Materials Literature
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Both one-dimensional two-phase Stefan problems with the thermodynamic equilibrium condition $\theta (R(t),t) = 0$, and with the kinetic rule $\theta (R(t),t) = - \varepsilon \dot R(t)$ at the moving boundary $x = R(t)$ are considered. We study the properties of the regular solutions of the problem with equilibrium con…
The title compounds have an isotypic averaged structure but differ in significant detail with respect to disorder. Disorder diffuse scattering has been studied in situ up to 1150 K with a heating camera and X-ray films and an image-plate system at the synchrotron source Deutsches Elektronensynchrotron/HASYLAB. With th…
Abstract The mechanism of reinforcing rubber with carbon black particles is investigated by comparing the strain energy density functions of pure and reinforced rubbers. Finite deformation biaxial extension experiments are used to measure the strain energy density. The functional form of the reinforced system, which h…
Surface electrode patterns with systematic changes of electrode gap distances and widths have been developed to investigate the averaging effect in the current-voltage ( I-V ) measurements of ZnO varistors. Varistor breakdown voltages, V B , and the nonlinear exponent, α, were obtained from the I-V measurements. The α…
An approach to the R ‐curve behavior of 2‐D woven ceramic matrix composites is proposed. This approach takes into account the presence of a process zone at the crack tip. The strain energy release rate is determined using an equivalent system of two specimens free of process zones. The process zone size is determined…
The penetration performance of uranium alloy kinetic energy (long rod) projectiles are superior to that of equivalent projectiles manufactured from high-density tungsten-based composites. Prior research efforts seeking improvements in the penetration capabilities of tungsten penetrator materials have focussed on incre…
Alloys of Dy0.73Tb0.27Fe2−xNix [0≤x≤2] were prepared and the lattice parameters obtained at room temperature showed a deviation from Vegard’s law owing to the presence of magnetovolume effect. Magnetization studies were carried out up to an applied field of 10 kOe in the temperature range 4.2–750 K. Magnetization data…
An extensive review of recent developments in the synthesis, crystallization, structure and morphology of poly(phenylene sulphide) (PPS) polymers is presented. There has been a vast proliferation of knowledge about such thermoplastic matrix materials and the more important findings are now discussed, mainly for the li…
Abstract The gallium sulphide cubane compounds [(Me 2 EtC)GaS] 4 and [(Et 2 MeC)GaS] 4 , have been synthesised, and their potential as MOCVD precursors for GaS is discussed. The molecular structure of [(Et 2 MeC)GaS] 4 has been determined by X‐ray diffraction. In addition, the vapour phase structure of the GaSe precur…
Abstract The polarizability and hyperpolarizabilities of nitrophenols as model compounds for studying nonlinear optics have been investigated at the Hartree‐Fock level of approximation by means of the Dalgarno Uncoupled Hartree‐Fock (DUHF) or Sum Over Orbitals (SOO) method. The additive character and the charge transf…
Undersaturated and supersaturated zincate solutions have been prepared electrochemically and chemically, and studied using nuclear magnetic resonance (NMR) spectrometry and extended x‐ray absorption fine structure (EXAFS). 67 Zn NMR spectroscopy shows only one resonance line, the area of which first increases with the…
Removal of the foliaceous varices from the shells of Chicoreus dilectus had no significant effect on the crushing strength (load at failure) of the shells, but decreased the total work necessary to break the shells by 35–50%. This effect was due to the removal of varices as an architectural feature of the shell rather…
A neuro‐fuzzy control model has been devised for the next generation of so‐called “intelligent sewing machines”. The model incorporates discrimination of material characteristics to be stitched by automatic determination of their properties. The fabric/machine interactions at different speeds have been computed in the…
In this paper, we present a finite element model for the calculation of zero phase sequence reactance for three phase three leg core type power transformers. An axisymmetrical approximation is assumed. A simplified model is used to assess the tank's hottest spot temperature.>
We present an experiment of densification of a 2D horizontal assembly made of regular pentagons. The annealing leads to a dense crystalline arrangement with quasisixfold symmetry in spite of the geometrical characteristics of the grains and of the a priori short-range correlation length in the packing. This configurat…
The structures of tetra-n-butylammonium bromide,N(C4H9)4Br (abbreviated: 4Br) and tetra-n-butylam-monium iodide, N(C4H9)4I (abbreviated:4I) have been determined. For 4Br: Mw = 322.4 Da, c-centered monoclinic space group C2/c, a = 14.409(5) Å, b = 13.901(2)Å, c = 20.345(9)Å, β= 110.18(3)Å, V =3729.4Å3, Z =8, Dc = 1.148…
Indentation crack‐shape evolution during subcritical crack growth was examined in soda‐lime glass. Crack‐arrest markings were generated on the fracture surfaces by temporary unloading during subcritical crack growth. Crack shapes were determined from these crack‐arrest markings by optical microscopy. The shapes were f…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFurther Gold Aggregation at a Pentanuclear Gold Cluster with Hypercoordinate Interstitial NitrogenKlaus Angermaier and Hubert SchmidbaurCite this: Inorg. Chem. 1995, 34, 11, 3120–3122Publication Date (Print):May 1, 1995Publication History Published online1 May 2002Published…
The semiempirical atom superposition and electron delocalization molecular orbital (ASED-MO) theory was used to study the H-Fe interaction. Calculations were carried out using clusters of the type Fe 35 simulating both the adsorption and the absorption of an H atom on/in the (100) face and in the (100) dislocation. Th…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAddition of Metallic Mercury to Platinum- and Palladium-Gold Cluster Compounds. X-ray Crystal and Molecular Structures of [(Hg)2Pd(AuPPh3)8](NO3)2 and [(Hg)Pt(AuPPh3)8](NO3)2Rachael A. T. Gould, Kathryn L. Craighead, Jack S. Wiley, and Louis H. PignoletCite this: Inorg. Chem…