinuclear complexes [Mn 3 (μ-RCOO) 6 (bpy) 2 ] with R = 2-ClPh…
The polyvalent cations Mg2+, Zn2+, and Al3+ were intercalated into V2O5 aerogel to a maximum concentration of 4, 2.5, and 3.33 equiv, respectively, per mole of V2O5. The intercalation was reversible in each case, analogous to the intercalation of Li+ ions. Pillaring of the host facilitates the intercalation process.
Using a near-field scanning optical microscope capable of quantitative polarimetry, we map the anisotropic strain fields associated with individual submicron defects near the fusion boundaries of SrTiO$_{3}$ bicrystals. Many defects exhibit unexpected spiral-shape strain patterns, whose handedness is believed to be li…
The interactions of several water-soluble ionic porphyrins with different ionic or neutral surfactants in aqueous solutions were studied as a function of surfactant concentration. The interaction leads to the formation of porphyrin aggregates and/or micelle-encapsulated monomers with the exception of those porphyrin−s…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
A correlation between the orientation of [TCNE] • - (TCNE = tetracyanoethylene) bound to a [Mn III (por)] + (por = substituted meso -tetraphenylporphyrin) and the magnitude of magnetic coupling for a series of previously prepared [Mn(por)][TCNE]·2PhMe linear-chain molecule-based ferrimagnets has been identified. The t…