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Multicycle water vapour stability of microporous breathing MOF aluminium isophthalate CAU-10-H

Dominik Fröhlich、Stefan K. Henninger、Christoph Janiak2014-01-01Dalton Transactions

The hydrothermal stability of aluminium hydroxide isophthalate MOF CAU-10-H was proven, under humid multi-cycling conditions. Detailed in situ thermogravimetric measurements and in situ powder X-ray diffraction analysis during water ad-/desorption were used. A reversible structural change during adsorption was detecte…

Metal-Organic Frameworks: Synthesis and ApplicationsIndustrial Gas Emission ControlMagnesium Oxide Properties and Applications

ALUMINIUM METAL MATRIX COMPOSITES - A REVIEW

B. Vijaya Ramnath、C. Elanchezhian、Thanniru Shanmukhi Sai Sri 等 5 位作者2014-01-01OpenAlex

Aluminium matrix composites (AMCs) are potential materials for various applications due to their good physical and mechanical properties. The addition of reinforcements into the metallic matrix improves the stiffness, specific strength, wear, creep and fatigue properties com- pared to the conventional engineering mate…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMetallurgical and Alloy Processes

Water sensitivity of layered P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 cathode material

Daniel Buchholz、Luciana Gomes Chagas、Christoph Vaalma 等 5 位作者2014-01-01Journal of Materials Chemistry A

The interlayer distance calculated with the Bragg equation identifies the sodium content below which the spontaneous hydration of P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 occurs.

Advancements in Battery MaterialsFerroelectric and Piezoelectric MaterialsTransition Metal Oxide Nanomaterials

Co 3 O 4 nanowires supported on 3D N-doped carbon foam as an electrochemical sensing platform for efficient H 2 O 2 detection

Minmin Liu、Shuijian He、Wei Chen2014-01-01Nanoscale

Using a simple hydrothermal procedure and a subsequent annealing treatment, one-dimensional (1D) cobalt oxide nanowires (Co3O4-NWs) with tunable size have been successfully in situ fabricated on a three-dimensional (3D) carbon foam (CF) network. By changing the hydrothermal treatment time (0.5, 1, or 2 h) at 180 °C, s…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

A highly permeable polyimide with enhanced selectivity for membrane gas separations

Yulia Rogan、Richard Malpass‐Evans、Mariolino Carta 等 11 位作者2014-01-01Journal of Materials Chemistry A

Introducing the highly rigid ethanoanthracene unit into polyimides of intrinsic microporosity provides an impressive enhancement of gas selectivity by molecular sieving.

Graphene research and applicationsMembrane Separation and Gas TransportSynthesis and properties of polymers

A convenient method to prepare a novel alkali metal sodium doped carbon nitride photocatalyst with a tunable band structure

Jian Zhang、Shaozheng Hu、Yanjuan Wang2014-01-01RSC Advances

Sodium doped into a g-C 3 N 4 crystal lattice can tune the position of CB and VB potentials, influence the structural and optical properties, and thus improve the Rhodamine B photodegradation and mineralization performances.

Advanced Photocatalysis TechniquesZnO doping and propertiesElectronic and Structural Properties of Oxides

Carbon dioxide conversion into hydrocarbon fuels on defective graphene-supported Cu nanoparticles from first principles

Dong‐Hee Lim、Jun Ho Jo、Dong Yun Shin 等 6 位作者2014-01-01Nanoscale

Density functional theory studies demonstrate that defective graphene-supported Cu nanoparticles can modify the structural and electronic properties of copper for enhancing electrochemical reduction of carbon dioxide (CO2) into hydrocarbon fuels (CH4, CO, and HCOOH). We not only provide improved understanding of CO2 c…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationCO2 Reduction Techniques and Catalysts

A swivel-cruciform thiophene based hole-transporting material for efficient perovskite solar cells

Krishnamoorthy Thirumal、Kunwu Fu、Pablo P. Boix 等 11 位作者2014-01-01Journal of Materials Chemistry A

