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A reversible light-operated nanovalve on mesoporous silica nanoparticles

Derrick Tarn、Daniel P. Ferris、Jonathan C. Barnes 等 6 位作者2014-01-01Nanoscale

Two azobenzene α-cyclodextrin based nanovalves are designed, synthesized and assembled on mesoporous silica nanoparticles. Under aqueous conditions, the cyclodextrin cap is tightly bound to the azobenzene moiety and capable of holding back loaded cargo molecules. Upon irradiation with a near-UV light laser, trans to c…

Advanced biosensing and bioanalysis techniquesMesoporous Materials and CatalysisElectrowetting and Microfluidic Technologies

Low-cost synthesis of carbon nanodots from natural products used as a fluorescent probe for the detection of ferrum(iii) ions in lake water

Jingyi Xu、Ying Zhou、Shuxian Liu 等 5 位作者2014-01-01Analytical Methods

A simple, low cost, and green method was developed for the synthesis of water-soluble and well-dispersed fluorescent carbon nanodots (CDs) via a one-step hydrothermal treatment of potatoes. The as-prepared CDs exhibit a strong blue fluorescence, with a quantum yield of up to 15%. We further explored the use of these C…

Heavy Metal Exposure and ToxicityMercury impact and mitigation studiesCarbon and Quantum Dots Applications

Two-dimensional layered semiconductor/graphene heterostructures for solar photovoltaic applications

Mariyappan Shanmugam、Robin Jacobs-Gedrim、Eui Sang Song 等 4 位作者2014-01-01Nanoscale

Schottky barriers formed by graphene (monolayer, bilayer, and multilayer) on 2D layered semiconductor tungsten disulfide (WS2) nanosheets are explored for solar energy harvesting. The characteristics of the graphene-WS2 Schottky junction vary significantly with the number of graphene layers on WS2, resulting in differ…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Nanostructured electrochromic films by inkjet printing on large area and flexible transparent silver electrodes

Michael Layani、Peter Darmawan、Wan Ling Foo 等 8 位作者2014-01-01Nanoscale

Printed electrochromic flexible films were obtained by combining transparent silver grid electrodes formed by self-assembly and inkjet printed WO3 nanoparticles. Concentrated dispersions of WO3 nanoparticles were inkjet printed on transparent plastic silver grid electrodes with a high transparency of 83% in the spectr…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Nanocomposite films and coatings using inorganic nanobuilding blocks (NBB): current applications and future opportunities in the food packaging sector

Ilke Uysal‐Unalan、Guido Cerri、Eva Marcuzzo 等 5 位作者2014-01-01RSC Advances

The aim of this review is to provide an in-depth overview on the use of inorganic nano-sized entities for the generation of nanocomposite materials in the form of films and coatings for food packaging applications. According to recent trends toward “green” strategies, special focus has been dedicated to the developmen…

Nanocomposite Films for Food PackagingPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Liquid acid-catalysed fabrication of nanoporous 1,3,5-triazine frameworks with efficient and selective CO2 uptake

Shaohui Xiong、Xian Fu、Lu Xiang 等 9 位作者2014-01-01Polymer Chemistry

New classes of nanoporous organic polymers based on 1,3,5-triazine units (NOP-1–6) were synthesized via a straightforward, methane-sulfonic acid-catalysed, cost-effective Friedel–Crafts reaction of 2,4,6-trichloro-1,3,5-triazine and tetrahedral building blocks. Among them, NOP-3 with a Brunauer–Emmet–Teller (BET) spec…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Synthesis of graphene/Ni–Al layered double hydroxide nanowires and their application as an electrode material for supercapacitors

Jamil R. Memon、Jinhua Sun、Dongli Meng 等 8 位作者2014-01-01Journal of Materials Chemistry A

Graphene oxide (GO) as a template for the morphology controllable synthesis of inorganic particles has recently attracted enormous attention. In this study, we report the synthesis of graphene/Ni–Al layered double hydroxide (LDH) nanowires by using GO and adjusting the loading of urea in hydrothermal reactions. Transm…

Advanced Photocatalysis TechniquesSupercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and Applications

Bidentate-complex-derived TiO2/carbon dot photocatalysts: in situ synthesis, versatile heterostructures, and enhanced H2 evolution

Jing Wang、Minmin Gao、Ghim Wei Ho2014-01-01Journal of Materials Chemistry A

In this paper, we demonstrate a series of metal-free and inexpensive TiO2/carbon dot (CD) nanocomposites via facile hydrothermal synthesis from bidentate complexes of a green carbon source, vitamin C (VC). Other than the importance of deriving CDs from alternate carbon materials instead of graphitic precursors, the in…

Advanced Photocatalysis TechniquesCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis

Generalized phase behavior of cluster formation in colloidal dispersions with competing interactions

