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The yin: an adverse health perspective of nanoceria: uptake, distribution, accumulation, and mechanisms of its toxicity

Robert A. Yokel、Salik Hussain、Stavros Garantziotis 等 6 位作者2014-01-01Environmental Science Nano

, which becomes more relevant as particle size decreases and the ratio of surface area to volume increases. Given its biopersistence and resulting increased toxicity with time, there is a risk that long-term exposure to low nanoceria levels may eventually lead to adverse health effects. This critical review provides r…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis

Polypyrrole nanoparticles as promising enzyme mimics for sensitive hydrogen peroxide detection

Yu Tao、Enguo Ju、Jinsong Ren 等 4 位作者2014-01-01Chemical Communications

We discovered for the first time that the polypyrrole nanoparticles possess intrinsic peroxidase-like activity, which can be employed to quantitatively monitor the H2O2 generated by macrophages.

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

A combined DFT + U and Monte Carlo study on rare earth doped ceria

Steffen Grieshammer、Benjamin O. H. Grope、Julius Koettgen 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

We investigate the dopant distribution and its influence on the oxygen ion conductivity of ceria doped with rare earth oxides by combining density functional theory and Monte Carlo simulations. We calculate the association energies of dopant pairs, oxygen vacancy pairs and between dopant ions and oxygen vacancies by m…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsCatalysis and Oxidation Reactions

Conversion efficiency of skutterudite-based thermoelectric modules

James R. Salvador、Jung Y. Cho、Zuxin Ye 等 12 位作者2014-01-01Physical Chemistry Chemical Physics

Presently, the only commercially available power generating thermoelectric (TE) modules are based on bismuth telluride (Bi2Te3) alloys and are limited to a hot side temperature of 250 °C due to the melting point of the solder interconnects and/or generally poor power generation performance above this point. For the pu…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

The d-p band-inversion topological insulator in bismuth-based skutterudites

Ming Yang、Wu-Ming Liu2014-01-01arXiv

Skutterudites, a class of materials with cage-like crystal structure which have received considerable research interest in recent years, are the breeding ground of several unusual phenomena such as heavy fermion superconductivity, exciton-mediated superconducting state and Weyl fermions. Here, we predict a new topolog…

Materials Science

Enhancement of non-resonant dielectric cloaks using anisotropic composites

Akihiro Takezawa、Mitsuru Kitamura2014-01-01AIP Advances

Cloaking techniques conceal objects by controlling the flow of electromagnetic waves to minimize scattering. Herein, the effectiveness of homogenized anisotropic materials in non-resonant dielectric multilayer cloaking is studied. Because existing multilayer cloaking by isotropic materials can be regarded as homogenou…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Realization of Pristine and Locally-Tunable One-Dimensional Electron Systems in Carbon Nanotubes

Jonah Waissman、Maayan Honig、Sharon Pecker 等 6 位作者2014-01-01arXiv

Recent years have seen the development of several experimental systems capable of tuning local parameters of quantum Hamiltonians. Examples include ultracold atoms, trapped ions, superconducting circuits, and photonic crystals. By design, these systems possess negligible disorder, granting them a high level of tunabil…

Mesoscale and Nanoscale PhysicsMaterials Science

Dependence of coupling of quasi 2-D MoS 2 with substrates on substrate types, probed by temperature dependent Raman scattering

Liqin Su、Yong Zhang、Yifei Yu 等 4 位作者2014-01-01Nanoscale

This work reports a study on the temperature dependence of in-plane E and out-of-plane A1g Raman modes of single-layer (1L) and bi-layer (2L) MoS2 films on sapphire (epitaxial) and SiO2 (transferred) substrates as well as bulk MoS2 single crystals in a temperature range of 25-500 °C. For the films on the transferred S…

Graphene research and applications2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting Materials

Ultrathin g-C 3 N 4 /TiO 2 composites as photoelectrochemical elements for the real-time evaluation of global antioxidant capacity

Weiguang Ma、Dongxue Han、Min Zhou 等 7 位作者2014-01-01Chemical Science

Using utg-C 3 N 4 /TiO 2 , a photoelectrochemical platform was designed for the sensing of global antioxidant capacity, which presented a rapid response, and anti-fouling and colour-interference-proof properties.

Electrochemical sensors and biosensorsElectrochemical Analysis and ApplicationsAdvanced Nanomaterials in Catalysis

Two-step reduction of self-assembed three-dimensional (3D) reduced graphene oxide (RGO)/zinc oxide (ZnO) nanocomposites for electromagnetic absorption

Fan Wu、Yilu Xia、Yuan Wang 等 4 位作者2014-01-01Journal of Materials Chemistry A

Graphene oxide and zinc oxide nanoparticles have formed a three-dimensional nanocomposite with a high performance of electromagnetic absorption via a hydrothermal process. UV-irradiation removed the remaining oxygen functional groups from the skeleton of the reduced graphene oxide.

Graphene research and applicationsElectromagnetic wave absorption materialsPolymer Nanocomposite Synthesis and Irradiation

Energy consumption of the nanofibrillation of bleached pulp, wheat straw and recycled newspaper through a grinding process

Sébastien Josset、Paola Orsolini、Gilberto Siqueira 等 6 位作者2014-01-01Nordic Pulp & Paper Research Journal

Article Energy consumption of the nanofibrillation of bleached pulp, wheat straw and recycled newspaper through a grinding process was published on January 1, 2014 in the journal Nordic Pulp & Paper Research Journal (volume 29, issue 1).

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Non-linear optical properties of gold quantum clusters. The smaller the better

Isabelle Russier‐Antoine、Franck Bertorelle、Marin Vojković 等 9 位作者2014-01-01Nanoscale

By developing a new method for synthesizing atomically monodisperse Au15 nanoclusters stabilized with glutathione molecules and using the current state-of-the-art methods for synthesizing monodisperse protected Au25 nanoclusters, we investigated their nonlinear optical (NLO) properties after two-photon absorption. The…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Fundamental challenges in packing problems: from spherical to non-spherical particles

Adrian Baule、Hernán A. Makse2014-01-01Soft Matter

Random packings of objects of a particular shape are ubiquitous in science and engineering. However, such jammed matter states have eluded any systematic theoretical treatment due to the strong positional and orientational correlations involved. In recent years progress on a fundamental description of jammed matter co…

Proteins in Food SystemsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

Polyurethane microcapsules for self-healing paint coatings

Eunjoo Koh、Nam‐Kyun Kim、Jihoon Shin 等 4 位作者2014-01-01RSC Advances

Polyurethane microcapsules containing water-borne polyurethane (PU) paint as a core material for self-repairing protection coatings were successfully manufactured via interfacial polymerization of diol–diisocyanate prepolymer and 1,4-butanediol as a chain extender in an emulsion solution.

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingAntimicrobial agents and applications

Advanced thermoelectrics governed by a single parabolic band: Mg 2 Si 0.3 Sn 0.7 , a canonical example

Wei Liu、Hang Chi、Hui Sun 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

The well-known single parabolic band (SPB) model has been useful in providing insights into the understanding of transport properties of numerous thermoelectric materials. However, the conduction and valence bands of real semiconductors are rarely truly parabolic which limits the predictive power of the SPB model. The…

Advanced Thermoelectric Materials and DevicesHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity

A liquid azobenzene derivative as a solvent-free solar thermal fuel

Kouta Masutani、Masa‐aki Morikawa、Nobuo Kimizuka2014-01-01Chemical Communications

A liquid solar thermal fuel is developed; a low-molecular weight liquid trans-azobenzene derivative shows facile photoisomerization to the higher-energy cis-isomer in neat condition so that a high volumetric energy density is achieved. Shear viscosity measurements for each isomer liquid unveiled transitions from non-N…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsPhotochromic and Fluorescence Chemistry

Magnetic, superhydrophobic and durable silicone sponges and their applications in removal of organic pollutants from water

Lingxiao Li、Bucheng Li、Lei Wu 等 5 位作者2014-01-01Chemical Communications

Porous silicone sponges are fabricated by polymerization of organosilanes in the presence of Fe3O4@silica nanoparticles. The sponges feature fast magnetic responsivity, superhydrophobicity/superoleophilicity, high compressibility and stability. The sponges can selectively absorb floating oils on a water surface, heavy…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics