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Unique Piezochromic Fluorescence Behavior of Dicyanodistyrylbenzene Based Donor–Acceptor–Donor Triad: Mechanically Controlled Photo‐Induced Electron Transfer (eT) in Molecular Assemblies

Min Sang Kwon、Johannes Gierschner、Seong‐Jun Yoon 等 4 位作者2012-08-07Advanced Materials

A novel donor-acceptor-donor triad that exhibits fluorescence on-off switching with high contrast ratio (ca. 10(3) ) in response to a mechanical stimulus in the solid state is reported. This system provides a very unique example of high-contrast fluorescence switching that is driven by a mechanical-force-controlled ph…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Interface Formation in Monolayer Graphene-Boron Nitride Heterostructures

Peter Sutter、R. Cortés、Jayeeta Lahiri 等 4 位作者2012-08-07Nano Letters

The ability to control the formation of interfaces between different materials has become one of the foundations of modern materials science. With the advent of two-dimensional (2D) crystals, low-dimensional equivalents of conventional interfaces can be envisioned: line boundaries separating different materials integr…

Graphene research and applicationsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Role of Solvent Parameters in the Regeneration of Cellulose from Ionic Liquid Solutions

Lauri K. J. Hauru、Michael Hummel、Alistair W. T. King 等 5 位作者2012-08-07Biomacromolecules

The ionic liquids 1-ethyl-3-methylimidazolium acetate [emim]OAc, N,N,N,N-tetramethylguanidium propionate [TMGH]EtCO(2), and N,N,N,N-tetramethylguanidium acetate [TMGH]OAc, and the traditional cellulose solvent N-methylmorpholine N-oxide NMMO were characterized for their Kamlet-Taft (KT) values at several water content…

Advanced Cellulose Research StudiesCatalysis for Biomass ConversionLignin and Wood Chemistry

Coordination-driven synthesis of Ag(I) compounds based on a double emission ligand consisting of 1,3,4-oxadiazole and cyclotriphosphazene units

Xiang-Wen Wu、Xiaoyan Wang、Qinglong Li 等 5 位作者2012-08-06Journal of Coordination Chemistry

A new ligand (L) which consists of cyclotriphosphazene and 1,3,4-oxadiazole units is reported. Two new Ag(I) coordination compounds {[Ag(L)SO3CF3] n (1) and Ag2L2(NO3)2 (2)} based on L and Ag(I) salts are obtained. Compound 1 features a 1-D chain, in which the ligand L adopts a divergent trans-conformation, whereas 2…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Low-temperature, facile fabrication of ultrafine Cu2O networks by anodization on TiO2nanotube arrays

Shenglian Luo、Y Li、Lixia Yang 等 6 位作者2012-08-06Semiconductor Science and Technology

A green and facile process was developed to fabricate ultrafine p-type Cu2O single crystal nanowires by anodizing copper (Cu0) particles preloaded on TiO2?nanotube arrays. The Cu2O nanowires with a diameter of less than 5?nm were assembled on the top surface of n-type TiO2?nanotube arrays, constructing a novel p?n jun…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Facile preparation of Carbon nanotubes and graphene sheets by a catalyst-free refluxing approach

Jinyong Wang、Wei Li、Fei Peng 等 4 位作者2012-08-06Nano Research

A facile catalyst-free one-step approach for the preparation of carbon nanotubes and graphene sheets at ambient pressure and ∼ 230 °C has been developed. Carbon nanotubes and graphene sheets are prepared by reducing tetrachloroethylene with sodium in paraffin oil under reflux. The as-prepared products can be easily pu…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

QUANTIFYING NANOPARTICLE TRANSPORTIN VIVOUSING HYPERSPECTRAL IMAGING WITH A DORSAL SKINFOLD WINDOW CHAMBER

Trevor D. McKee、Juan Chen、Ian R. Corbin 等 5 位作者2012-08-06Journal of Innovative Optical Health Sciences

We have developed a noninvasive imaging method to quantify in vivo drug delivery pharmacokinetics without the need for blood or tissue collection to determine drug concentration. By combining the techniques of hyperspectral imaging and a dorsal skinfold window chamber, this method enabled the real-time monitoring of v…

Nanoparticle-Based Drug DeliveryAngiogenesis and VEGF in CancerNanoplatforms for cancer theranostics

Vibrational Study of Dipotassium Zinc Bis(Dihydrogendiphosphate) Dihydrate, K2ZN(H2P2O7)2·2H2O

Redouane Khaoulaf、Mustapha Ezzaafrani、A. Ennaciri 等 5 位作者2012-08-06Phosphorus, sulfur, and silicon and the related elements

Infrared and Raman spectra of dipotassium zinc bis(dihydrogendiphosphate) dihydrate, K2Zn(H2P2O7)2 .2H2O have been collected and interpreted using factor group analysis. Noncoincidence of the Raman and infrared spectra bands confirms a centrosymmetric structure for K2Zn(H2P2O7)2 .2H2O previously investigated by X-ray…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Quantum mechanical study of plasmonic coupling in sodium nanoring dimers

Haifeng Yin、Hong Zhang2012-08-06Applied Physics Letters

In sodium nanoring dimers, plasmon resonances and the plasmon-induced field enhancement are investigated by time-dependent density functional theory. The optical absorption, the induced charge response, and the frequency dependent current demonstrate that the main plasmon resonance modes are the charge transfer plasmo…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Site-Selective Spectroscopy of Garnet Crystals Doped with Chromium Ions

Hümeyra Örücü、G. Özen、Baldassare Di Bartolo 等 4 位作者2012-08-06The Journal of Physical Chemistry A

Site-selective spectroscopy is a tool that can be used to uncover the presence of multiple sites available to optically active ions in host lattices. In this Article, we present techniques that can be applied to appraise the different sites that may occur in systems where charge compensation is required or in systems…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Systematic tailoring of water absorption in photopolymerizable (meth)acrylate networks and its effect on mechanical properties

Nishant Lakhera、Kathryn E. Smith、Carl P. Frick2012-08-06Journal of Applied Polymer Science

Abstract Photopolymerizable (meth)acrylate networks offer several advantages as biomedical materials including their ability to be formed in situ , fast synthesis rates, and tailorable material properties. The objective of this study was to identify how phosphate buffered saline (PBS) absorption affects the thermomech…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingPhotopolymerization techniques and applications

Crystallization of Glycine by Drowning-Out Combined with Fines Dissolution and Cooling Process with in Situ Control using Focused Beam Reflectance Measurement and Attenuated Total Reflection–Fourier Transform Infrared Spectroscopy

Jun‐Woo Kim、Kee‐Kahb Koo2012-08-06Crystal Growth & Design

The DFC process (a combined process of drowning-out, fines dissolution, and cooling crystallization) was applied for the crystallization of glycine. The DFC process encourages seed crystals to grow further by the dissolution of fines generated by drowning-out. Therefore, glycine crystals obtained through the DFC proce…

Enzyme Structure and FunctionCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Fabrication of mesenchymal stem cells-integrated vascular constructs mimicking multiple properties of the native blood vessels

Feng Wang、Zhenqing Li、Jianjun Guan2012-08-06Journal of Biomaterials Science Polymer Edition

Mesenchymal stem cells (MSCs)-populated small diameter (6 mm) vascular constructs were fabricated. The constructs mimicked the native vessels in multiple levels, i.e. having similar structure and morphology to that of the extracellular matrix in the native blood vessels; recapitulating mechanical properties such as co…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

In-situmeasurement of annealing kinetics of individual bulk grains in nanostructured aluminium

