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The emergence of complex behaviours in molecular magnetic materials

Karin Goß、Dante Gatteschi、Lapo Bogani2014-01-01Physical Chemistry Chemical Physics

Molecular magnetism is considered an area where magnetic phenomena that are usually difficult to demonstrate can emerge with particular clarity. Over the years, however, less understandable systems have appeared in the literature of molecular magnetic materials, in some cases showing features that hint at the spontane…

Magnetism in coordination complexesAdvanced Condensed Matter PhysicsOrganic and Molecular Conductors Research

Performance Improvement of PS from Expanded Polystyrene Off-grade

Chatrawee Direksilp、Poonsub Threepopnatkul2014-01-01Energy Procedia

EPS off-grade is commonly known as waste in the manufacturing process of Expanded Polystyrene (EPS). It is worthwhile to recover such waste by improving its properties. However, blowing agent used in the EPS would be a drawback in the recovering process. Our research implemented the improvement by the addition of impa…

Polymer crystallization and propertiesFiber-reinforced polymer compositesRecycling and Waste Management Techniques

New insights into the chemistry of di- and trimetallic iron dithiolene derivatives. Structural, Mössbauer, magnetic, electrochemical and theoretical studies

Sonia Bruña、Isabel Cuadrado、Esther Delgado 等 11 位作者2014-01-01Dalton Transactions

Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted into the known dinuclear compound 1 to afford finally the neutr…

Magnetism in coordination complexesMetalloenzymes and iron-sulfur proteinsOrganic and Molecular Conductors Research

Field-Theoretic Simulations of Multi-Cylinder Configurations in VIA Lithography

Nabil Laachi、Tatsuhiro Iwama、Kris T. Delaney 等 7 位作者2014-01-01Journal of Photopolymer Science and Technology

We have studied the self-assembly of PS-PMMA block copolymers by means of SCFT simulations in elongated templates and established commensurability windows for the formation of single rows of two and three cylindrical VIAs. Our results indicate that VIAS with increasing CD form inside templates of increasing dimensions…

Advancements in Semiconductor Devices and Circuit DesignAdvancements in Photolithography TechniquesBlock Copolymer Self-Assembly

Properties of RF-Sputtered PZT Thin Films with Ti/Pt Electrodes

Yan Cui、Yao Minglei、Zhang Qunying 等 6 位作者2014-01-01International Journal of Polymer Science

Effect of annealing temperature and thin film thickness on properties of Pb(Zr0.53Ti0.47)O3(PZT) thin film deposited via radiofrequency magnetron sputtering technique onto Pt/Ti/SiO2/Si substrate was investigated. Average grain sizes of the PZT thin film were measured by atomic force microscope; their preferred orient…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Synthesis, Thermal Behaviour, XRD, and Luminescent Properties of Lighter Lanthanidethiodipropionate Hydrates Containing Aminogunidine as Neutral Ligand

S. Packiaraj、S. Govindarajan2014-01-01Open Journal of Inorganic Chemistry

Aminoguanidine lanthanide thiodipropionate hydrates of composition [Ln(Agun)2(tdp)3·nH2O], Agun = Aminoguanidine, tdp = thiodipropionic acid, where Ln = La, Pr, Nd and Sm if n = 2, have been prepared and characterized by physic-chemical techniques.

Crystal structures of chemical compoundsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Control of Interface Evolution in Multiphase Fluid Flows

Ľubomír Baňas、Markus Klein、Andreas Prohl2014-01-01SIAM Journal on Control and Optimization

We consider an optimal control problem for the interface in a two-dimensional multiphase fluid problem. The minimization functional consists of two parts: the $L^2$-distance to a given density profile and the interfacial length. We show existence and derive necessary first order optimality conditions for a correspondi…

Solidification and crystal growth phenomenaAdvanced Mathematical Modeling in EngineeringFluid Dynamics and Thin Films

Effect of Sn2+on Anodic Dissolution of Ni in Perchloric Acid

Masahiro Seo、Atsushi Hyono、H. Habazaki 等 4 位作者2014-01-01Journal of The Electrochemical Society

The effect of Sn 2+ on the anodic dissolution of nickel was investigated in deaerated 0.2 M HClO 4 solution containing Sn 2+ at room temperature. It has been found that the addition of 10 −3 M Sn 2+ inhibits completely the anodic dissolution of Ni. In contrast, tin itself is not passivated in 0.2 M HClO 4 irrespective…

Corrosion Behavior and InhibitionSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Conjugated anthracene dendrimers with monomer-like fluorescence

Karl Börjesson、Mélina Gilbert Gatty、Damir Dzebo 等 5 位作者2014-01-01RSC Advances

A series of highly fluorescent conjugated anthracene dendrimers having monomeric emission profile, but still exhibiting fast exciton depolarisation, are here presented.