P. Douglas Godfrin、Néstor E. Valádez-Pérez、Ramón Castañeda-Priego 等 5 位作者2014-01-01Soft Matter

Colloidal liquids interacting with short range attraction and long range repulsion, such as proposed for some protein solutions, have been found to exhibit novel states consisting of equilibrium particle clusters. Monte Carlo simulations are performed for two physically meaningful inter-particle potentials across a br…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Silk dissolution and regeneration at the nanofibril scale

Feng Zhang、Qiang Lü、Jinfa Ming 等 10 位作者2014-01-01Journal of Materials Chemistry B

Native silk features strong, extensible and tough properties which originate from its hierarchical nanofibril structure. In the present study, native silk nanofibrils were obtained by dissolving degummed silk in salt–formic acid (FA), such as CaCl2–FA. The CaCl2–FA dissolved silk by breaking hydrogen bonds in the crys…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Spinning of carbon nanotube fibres using the floating catalyst high temperature route: purity issues and the critical role of sulphur

Thurid Gspann、Fiona Smail、Alan H. Windle2014-01-01Faraday Discussions

The CVD process for the spinning of carbon nanotube (CNT) fibres combines the nucleation, growth and aggregation of CNTs in the form of an aerogel with fibre spinning into a single process step. The optimisation of the process requires agility in multi-dimensional parameter space, so one tends to find parameter 'islan…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Two-dimensional semiconductors with possible high room temperature mobility

WenXU、Zhang、Zhishuo 等 7 位作者2014-01-01纳米研究:英文版

M (=瞬间, W , Sn , Hf , Zr 和磅)是转变金属的 2 ,,和 X 是 S , Se 和 Te 。我们由变丑潜力近似对待散布矩阵。我们从 14 混合物发现了那,尘埃 2 , HfSe 2 和 ZrSe 2 正在答应考虑到他们的可能的高活动性和有限乐队差距。有限活动性能在 2,500 厘米上面的声子 2 ? 抌??

Semiconductor Quantum Structures and Devices2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

Exciton diffusion in monolayer and bulk MoSe 2

Nardeep Kumar、Qiannan Cui、Frank Ceballos 等 6 位作者2014-01-01Nanoscale

The exciton dynamics in monolayer and bulk MoSe2 samples are studied by transient absorption microscopy with a high spatiotemporal resolution. Excitons are injected with a point-like spatial distribution using a tightly focused femtosecond pulse. The spatiotemporal dynamics of these excitons are monitored by measuring…

Perovskite Materials and Applications2D Materials and ApplicationsQuantum Dots Synthesis And Properties

Morphology control, defect engineering and photoactivity tuning of ZnO crystals by graphene oxide – a unique 2D macromolecular surfactant

Xiaoyang Pan、Min‐Quan Yang、Yi‐Jun Xu2014-01-01Physical Chemistry Chemical Physics

Zinc oxide (ZnO) nanostructured materials have received significant attention because of their unique physicochemical and electronic properties. In particular, the functional properties of ZnO are strongly dependent on its morphology and defect structure, particularly for a semiconductor ZnO-based photocatalyst. Here,…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Surface properties of α-MnO 2 : relevance to catalytic and supercapacitor behaviour

D. A. Tompsett、Stephen C. Parker、M. Saiful Islam2014-01-01Journal of Materials Chemistry A

First-principles methods demonstrate the presence of facile oxygen vacancy formation at surfaces of α-MnO 2 , important to its good catalytic activity.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationNanomaterials for catalytic reactions

Enhancing thermoelectric properties of a p-type Mg 3 Sb 2 - based Zintl phase compound by Pb substitution in the anionic framework

A. Bhardwaj、D. K. Misra2014-01-01RSC Advances

Pb substitution on anionic site of Mg 3 Sb 2 structure enhances the power factor and simultaneously reduces the thermal conductivity which leads to a ZT ≈ 0.84 at 773 K for Mg 3 Sb 1.8 Pb 0.2 alloy. The enhanced ZT of this system is comparable to bismuth telluride and selenide industrial materials which are toxic and…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity

Sliding Wear Properties of Jute Fabric Reinforced Polypropylene Composites

Temesgen Berhanu Yallew、Pradeep Kumar、Inderdeep Singh2014-01-01Procedia Engineering

Nowadays, advanced plant fiber reinforced composites have captured the attention of many important manufacturing sectors such as the construction, automotive, and packaging industries. Recently, Jute fiber reinforced composites have replaced the most widely used synthetic fiber (glass, kevlar) reinforced composites in…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesTribology and Wear Analysis

The yin: an adverse health perspective of nanoceria: uptake, distribution, accumulation, and mechanisms of its toxicity

Robert A. Yokel、Salik Hussain、Stavros Garantziotis 等 6 位作者2014-01-01Environmental Science Nano

, which becomes more relevant as particle size decreases and the ratio of surface area to volume increases. Given its biopersistence and resulting increased toxicity with time, there is a risk that long-term exposure to low nanoceria levels may eventually lead to adverse health effects. This critical review provides r…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis