Materials Literature
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Exponential band edges have been observed in a variety of materials, both crystalline and amorphous. In this Letter, we infer the structural origins of these tails in amorphous and defective crystalline Si by direct calculation with current ab initio methods. We find that exponential tails appear in relaxed models of…
We study theoretically the charge transport pumped by magnetization dynamics through epitaxial FIF and FNIF magnetic tunnel junctions (F: Ferromagnet, I: Insulator, N: Normal metal). We predict a small but measurable DC pumping voltage under ferromagnetic resonance conditions for collinear magnetization configurations…
The spectrally- and polarization-resolved absorption cross-sections of a single gold nanorod have been investigated using the spatial modulation spectroscopy technique. The ensemble of its optical features, that is, longitudinal and transverse surface plasmon resonances and interband absorption, has been quantitativel…
Phase-change materials are successfully employed in optical data storage and are becoming a promising candidate for future electronic storage applications. Despite the increasing technological interest, many fundamental properties of these materials remain poorly understood. However, in the last few years the understa…
The dynamics of a "peeling front" or an elastic line is studied under creep (constant load) conditions. Our experiments show an exponential dependence of the creep velocity on the inverse force (mass) applied. In particular, the dynamical correlations of the avalanche activity are discussed here. We compare various av…
The electronic structure of the magnetic semiconductor Ga$_{1-x}$Cr$_{x}$N and the effect of Si doping on it have been investigated by photoemission and soft x-ray absorption spectroscopy. We have confirmed that Cr in GaN is predominantly trivalent substituting for Ga, and that Cr 3$d$ states appear within the band ga…
The dynamics of magnetization in the presence of spin-transfer torque was studied. We derived the equation for the motion of magnetization in the presence of a spin current by using the local equilibrium assumption in non-equilibrium thermodynamics. We show that, in the resultant equation, the ratio of the Gilbert dam…
This work describes an innovative concept for the development of organized molecular systems thanks to the template effect of the pre-structured semi-conductive SmSi(111) interface. This substrate was selected because Sm deposition in the submonolayer range leads to a 8x2-reconstruction, which is a well-defined one-di…
A method that is used by space-confining NaAlH 4 into the as-synthesized ordered mesoporous silica (OMS) is presented in the present work. NaAlH 4 in the pores of OMS is obtained by impregnation and drying techniques. It has been found that the space-confined NaAlH 4 in the pores of OMS shows the lower temperature and…
Hierarchical, three-fold symmetrical, single-crystalline gold dendrites were synthesized by the reaction between a zinc plate and a solution of HAuCl 4 in the ionic liquid [BMIM][PF 6 ]. The unique dendritic gold nanostructures show a three-order hierarchy (i.e., a three-fold symmetrical <111>-oriented trunk, three gr…
Novel fluorescent, conformationally restricted dipyrromethene boron difluoride (BODIPY) dyes have been prepared by introducing a naphthalenyl group at the meso position of the BODIPY core. These BODIPY dyes exhibit increased fluorescence quantum yields compared with dyes that have a meso-position phenyl group with int…
This paper discusses the formation of nanosized hexagonal tungsten oxide (h-WO 3 ) during the annealing of hexagonal ammonium tungsten bronze (HATB), (NH 4 ) 0.33− x WO 3− y . This process was investigated by TG/DTA-MS, XRD, SEM, Raman, XPS, and 1 H-MAS NMR analyses. Through adjusting the temperature and atmosphere of…
Colloidal Ag nanoparticles coated with L-glutathione attached to bimane chromophores were studied by absorption, circular dichroism (CD), and fluorescence spectroscopies. The absorption and CD spectra were resonantly enhanced by Ag surface plasmons. The wavelength and particle-size dependence of the enhancement indica…
Triggered biodegradable composites made entirely from renewable resources are urgently sought after to improve material recyclability or be able to divert materials from waste streams. Many biobased polymers and natural fibers usually display poor interfacial adhesion when combined in a composite material. Here we pro…
Over 10000 individual trajectories of nonphotobleaching single-walled carbon nanotubes (SWNT) were tracked as they are incorporated into and expelled from NIH-3T3 cells in real time on a perfusion microscope stage. An analysis of mean square displacement allows the complete construction of the mechanistic steps involv…
Cerium (Ce) is a rare earth metal that is not known to have any biological role. Cerium oxide materials of several sizes and shapes have been developed in recent years as a scaffold for catalysts. Indeed even cerium oxide nanoparticles themselves have displayed catalytic activities and antioxidant properties in tissue…
Going for gold: Density functional calculations show how gold nanoparticles are more active catalysts for CO oxidation than other metal nanoparticles. The high catalytic activity of nanosized gold clusters at low temperature is found to be related to the ability of low-coordinate metal atoms to activate reactants.
In this work, ZnO nanofluids were produced by a medium mill with a pH value of about 7.2 and characterized by Nano-Sizer and SEM. After milling, ZnO nanofluids were formed with an average particle size of ∼198.4 nm. The ZnO nanofluids used for testing were stored for different periods (1-, 90- and 120-day) and kept in…
We present the design for an absorbing metamaterial (MM) with near unity absorbance A(omega). Our structure consists of two MM resonators that couple separately to electric and magnetic fields so as to absorb all incident radiation within a single unit cell layer. We fabricate, characterize, and analyze a MM absorber…
To determine the hysteresis loss in a sample, usually the enclosed area of the loop is evaluated. In the drag force method, based on a proper energy balance, the hysteresis loss is obtained by analyzing the drag force profile when slowly moving the sample forward and backward through the strong field of permanent magn…