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Influence of intermolecular interactions on spectroscopic characteristics of metal nanoparticles and their composites

I. I. Shaganov、T. S. Perova、Maria Mukhina 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

In this paper we investigate the possibility to apply the concepts of non-specific intermolecular interactions and dispersive local field effect approach for study of the influence of interactions of metal nanoparticles with matrix molecules on the spectral characteristics of composites. The effect of intermolecular (…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials StudiesLaser-Ablation Synthesis of Nanoparticles

Accelerated Weathering Properties of Hemp Fibre Composites

Asim Shahzad2014-01-01OALib

Properties of hemp fibre reinforced unsaturated polyester composites following exposure to accelerated weathering conditions have been studied. Exposure to ultraviolet (UV) radiation and UV radiation plus condensation resulted in immediate loss in weight which stabilised following prolonged exposure times. The same ex…

Natural Fiber Reinforced CompositesFlame retardant materials and propertiesTextile materials and evaluations

Comparison between Two Separate Injections and a Single Injection of Double-dose Contrast Medium for Contrast-enhanced MR Imaging of Metastatic Brain Tumors

Tomoko Ochi、Toshiaki Taoka、Ryosuke Matsuda 等 11 位作者2014-01-01Magnetic Resonance in Medical Sciences

PURPOSE: As stereotactic radiotherapy (SRT) becomes widespread, precise information including number, location, and margin of lesions is required when magnetic resonance (MR) imaging of brain metastasis is performed. We compare methods using 2 separate injections and a single injection for the administration of a doub…

Advanced Radiotherapy TechniquesAdvanced MRI Techniques and ApplicationsLanthanide and Transition Metal Complexes

Heterogeneous phase formation in diluted magnetic semiconducting Zn 1−x−y Co x Al y O (CAZO) nanoparticles

R. Siddheswaran、Rostislav Medlín、Petr Bělský 等 7 位作者2014-01-01RSC Advances

This article reports a systematic investigation of the synthesis and structural characterization of composite CAZO [(Zn 1−x−y Co x Al y O; x = 0.04, 0.03, 0.02; y = 0.01, 0.02, 0.03)] nanoparticles from combustion.

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Low thermal conductivity of amorphous Si/Si 0.75 Ge 0.25 multilayer films with Au-interlayers

Cong Lin、Zhigang Zeng、F. J. Ye 等 8 位作者2014-01-01Europhysics Letters (EPL)

The cross-plane thermal conductivity of amorphous Si/Si 0.75 Ge 0.25 multilayer films with Au-interlayers prepared by magnetron sputtering was successfully measured using a differential technique at room temperature. Though gold has great thermal conductivity, the samples possess a thermal conductivity of 0.53 W/mK, w…

Thermal properties of materialsPhase-change materials and chalcogenidesSemiconductor materials and interfaces

CdTeO3 Deposited Mesoporous NiO Photocathode for a Solar Cell

Chuan Zhao、Xiaoping Zou、Sheng He2014-01-01Journal of Nanomaterials

Semiconductor sensitized NiO photocathodes have been fabricated by successive ionic layer adsorption and reaction (SILAR) method depositing CdTeO3 quantum dots onto mesoscopic NiO films. A solar cell using CdTeO3 deposited NiO mesoporous photocathode has been fabricated. It yields a photovoltage of 103.7 mV and a shor…

TiO2 Photocatalysis and Solar CellsChalcogenide Semiconductor Thin FilmsTransition Metal Oxide Nanomaterials

High-frequency (20 to 40 MHz) acoustic response of liquid-filled nanocapsules

Sara Jafari、Odile Diou、Jonathan Mamou 等 7 位作者2014-01-01IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

Liquid-core nanoparticles are promising candidates for targeted ultrasound-controlled therapy, but their acoustic detection remains challenging. High-frequency (20 to 40 MHz) tone burst sequences were implemented with a programmable ultrasound biomicroscope to characterize acoustic response from perfluorooctyl bromide…

Ultrasonics and Acoustic Wave PropagationAcoustic Wave Resonator TechnologiesUltrasound and Cavitation Phenomena

Preparation of Silver Nanoparticles by Using Tripropylene Glycol as the Reducing Agents of Polyol Process

Tzu Hsuan Chiang、Kaiyun Wu、Tsung-Eong Hsieh2014-01-01IEEE Transactions on Nanotechnology

Silver (Ag) nanoparticles were prepared by the polyol process using tripropylene glycol, 3-ethyl-3-oxetanemethanol, and polycaprolactone triol as the reducing agents and poly(vinylpyrrolidone) (PVP) with average molecular weights (Mw) of 10 000, 55 000, and 1 300 000 as the protective agent, respectively. It was found…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing Technologies