Guilin Wu、Dorte Juul Jensen2012-08-06The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Non-destructive three-dimensional X-ray diffraction (3DXRD) was used to characterise the coarsening and growth of bulk crystallites in very heavily deformed aluminium in-situ during isothermal annealing. It was found that initially during the annealing, coarsening by recovery dominates. Later recrystallisation starts…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Synthesis and characterization of polypyrrole‐platinum composite for use as electrode material

R. Jayasree、R. Chandrasekar、L. Cindrella2012-08-06Polymer Composites

Abstract Synthesis and characterization of polypyrrole (PPy) supported platinum by a simple method is reported in this study. The porous structure of PPy and its tendency for doping with acids prompted us to utilize this property to incorporate platinum by adsorption followed by reduction on the PPy matrix. Dispersed…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Computational studies of the corrosion‐inhibition efficiency of iron by triazole surfactants

M'hamed Touil、Najat Hajjaji、Dage Sundholm 等 4 位作者2012-08-06International Journal of Quantum Chemistry

Abstract The corrosion‐inhibition efficiency of N ‐decyl‐1,2,4‐triazole, N ‐undecyl‐1,2,4‐triazole, and N ‐dodecyl‐1,2,4‐triazole surfactants and the corresponding protonated molecules have been studied computationally using density functional theory and second‐order Møller–Plesset calculations. Corrosion‐inhibition p…

Metal complexes synthesis and propertiesCorrosion Behavior and InhibitionSurfactants and Colloidal Systems

Fast excited state diffusion in a-As2Se3 chalcogenide films

Abhishesh Regmi、Ashtosh Ganjoo、Donghui Zhao 等 5 位作者2012-08-06Applied Physics Letters

Transient grating experiments after optical band-gap pulsed illumination of amorphous a-As2Se3 thin films reveal the existence of a well defined transport process occurring on length- and time-scales of the order of micrometers and microseconds, respectively. We tentatively assign this fast process, corresponding to a…

Liquid Crystal Research AdvancementsThin-Film Transistor TechnologiesPhase-change materials and chalcogenides

Piezoelectricity and local structural distortions in (Na0.5Bi0.5)1−xSrxTiO3-Bi12TiO20 flexoelectric-type polar ceramics

L. H. Wang、Ming Zhao、Chunlei Wang 等 6 位作者2012-08-06Applied Physics Letters

We have previously described sintered Na0.5Bi0.5TiO3-Bi12TiO20 composites as flexoelectric-type polar ceramics because they have a net macroscopic flexoelectric polarization. Here, we report on the universal existence of the macroscopic flexoelectric polarization in the (Na0.5Bi0.5)1−xSrxTiO3-Bi12TiO20 system, in whic…

Ferroelectric and Piezoelectric MaterialsVibration Control and Rheological FluidsNonlocal and gradient elasticity in micro/nano structures

Modification of Polycarbonate and Glycol Modified Poly(ethylene terephthalate) by Addition of Silica‐Nanoparticles Grafted with SAN Copolymer Using “Classical” and ARGET ATRP

Andreas Haase、Pascal Hesse、Lars Brommer 等 8 位作者2012-08-06Macromolecular Materials and Engineering

Abstract This study presents a nanocomposite manufacturing route starting from non‐functionalized nanosilica and SAN surface modification via “grafting from” ATRP up to processing of transparent polycarbonate and glycol modified poly(ethylene terephthalate) nanocomposites. Synthesis limitations of low molecular weight…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesOrthopaedic implants and arthroplasty

Thermal properties of layered cobaltitesRBaCo2O5.5(R=Y, Gd, and Tb)

J. Więckowski、M. Gutowska、A. Szewczyk 等 8 位作者2012-08-06Physical Review B

Specific heat studies of a series of $R$BaCo${}_{2}$O${}_{5.5}$ $(R=\text{Y}$, Gd, and Tb) layered cobaltites are reported. They were aimed at explaining an influence of different rare-earth ions on thermal properties of these compounds and at studying phase transitions appearing in them. The studies were performed ov…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics