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The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes

Lei Cheng、Ethan J. Crumlin、Wei Chen 等 16 位作者2014-01-01Physical Chemistry Chemical Physics

Dense LLZO (Al-substituted Li7La3Zr2O12) pellets were processed in controlled atmospheres to investigate the relationships between the surface chemistry and interfacial behavior in lithium cells. Laser induced breakdown spectroscopy (LIBS), scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscop…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Electrochemical CO 2 reduction on Cu 2 O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons

Recep Kaş、Ruud Kortlever、Alexander Milbrat 等 6 位作者2014-01-01Physical Chemistry Chemical Physics

The catalytic activity and hydrocarbon selectivity in electrochemical carbon dioxide (CO2) reduction on cuprous oxide (Cu2O) derived copper nanoparticles is discussed. Cuprous oxide films with [100], [110] and [111] orientation and variable thickness were electrodeposited by reduction of copper(ii) lactate on commerci…

Advanced Thermoelectric Materials and DevicesIonic liquids properties and applicationsCO2 Reduction Techniques and Catalysts

Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4–Pt nanocomposite photocatalysts

Jiaguo Yu、Ke Wang、Wei Xiao 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

Photocatalytic reduction of CO2 into renewable hydrocarbon fuels is an alternative way to develop reproducible energy, which is also a promising way to solve the problem of the greenhouse effect. In this work, graphitic carbon nitride (g-C3N4) was synthesized by directly heating thiourea at 550 °C and then a certain a…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCO2 Reduction Techniques and Catalysts

The extracellular matrix: Structure, composition, age-related differences, tools for analysis and applications for tissue engineering

Jaspreet K. Kular、Shouvik Basu、Ram I. Sharma2014-01-01Journal of Tissue Engineering

The extracellular matrix is a structural support network made up of diverse proteins, sugars and other components. It influences a wide number of cellular processes including migration, wound healing and differentiation, all of which is of particular interest to researchers in the field of tissue engineering. Understa…

Electrospun Nanofibers in Biomedical ApplicationsBone and Dental Protein StudiesTissue Engineering and Regenerative Medicine

Design, synthesis and photophysical studies of dipyrromethene-based materials: insights into their applications in organic photovoltaic devices

André Bessette、Garry S. Hanan2014-01-01Chemical Society Reviews

This review article presents the most recent developments in the use of materials based on dipyrromethene (DPM) and azadipyrromethenes (ADPM) for organic photovoltaic (OPV) applications. These chromophores and their corresponding BF2-chelated derivatives BODIPY and aza-BODIPY, respectively, are well known for fluoresc…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Photocatalytic degradation of methylene blue in ZIF-8

Huan-Ping Jing、Chong‐Chen Wang、Yiwen Zhang 等 5 位作者2014-01-01RSC Advances

ZIF-8 was used to perform photocatalytic degradation of methylene blue, a typical organic dye.

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces

Toru Hatsukade、Kendra P. Kuhl、Etosha R. Cave 等 5 位作者2014-01-01Physical Chemistry Chemical Physics

The electrochemical reduction of CO2 could allow for a sustainable process by which renewable energy from wind and solar are used directly in the production of fuels and chemicals. In this work we investigated the potential dependent activity and selectivity of the electrochemical reduction of CO2 on metallic silver s…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCO2 Reduction Techniques and Catalysts

A Critical Review of Modeling Transport Phenomena in Polymer-Electrolyte Fuel Cells

Adam Z. Weber、Rodney L. Borup、Robert M. Darling 等 15 位作者2014-01-01Journal of The Electrochemical Society

Polymer-electrolyte fuel cells are a promising energy-conversion technology. Over the last several decades significant progress has been made in increasing their performance and durability, of which continuum-level modeling of the transport processes has played an integral part. In this review, we examine the state-of…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Recent advances in BiOX (X = Cl, Br and I) photocatalysts: synthesis, modification, facet effects and mechanisms

Liqun Ye、Yurong Su、Xiaoli Jin 等 5 位作者2014-01-01Environmental Science Nano

Photocatalysis technology, using semiconductor nano-materials to decompose toxic pollutants under solar light irradiation, displays great prospects for environmental protection. This review gives an overview of the applications of BiOX (X = Cl, Br and I) photocatalysts for efficient photocatalytic degradation (PCD) re…

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsAdvanced Nanomaterials in Catalysis

High valence 3p and transition metal based MOFs

Thomas Devic、Christian Serre2014-01-01Chemical Society Reviews

This article focuses on high valence 3p and transition metal based metal organic frameworks. In the first part we will discuss the complex solution chemistry of these metals which makes this sub-class of MOFs more of a challenge than the traditional low valence metal based MOFs. This is followed by a short review of t…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMachine Learning in Materials Science

Post-synthetic metalation of metal–organic frameworks

Jack D. Evans、Christopher J. Sumby、Christian J. Doonan2014-01-01Chemical Society Reviews

Post-synthetic metalation (PSMet) offers expansive scope for a targeted approach to tailoring the properties of MOFs. Numerous methods for carrying-out PSMet chemistry have been reported, however, these can be categorized into three general strategies: (a) addition to coordinating groups; (b) counter-ion exchange in c…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesNanocluster Synthesis and Applications

Zeolitic imidazolate framework composite membranes and thin films: synthesis and applications

Jianfeng Yao、Huanting Wang2014-01-01Chemical Society Reviews

Zeolitic imidazolate frameworks (ZIFs), a subclass of metal organic frameworks, are built of tetrahedral metal ions bridged by imidazolates. They have permanent porosity and relatively high thermal and chemical stability, which make them attractive candidates for many industrial applications. In recent years, signific…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

A stretchable strain sensor based on a metal nanoparticle thin film for human motion detection

John J. Lee、Sanghyeok Kim、Jin-Jae Lee 等 7 位作者2014-01-01Nanoscale

Wearable strain sensors for human motion detection are being highlighted in various fields such as medical, entertainment and sports industry. In this paper, we propose a new type of stretchable strain sensor that can detect both tensile and compressive strains and can be fabricated by a very simple process. A silver…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTactile and Sensory Interactions

Magnetic nanomaterials in catalysis: advanced catalysts for magnetic separation and beyond

Liane M. Rossi、Natália J. S. Costa、Fernanda P. Silva 等 4 位作者2014-01-01Green Chemistry

While magnetic separation techniques have long been in use, intensive research into superparamagnetic nanomaterials has accelerated the development of magnetically recoverable catalysts. Preparation techniques are currently undergoing rapid development and magnetic separation has been studied to facilitate the handlin…

Nanoparticle-Based Drug DeliveryCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Long-range correlation energy calculated from coupled atomic response functions

Ambrosetti, Alberto、Reilly, Anthony M.、DiStasio, Robert A. Jr 等 8 位作者2014-01-01Max Planck Digital Library

An accurate determination of the electron correlation energy is an essential prerequisite for describing the structure, stability, and function in a wide variety of systems. Therefore, the development of efficient approaches for the calculation of the correlation energy (and hence the dispersion energy as well) is ess…

Advanced Chemical Physics StudiesQuantum Dots Synthesis And PropertiesMachine Learning in Materials Science

Band-gap tuning of lead halide perovskites using a sequential deposition process

Sneha A. Kulkarni、Tom Baikie、Pablo P. Boix 等 6 位作者2014-01-01Journal of Materials Chemistry A

Demonstration of band-gap tuning of mixed anion lead halide perovskites (MAPb(I 1−x Br x ) 2 (0 ≤ x ≤ 1)) by means of a sequential deposition process.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films