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Encapsulated phase change materials stabilized by modified graphene oxide

Yi Zhang、Xianhua Zheng、Haitao Wang 等 4 位作者2014-01-01Journal of Materials Chemistry A

The microencapsulation of phase change materials (n-hexadecane) with double-walled shells (polystyrene/graphene oxide) was realized from Pickering emulsion templating. Graphene oxide nanosheets were modified by the polycondensate of diethanolamine and adipic acid, which can well stabilize oil-in-water (O/W) Pickering…

Polymer composites and self-healingAdvanced Materials and MechanicsPickering emulsions and particle stabilization

Quantum dots in diagnostics and detection: principles and paradigms

Thomas R. Pisanic、Yi Zhang、T. H. Wang2014-01-01The Analyst

Quantum dots are semiconductor nanocrystals that exhibit exceptional optical and electrical behaviors not found in their bulk counterparts. Following seminal work in the development of water-soluble quantum dots in the late 1990's, researchers have sought to develop interesting and novel ways of exploiting the extraor…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesAdvanced Nanomaterials in Catalysis

Charge carrier mobility in organic molecular materials probed by electromagnetic waves

Shu Seki、Akinori Saeki、Tsuneaki Sakurai 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

Charge carrier mobility is an essential parameter providing control over the performance of semiconductor devices fabricated using a variety of organic molecular materials. Recent design strategies toward molecular materials have been directed at the substitution of amorphous silicon-based semiconductors; accordingly,…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Magnetic iron oxide–fluorescent carbon dots integrated nanoparticles for dual-modal imaging, near-infrared light-responsive drug carrier and photothermal therapy

Hui Wang、Jing Shen、Yingyu Li 等 9 位作者2014-01-01Biomaterials Science

The multifunctional hybrid nanoparticles described demonstrate great promise towards advanced nanoplatforms for simultaneous imaging diagnostics and high efficacy therapy.

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Advances in the environmental transmission electron microscope (ETEM) for nanoscale in situ studies of gas–solid interactions

Joerg R. Jinschek2014-01-01Chemical Communications

Although available since the early days of electron microscopy, recent technology developments of the environmental transmission electron microscope (ETEM) have enabled new research in the study of nanomaterials in gaseous environments. Significant improvements in scanning/transmission electron microscope (S/TEM) tech…

Electrocatalysts for Energy ConversionAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Fast one-step synthesis of N-doped carbon dots by pyrolyzing ethanolamine

Xinwei Dong、Yanjie Su、Huijuan Geng 等 7 位作者2014-01-01Journal of Materials Chemistry C

N-doped CDs can be obtained directly with high yield by pyrolyzing ethanolamine in air within just 7 minutes with the assistance of hydrogen peroxide.

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Multichromophoric electrochromic polymers: colour tuning of conjugated polymers through the side chain functionalization approach

Luca Beverina、G. Pagani、Mauro Sassi2014-01-01Chemical Communications

Organic electrochromic materials have gained constantly increasing interest over the years with respect to their inorganic counterpart due to essentially two distinctive characteristics: their processability through solution based low cost processes and their wide colour palette. Such characteristic features enabled t…

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications

One pot synthesis of monodisperse water soluble iron oxide nanocrystals with high values of the specific absorption rate

Pablo Guardia、Andreas Riedinger、Simone Nitti 等 10 位作者2014-01-01Journal of Materials Chemistry B

We report a highly reproducible route to synthesize iron oxide nanoparticles (IONPs) with control over size and shape and with size dispersions around 10%. By tuning the relative ratio of squalane to dibenzyl ether, which were used as solvents in the synthesis, the size of the particles could be varied from 14 to arou…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Direct validation of the restriction of intramolecular rotation hypothesis via the synthesis of novel ortho-methyl substituted tetraphenylethenes and their application in cell imaging

Guofeng Zhang、Ze‐Qiang Chen、Matthew P. Aldred 等 8 位作者2014-01-01Chemical Communications

We demonstrate a novel synthetic approach to ortho-methyl substituted tetraphenylethene materials, which can be utilised for directly validating the restriction of intramolecular rotation hypothesis as the basic mechanism of aggregation-induced emission phenomenon and cell imaging.

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Preparation and Characterization of Biodegradable PLA/PCL Polymeric Blends

A.K. Matta、R. Umamaheswara Rao、K.N.S. Suman 等 4 位作者2014-01-01Procedia Materials Science

In this study, blends of biodegradable Poly (lactic acid) (PLA) and Polycaprolactone (PCL), were prepared using Hakee Rheomix and characterized for rheological, thermal, mechanical and viscoelastic properties. Morphology of tensile fractured surfaces was examined through scanning electron microscopy (SEM). The blends…

biodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing TechnologiesCarbon dioxide utilization in catalysis

Photo-mechanical azobenzene cocrystals and in situ X-ray diffraction monitoring of their optically-induced crystal-to-crystal isomerisation

Oleksandr S. Bushuyev、T. Christopher Corkery、Christopher J. Barrett 等 4 位作者2014-01-01Chemical Science

We demonstrate the first supramolecular cocrystallisation strategy for generating crystalline azobenzene materials with a range of photo-mechanical and thermochemical properties: from those that exhibit isomerisation without any change in crystal shape to those that undergo a crystal-to-crystal cis – trans isomerisati…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Dissecting the steps of CO 2 reduction: 1. The interaction of CO and CO 2 with γ-Al 2 O 3 : an in situ FTIR study

János Szanyi、Ja Hun Kwak2014-01-01Physical Chemistry Chemical Physics

The adsorption of CO2 and CO was investigated on a pure γ-Al2O3 support material that has been used in Pd and Ru catalysts for the reduction of CO2. The adsorption of CO2 resulted in the formation of carbonates, bicarbonates and linearly adsorbed CO2 species. The amount and the nature of the adsorbed species were depe…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Enhanced up-conversion and temperature-sensing behaviour of Er 3+ and Yb 3+ co-doped Y 2 Ti 2 O 7 by incorporation of Li + ions

Bheeshma Pratap Singh、Abdul K. Parchur、R. S. Ningthoujam 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

Y2Ti2O7:Er(3+)/Yb(3+) (EYYTO) phosphors co-doped with Li(+) ions were synthesized by a conventional solid-state ceramic method. X-ray diffraction studies show that all the Li(+) co-doped EYYTO samples are highly crystalline in nature with pyrochlore face centred cubic structure. X-ray photon spectroscopy studies revea…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsMicrowave Dielectric Ceramics Synthesis

Nanostructured CuO/reduced graphene oxide composite for hybrid supercapacitors

Kamatchi Kamaraj Purushothaman、Balakrishanan Saravanakumar、I. Manohara Babu 等 5 位作者2014-01-01RSC Advances

To address the issues such as low ionic conductivity, poor electrode kinetics and cyclic stability, the strategy of combining carbon-based materials with transition metal oxide (TMO) is adopted. In this article, the preparation of CuO/reduced graphene oxide (RGO) nanocomposite electrodes by a simple, low cost hydrothe…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

On the upconversion fluorescence in carbon nanodots and graphene quantum dots

Xiaoming Wen、Pyng Yu、Yon‐Rui Toh 等 5 位作者2014-01-01Chemical Communications

Upconversion fluorescence has been frequently cited as an important feature in carbon nanodots (CNDs) and graphene quantum dots (GQDs); and some mechanisms and potential applications have been proposed. Contrary to such a general belief, we demonstrate in this report no observable upconversion fluorescence based on fi…

Graphene research and applicationsLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Towards polymetallic lanthanide complexes as dual contrast agents for magnetic resonance and optical imaging

Elke Debroye、Tatjana N. Parac‐Vogt2014-01-01Chemical Society Reviews

Magnetic resonance imaging (MRI) is a popular imaging technique in medical diagnostics. With the development of contrast agents, interest in its applications has grown tremendously. Significant effort has been made in order to identify the most important parameters that enhance the relaxation efficiency of MRI probes.…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

High-power and high-energy asymmetric supercapacitors based on Li + -intercalation into a T-Nb 2 O 5 /graphene pseudocapacitive electrode

Lingping Kong、Chuanfang Zhang、Songmin Zhang 等 9 位作者2014-01-01Journal of Materials Chemistry A

T-Nb 2 O 5 /graphene nanocomposites were fabricated and then paired with mesoporous carbon electrodes to construct the asymmetrical supercapacitors with high energy and power densities.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies