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Upconversion from aqueous phase lanthanide chelates

Xudong Xiao、Jeanne P. Haushalter、Gregory W. Faris2005-07-01Optics Letters

We have prepared and characterized several lanthanide ion complexes of multidentate ligands or chelates in an effort to develop new upconverting luminescent labels that can be immune to autofluorescence and photobleaching. This study has involved the characterization of various chelates of Nd, Er, and Tm with respect…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesLanthanide and Transition Metal Complexes

Effect of Oil Palm Empty Fruit Bunch and Acrylic Impact Modifier on Mechanical Properties and Processability of Unplasticized Poly(Vinyl Chloride) Composites

A. Abu Bakar、Azman Hassan、Ahmad Fuad Mohd Yusof2005-07-01Polymer-Plastics Technology and Engineering

Interest in the use of natural fibers as fillers has grown over the past few years due to the advantages it offers. The use of oil palm empty fruit bunch (EFB) as a filler in the unplasticized poly(vinyl chloride) (PVC-U) is a new attraction in polymer composite technology. The objectives of this study are to investig…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

The Relationship between Steady Shear Viscosity and Complex Viscosity

Shu‐Ping Li、Ge Zhao、Hong‐Yuan Chen2005-07-01Journal of Dispersion Science and Technology

Theoretical analysis on the relationship of complex viscosity (η*) and steady shear viscosity (η) indicates that viscous viscosity (η′) measured under linear viscoelastic region equates with steady shear viscosity at low shear rates, and the Cox‐Merz Rule applies only to the suspension whose viscous viscosity of the s…

Polymer Nanocomposites and PropertiesSurfactants and Colloidal SystemsLayered Double Hydroxides Synthesis and Applications

Role of Compatibilization in Recycling Rubber Waste by Blending with Plastics

D. Mangaraj2005-07-01Rubber Chemistry and Technology

Abstract Blending ground rubber with thermoplastic and thermoset polymers is a very cost effective and efficient method for recycling rubber waste. However it is important for vulcanized rubber particles and the thermoplastic matrix to adhere to each other to form co-continuous type morphology to provide necessary str…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

The Effect of Oxygen Vacancies in the Early Stages of BaTiO3 Nanopowder Sintering

Roni D. Levi、Yoed Tsur2005-07-01Advanced Materials

The influence of process atmosphere during sintering is an aspect of nanopowder processing that has not been widely investigated. Reducing the chemical potential of oxygen promotes the beginning of sintering in nanopowder particles of a model oxide material. The importance of oxygen vacancies is shown by both sinterin…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisElectronic and Structural Properties of Oxides

Deposition of Ru Thin Films from Supercritical Carbon Dioxide Fluids

Eiichi Kondoh2005-07-01Japanese Journal of Applied Physics

Ruthenium has been of interest for application in ULSI capacitor electrodes and more recently as a barrier metal against Cu diffusion. Thin-film deposition from supercritical CO 2 has gained particular attention as a new deposition technique that provides nano-penetration capability and a possibility of developing new…

Catalytic Processes in Materials SciencePhase Equilibria and ThermodynamicsIonic liquids properties and applications

Methods of Detecting Fouling Caused by Heating of Milk

Sangeeta Prakash、Nivedita Datta、Hilton C. Deeth2005-07-01Food Reviews International

Fouling is the deposition of milk solids on heat transfer surfaces, particularly heat exchangers. It is a major industrial problem, which causes a decrease in heat transfer efficiency and shortens run times. The resultant effect is a decrease in process efficiency and economy. For studying and monitoring deposit forma…

Calcium Carbonate Crystallization and InhibitionElectrohydrodynamics and Fluid DynamicsMagnetic and Electromagnetic Effects

Elastomers: A Literature Review with Emphasis on Oil Resistance

Abhimanyu O. Patil、Thomas Coolbaugh2005-07-01Rubber Chemistry and Technology

Abstract There has been a long-standing commercial desire for elastomers with a high degree of oil-resistance. For example, oil-resistant materials are very important to the automotive industry since a variety of components may come into contact with a number of fluids (hydrocarbon and otherwise). In the specific case…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Surface Structure and Energetics of Hydrogen Adsorption on the Fe(111) Surface

Chun‐Fang Huo、Yongwang Li、Jianguo Wang 等 4 位作者2005-07-01The Journal of Physical Chemistry B

Spin-polarized density functional theory calculations have been performed to characterize the hydrogen adsorption and diffusion on the Fe(111) surface at 2/3-, 1-, and 2-monolayer (ML) coverages. It is found that the most favored adsorption site for atomic hydrogen (H) is the top-shallow bridge site (tsb), followed by…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceHydrogen Storage and Materials

Corrosion inhibition of triethanolammonium bromide mono‐ and dibenzoate as cationic inhibitors in an acidic medium

Nabel A. Negm、S.M. Morsy2005-07-01Journal of Surfactants and Detergents

Abstract A weight loss technique was used to determine the corrosion inhibition efficiency of synthesized alkyl mono‐and dibenzoate triethanolammonium bromide derivatives (TEAMB, TEADB) in an acidic medium (2 N HCl) at different doses (50, 100, and 200 ppm). The results showed that monoderivatives had a higher corrosi…

Corrosion Behavior and InhibitionPetroleum Processing and AnalysisConcrete Corrosion and Durability

An evaluation of thermochromic prints based on microencapsulated liquid crystals using variable temperature colour measurement