A novel swivel-cruciform 3,3′-bithiophene based hole-transporting material (HTM) with a low lying highest occupied molecular orbital (HOMO) level for application in perovskite solar cells were synthesized.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Transmitarray Antenna Design Using Cross-Slot Elements With No Dielectric Substrate

Ahmed H. Abdelrahman、Atef Z. Elsherbeni、Fan Yang2014-01-01IEEE Antennas and Wireless Propagation Letters

The transmitarray antenna has received considerable attention in recent years as it combines the favorable features of the lens antenna and the array techniques. The goal of this letter is to present detailed design analysis of a multiple-conductor-layers transmitarray antenna using slot-type element with no dielectri…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Star-shaped Pd@Pt core–shell catalysts supported on reduced graphene oxide with superior electrocatalytic performance

Youngmin Kim、Yuseong Noh、Eun Ja Lim 等 6 位作者2014-01-01Journal of Materials Chemistry A

A surfactantless, one-pot reduction approach for Pd@Pt core–shell nano-stars on reduced graphene oxide with enhanced catalytic activity and stability for methanol oxidation in alkaline media.

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Sodium superionic conduction in Na₂B₁₂H₁₂

Terrence J. Udovic、Motoaki Matsuo、Atsushi Unemoto 等 9 位作者2014-01-01Chemical Communications

Impedance measurements indicate that Na₂B₁₂H₁₂ exhibits dramatic Na⁺ conductivity (on the order of 0.1 S cm⁻¹) above its order-disorder phase-transition at ≈529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes. Superionicity may be aided by the large size, quasispherical shape, and high…

Advanced Battery Materials and TechnologiesHydrogen Storage and MaterialsAdvanced battery technologies research

Three-dimensional hierarchical MoS 2 nanoflake array/carbon cloth as high-performance flexible lithium-ion battery anodes

Hailong Yu、Chunling Zhu、Kai Zhang 等 8 位作者2014-01-01Journal of Materials Chemistry A

3D hierarchical MoS 2 nanoflake array/carbon cloth is synthesized with a thickness of MoS 2 nanoflakes <15 nm. A full Li battery based on the cloth exhibits good electrochemical performance and high flexibility.

Advancements in Battery MaterialsSupercapacitor Materials and Fabrication2D Materials and Applications

Surfactant-free synthesis of a Fe3O4@ZIF-8 core–shell heterostructure for adsorption of methylene blue

Jun Zheng、Chao Cheng、Weijun Fang 等 7 位作者2014-01-01CrystEngComm

Nanoscale porous metal–organic frameworks and related materials have received considerable attention in recent years due to their widespread applications. However, the effective synthesis of magnetic core–shell MOFs still remains a significant challenge. In this article, a Fe3O4@ZIF-8 core–shell nanostructure with uni…

Metal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersCovalent Organic Framework Applications

Synthesis of metal–organic frameworks by continuous flow

Peter A. Bayliss、Ilich A. Ibarra、Eduardo Pérez 等 7 位作者2014-01-01Green Chemistry

MIL-53(Al) can be prepared via reaction in continuous flow in only 5–6 minutes with a space time yield of 1300 kg m −3 d −1 . Extraction of free terephthalic acid from within the pores of MIL-53(Al) using supercritical ethanol has been developed.

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Enhanced photoelectrochemical water splitting by nanostructured BiVO4–TiO2 composite electrodes

SocMan Ho‐Kimura、Savio J. A. Moniz、Albertus D. Handoko 等 4 位作者2014-01-01Journal of Materials Chemistry A

A novel wide spectrum responsive BiVO4–TiO2 junction composite photoanode has been successfully synthesized by a simple, solution-based metal–organic decomposition (MOD) method. The photocurrent was increased by ∼4 times using the junction with respect to bare BiVO4 under 100 mW cm−2 illumination, resulting in ∼5-fold…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications