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Naturally occurring phenolic sources: monomers and polymers

Bimlesh Lochab、Swapnil Shukla、I. K. Varma2014-01-01RSC Advances

Phenolic compounds sourced from agro-based feedstock, viz. cashew nut shell liquid, lignin, tannin, palm oil, and coconut shell tar, have come up as sustainable alternatives to petro-based feedstock. This review explores their utility as green polymer feedstock with citation of ~ 600 references.

Natural Fiber Reinforced CompositesPolymer composites and self-healingLignin and Wood Chemistry

Criteria for solvate ionic liquids

Toshihiko Mandai、Kazuki Yoshida、Kazuhide Ueno 等 5 位作者2014-01-01Physical Chemistry Chemical Physics

Certain concentrated mixtures of salts and solvents are not simply "solutions" anymore, but they may be described as "ionic liquids". In this perspective paper, we describe possible criteria for the new family of ionic liquids: "solvate" ionic liquids. This subclass of ionic liquids was originally proposed by Angell e…

Advanced Battery Materials and TechnologiesIonic liquids properties and applicationsPolyoxometalates: Synthesis and Applications

Facile synthesis of very-long silver nanowires for transparent electrodes

Jinting Jiu、Teppei Araki、J. Wang 等 12 位作者2014-01-01Journal of Materials Chemistry A

Silver nanowires >60 μm have been synthesized using a polyol process without stirring at 130 °C.

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Sensor and Energy Harvesting MaterialsNanomaterials and Printing Technologies

Polymorphism in cocrystals: a review and assessment of its significance

Srinivasulu Aitipamula、Pui Shan Chow、Reginald B. H. Tan2014-01-01CrystEngComm

Cocrystals have gained much interest in recent years owing to their potential to improve the physicochemical properties of the parent compounds. It was once thought that cocrystals could be a means to prevent polymorphism but many recent examples of cocrystal polymorphism have been discovered and reported. Similar to…

Crystallography and molecular interactionsEnergetic Materials and CombustionCrystallization and Solubility Studies

Nanoparticles for multimodal in vivo imaging in nanomedicine

James F. Leary、Jaehong Key2014-01-01International Journal of Nanomedicine

While nanoparticles are usually designed for targeted drug delivery, they can also simultaneously provide diagnostic information by a variety of in vivo imaging methods. These diagnostic capabilities make use of specific properties of nanoparticle core materials. Near-infrared fluorescent probes provide optical detect…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsPhotoacoustic and Ultrasonic Imaging

Multi-shelled CeO 2 hollow microspheres as superior photocatalysts for water oxidation

Jian Qi、Kun Zhao、Guodong Li 等 7 位作者2014-01-01Nanoscale

A general self-templating method is introduced to construct triple-shelled CeO₂ hollow microspheres, which are composed of tiny CeO₂ nanoparticles. When the triple-shelled CeO₂ hollow microspheres are used as photocatalysts for direct water oxidation with AgNO₃ as the electron scavenger, excellent activity and enhance…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

Electrospun Na3V2(PO4)3/C nanofibers as stable cathode materials for sodium-ion batteries

Jun Liu、Kun Tang、Kepeng Song 等 6 位作者2014-01-01Nanoscale

Sodium-ion batteries are considered as prime alternatives to lithium-ion batteries for large-scale renewable energy storage units due to their low cost and the abundance of sodium bearing precursors in the earth's mineral deposits. In the current work, a 3D NASICON framework Na3V2(PO4)3/carbon cathode electrode with 2…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Mixed solvents for the optimization of morphology in solution-processed, inverted-type perovskite/fullerene hybrid solar cells

Hak-Beom Kim、Hyosung Choi、Jaeki Jeong 等 7 位作者2014-01-01Nanoscale

We investigate mixed solvents of N,N-dimethylformamide (DMF) and γ-butyrolactone (GBL) to produce the smooth surface of a perovskite film and uniform crystal domains. This ideal morphology from mixed solvents enhances the power conversion efficiency to over 6% by improving the exciton dissociation efficiency and reduc…

Perovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsConducting polymers and applications

Inherent anchorages in UiO-66 nanoparticles for efficient capture of alendronate and its mediated release

Xiangyang Zhu、Jinlou Gu、Yao Wang 等 7 位作者2014-01-01Chemical Communications

Zr-based MOF nanoparticles were applied as efficient carriers for alendronate delivery, and an unprecedented drug loading capacity was achieved thanks to the inherent drug anchorages of Zr-O clusters therein. The encapsulated drug featured with a pH-dependent release profile, and inhibited the growth of cancer cells m…

Metal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersBoron Compounds in Chemistry

Efficient planar-heterojunction perovskite solar cells achieved via interfacial modification of a sol–gel ZnO electron collection layer

Junghwan Kim、Geunjin Kim、Tae Kyun Kim 等 9 位作者2014-01-01Journal of Materials Chemistry A

The importance of interfacial engineering as a new strategy for improving the power conversion efficiencies (PCEs) of planar-heterojunction (PHJ) perovskite solar cells is highlighted by incorporating sol–gel ZnO modified with PCBM.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

A thermally derived and optimized structure from ZIF-8 with giant enhancement in CO 2 uptake

Srinivas Gadipelli、Will Travis、Wei Zhou 等 4 位作者2014-01-01Energy & Environmental Science

Post-synthesis thermal annealing of ZIF-8 close to its framework decomposition temperature below 550 °C results in a modified structure with highly enhanced and stable cyclic CO 2 adsorption capacity of over 1.5 mmol g −1 at 25 °C and 1 bar of CO 2 , which is over 100% greater than that of initial ZIF-8.

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications

An Eu 3+ post-functionalized nanosized metal–organic framework for cation exchange-based Fe 3+ -sensing in an aqueous environment

You Zhou、Hao Chen、Bing Yan2014-01-01Journal of Materials Chemistry A

Highly luminescent MIL-53–COOH (Al) nanocrystals were fabricated by post-functionalization with Eu 3+ , which demonstrates super selectivity and sensitivity in detection of Fe 3+ in aqueous solutions.

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionAdvanced Nanomaterials in Catalysis

SARA ATRP or SET-LRP. End of controversy?

Dominik Konkolewicz、Yu Wang、Pawel Krys 等 7 位作者2014-01-01Polymer Chemistry

A debate has proceeded in the literature regarding the mechanism of reversible-deactivation radical polymerization in the presence of Cu0. The two proposed models are supplemental activator and reducing agent atom transfer radical polymerization (SARA ATRP) and single electron transfer living radical polymerization (S…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Fast Li-ion conduction in poly(ethylene carbonate)-based electrolytes and composites filled with TiO 2 nanoparticles

Yoichi Tominaga、Kenta Yamazaki2014-01-01Chemical Communications

We have found remarkable ion-conductive properties in a novel polymer electrolyte composed of poly(ethylene carbonate) and Li bis-(fluorosulfonyl) imide. The self-diffusion coefficient of Li-ions exceeded 10(-7) cm(2) s(-1) and the Li transference number was estimated to be more than 0.8 in composites filled with only…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance

Taiqiang Chen、Yong Liu、Likun Pan 等 8 位作者2014-01-01Journal of Materials Chemistry A

A simple and scalable electrospinning process followed by thermal treatment was used to fabricate carbon nanofibers (CFs). The as-prepared CFs were investigated as anode materials for sodium ion batteries (SIBs). Remarkably, due to their weakly ordered turbostratic structure and a large interlayer spacing between grap…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

High efficiency single-junction semitransparent perovskite solar cells

Cristina Roldán‐Carmona、Olga Malinkiewicz、Rafael Betancur 等 8 位作者2014-01-01Energy & Environmental Science

Semitransparent efficient methylammonium lead iodide perovskite based solar cells.

Perovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsConducting polymers and applications

Third-generation solar cells: a review and comparison of polymer:fullerene, hybrid polymer and perovskite solar cells

Junfeng Yan、Brian R. Saunders2014-01-01RSC Advances

Third-generation solar cells have excellent potential for delivering large scale, low-cost solar electricity. We review and compare the current understanding of the operation principles, performance improvements and future prospects for polymer:fullerene, hybrid polymer and perovskite solar cells.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Temperature-responsive hydrogel with ultra-large solar modulation and high luminous transmission for “smart window” applications

Yang Zhou、Yufeng Cai、Xiao Hu 等 4 位作者2014-01-01Journal of Materials Chemistry A

Thermally responsive hydrogel with a transition temperature of ~32 °C was for the first time studied as a novel candidate in thermochromic application. Unprecedented solar modulating ability (Δ T sol ) of 25.5% and high average luminance transmittance ( T lum ) of 70.7% were achieved.

Perovskite Materials and ApplicationsLiquid Crystal Research AdvancementsAdvanced Sensor and Energy Harvesting Materials

3D-printed magnetic Fe 3 O 4 /MBG/PCL composite scaffolds with multifunctionality of bone regeneration, local anticancer drug delivery and hyperthermia

Jianhua Zhang、Shichang Zhao、Min Zhu 等 7 位作者2014-01-01Journal of Materials Chemistry B

The 3D-printed Fe 3 O 4 /MBG/PCL scaffolds with potential multifunctionality would be promising for use in the treatment and regeneration of large bone defects after tumor resection.

Bone Tissue Engineering MaterialsNanoparticle-Based Drug DeliveryGraphene and Nanomaterials Applications