Robert Christie、Iain David Bryant2005-07-01Coloration Technology

A variable temperature colour measurement technique has been developed to characterise the temperature-dependent colour change, known as ‘colour play’, observed with thermochromic prints based on microencapsulated liquid crystals. The effect is most pronounced over a black background. The liquid crystals exhibiting th…

Liquid Crystal Research AdvancementsPlant and animal studiesPhotochromic and Fluorescence Chemistry

Borderline Class II/III Ligand-Centered Mixed Valency in a Porphyrinic Molecular Rectangle

Peter H. Dinolfo、Suk Joong Lee、Veaceslav Coropceanu 等 5 位作者2005-07-01Inorganic Chemistry

A molecular rectangle of the form ([Re(CO)(3)](2)BiBzIm)(2)-mu,mu'-(LL)(2), where BiBzIm is 2,2'-bisbenzimidazolate and LL are cofacially aligned [5,15-bis(4-ethynylpyridyl)-10,20-bis(n-hexyl)-porphyrinato]zinc ligands, has been examined via electrochemical, spectroelectrochemical, and electronic Stark effect methods.…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesMetal-Catalyzed Oxygenation Mechanisms

<title>Micromachined IR-source with excellent blackbody like behaviour (Invited Paper)</title>

W. Konz、J. Hildenbrand、Marie‐Luise Bauersfeld 等 7 位作者2005-07-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

There are several micro sized thermal emitters commercially available, but compared with an ideal black body radiator, their emissivity and thus the emitted radiation is moderate. This was the motivation to develop a novel type of micromachined thermal IR-emitters. The main difference compared with common thermal micr…

Photonic Crystals and ApplicationsSilicon Nanostructures and PhotoluminescenceThermal Radiation and Cooling Technologies

A microscopical study of diatom phytoplankton in deep crater Lake El'gygytgyn, Northeast Siberia

Holger Cremer、Bernd Wagner、O. Juschus 等 4 位作者2005-07-01Algological Studies/Archiv für Hydrobiologie Supplement Volumes

Abstract : A survey of the planktonic diatom community was carried out during summer2003 in Lake El’gygytgyn, a deep, cold, low conductive and oligotrophic crater lake inthe Northeast Siberian Arctic. Five planktonic diatom species were identified: Cy-clostephanos dubius , Cyclotella ocellata , Cyclotella tripartita ,…

Climate change and permafrostDiatoms and Algae ResearchGeological Studies and Exploration

Polar anchoring energy measurement of vertically aligned liquid-crystal cells

Xiangyi Nie、Yi‐Hsin Lin、Thomas Wu 等 6 位作者2005-07-01Journal of Applied Physics

An electric-field method is developed for measuring the polar anchoring energy of vertically aligned nematic liquid-crystal cells. Both theoretical analyses and confirming experimental results are presented. Vertically aligned liquid-crystal cells with buffed polyimide alignment layers are used to investigate the meas…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Strength, elasticity, and equation of state of the nanocrystalline cubic silicon nitrideγ−Si3N4to68GPa

Boris Kiefer、S. R. Shieh、T. S. Duffy 等 4 位作者2005-07-01Physical Review B

Lattice strains in nanocrystalline cubic silicon nitride were measured using an energy-dispersive x-ray diffraction technique under nonhydrostatic stress conditions up to a confining pressure of $68\phantom{\rule{0.3em}{0ex}}\mathrm{GPa}$. The high-pressure elastic properties of $\ensuremath{\gamma}\text{\ensuremath{-…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

Electro-optical and dielectric relaxation studies of an antiferroelectric liquid-crystal mixture (W-132A)

Abhishek Kumar Srivastava、Veena Agrawal、R. Dąbrowski 等 5 位作者2005-07-01Journal of Applied Physics

Electro-optical properties and dielectric relaxation phenomenon have been investigated for antiferroelectric liquid-crystal mixture W-132A exhibiting SmA*, SmC*, and wide temperature range (∼0–48°C) induced SmCA* phases. Spontaneous polarization, tilt angle, response time, viscosity, relaxation frequency, dielectric s…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

Dielectric Relaxation in Cellulose and its Derivatives

Adam Rachocki、Ewa Markiewicz、Jadwiga Tritt‐Goc2005-07-01Acta Physica Polonica A

The relaxation processes in cellulose, methyl cellulose, hydroxypropyl cellulose, and hydroxypropylmethyl cellulose were studied by dielectric spectroscopy. The dielectric spectra for these polysaccharides were measured in the frequency range from 100 Hz to 1 MHz and in the temperature range from 100 to 450 K. The die…

Liquid Crystal Research AdvancementsHigh voltage insulation and dielectric phenomenaAdvanced Cellulose Research Studies

The planar-to-tubular structural transition in boron clusters from optical absorption

Miguel A. L. Marques、Silvana Botti2005-07-01The Journal of Chemical Physics

The optical response of the lowest-energy isomers of the B20 family is calculated using time-dependent density-functional theory within a real-space, real-time scheme. Significant differences are found among the absorption spectra of the clusters studied. We show that these differences can be easily related to changes…

2D Materials and ApplicationsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Roles of Hydrophobicity and Volatility of Organic Substrates on Sonolytic Kinetics in Aqueous Solutions

Zhilin Wu、Bernd Ondruschka2005-07-01The Journal of Physical Chemistry A

The aquasonolytic rate constants of cyclic C6H(X), aliphatic C6H(X), thioethers, thiophenes, and N-heterocyclic compounds show over a 90-fold variation under identical conditions of ultrasonic irradiations. Henry's Law constant of the substrate has a substantial effect on the aquasonolytic rate; a higher Henry's Law c…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging