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Enhanced up-conversion and temperature-sensing behaviour of Er 3+ and Yb 3+ co-doped Y 2 Ti 2 O 7 by incorporation of Li + ions

Bheeshma Pratap Singh、Abdul K. Parchur、R. S. Ningthoujam 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

Y2Ti2O7:Er(3+)/Yb(3+) (EYYTO) phosphors co-doped with Li(+) ions were synthesized by a conventional solid-state ceramic method. X-ray diffraction studies show that all the Li(+) co-doped EYYTO samples are highly crystalline in nature with pyrochlore face centred cubic structure. X-ray photon spectroscopy studies revea…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsMicrowave Dielectric Ceramics Synthesis

Nanostructured CuO/reduced graphene oxide composite for hybrid supercapacitors

Kamatchi Kamaraj Purushothaman、Balakrishanan Saravanakumar、I. Manohara Babu 等 5 位作者2014-01-01RSC Advances

To address the issues such as low ionic conductivity, poor electrode kinetics and cyclic stability, the strategy of combining carbon-based materials with transition metal oxide (TMO) is adopted. In this article, the preparation of CuO/reduced graphene oxide (RGO) nanocomposite electrodes by a simple, low cost hydrothe…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

On the upconversion fluorescence in carbon nanodots and graphene quantum dots

Xiaoming Wen、Pyng Yu、Yon‐Rui Toh 等 5 位作者2014-01-01Chemical Communications

Upconversion fluorescence has been frequently cited as an important feature in carbon nanodots (CNDs) and graphene quantum dots (GQDs); and some mechanisms and potential applications have been proposed. Contrary to such a general belief, we demonstrate in this report no observable upconversion fluorescence based on fi…

Graphene research and applicationsLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Towards polymetallic lanthanide complexes as dual contrast agents for magnetic resonance and optical imaging

Elke Debroye、Tatjana N. Parac‐Vogt2014-01-01Chemical Society Reviews

Magnetic resonance imaging (MRI) is a popular imaging technique in medical diagnostics. With the development of contrast agents, interest in its applications has grown tremendously. Significant effort has been made in order to identify the most important parameters that enhance the relaxation efficiency of MRI probes.…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

High-power and high-energy asymmetric supercapacitors based on Li + -intercalation into a T-Nb 2 O 5 /graphene pseudocapacitive electrode

Lingping Kong、Chuanfang Zhang、Songmin Zhang 等 9 位作者2014-01-01Journal of Materials Chemistry A

T-Nb 2 O 5 /graphene nanocomposites were fabricated and then paired with mesoporous carbon electrodes to construct the asymmetrical supercapacitors with high energy and power densities.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

High surface area hypercrosslinked microporous organic polymer networks based on tetraphenylethylene for CO 2 capture

Shuwen Yao、Xiao Yang、Miao Yu 等 5 位作者2014-01-01Journal of Materials Chemistry A

A series of hypercrosslinked microporous organic copolymer networks was synthesized via Friedel–Crafts alkylation of tetraphenylethylene (TPE) and/or 1,1,2,2-tetraphenylethane-1,2-diol (TPD) promoted by anhydrous FeCl 3 .

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture TechnologiesCovalent Organic Framework Applications

Exchange-coupled nanocomposites: chemical synthesis, characterization and applications

Fei Liu、Yanglong Hou、Song Gao2014-01-01Chemical Society Reviews

Nanocomposites containing soft and hard magnetic phases have attracted immense attention for energy-related and biomedical applications. With exchange coupling between nanoscale grains in the composites, magnetization of the soft magnetic phase can rotate coherently with that of the hard magnetic phase. In particular,…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsNanomaterials for catalytic reactions

Postsynthetic lanthanide functionalization of nanosized metal–organic frameworks for highly sensitive ratiometric luminescent thermometry

You Zhou、Bing Yan、Fang Lei2014-01-01Chemical Communications

A straightforward postsynthetic lanthanide functionalization strategy is developed for fabricating highly sensitive ratiometric luminescent nanothermometers based on nanosized MOFs, which highlights the ability of a broad range of nanosized MOFs to construct nanothermometers.

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Chemically exfoliated ReS 2 nanosheets

Takeshi Fujita、Yoshikazu Ito、Yongwen Tan 等 9 位作者2014-01-01Nanoscale

The production of two-dimensional rhenium disulfide (ReS2) nanosheets by exfoliation using lithium intercalation is demonstrated. The vibrational and photoluminescence properties of the exfoliated nanosheets are investigated, and the local atomic structure is studied by scanning and transmission electron microscopy. T…

2D Materials and ApplicationsChalcogenide Semiconductor Thin FilmsMXene and MAX Phase Materials

Application of short-term inhalation studies to assess the inhalation toxicity of nanomaterials

Robert Landsiedel、Lan Ma‐Hock、Thomas Hofmann 等 10 位作者2014-01-01Particle and Fibre Toxicology

BACKGROUND: A standard short-term inhalation study (STIS) was applied for hazard assessment of 13 metal oxide nanomaterials and micron-scale zinc oxide. METHODS: Rats were exposed to test material aerosols (ranging from 0.5 to 50 mg/m3) for five consecutive days with 14- or 21-day post-exposure observation. Bronchoalv…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsOccupational exposure and asthma

Polymer thermoelectric modules screen-printed on paper

Qingshuo Wei、Masakazu Mukaida、Kazuhiro Kirihara 等 5 位作者2014-01-01RSC Advances

Screen-printed polymer thermoelectric devices provided sufficient power to illuminate light-emitting diodes.

Organic Electronics and PhotovoltaicsAdvanced Thermoelectric Materials and DevicesGreen IT and Sustainability

Coal based activated carbon nanofibers prepared by electrospinning

Hongyang Zhao、Luxiang Wang、Dianzeng Jia 等 6 位作者2014-01-01Journal of Materials Chemistry A

Porous carbon nanofibers were prepared by electrospinning using coal as the raw material. The activated carbon fiber mat is a promising candidate for the electrode of supercapacitors.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical Applications

Green Approach for Fabrication and Applications of Zinc Oxide Nanoparticles

Brajesh Kumar、Kumari Smita、Luis Cumbal 等 4 位作者2014-01-01Bioinorganic Chemistry and Applications

Zinc oxide nanoparticles (ZnO-NPs) are known to be one of the multifunctional inorganic compounds which are widely used in everyday applications. This study aims to fabricate ZnO-NPs using grapefruit (Citrus paradisi) peel extract with particle size ranging from 12 to 72 nm. Structural, morphological, and optical prop…

Nanoparticles: synthesis and applicationsZnO doping and propertiesCopper-based nanomaterials and applications

Remarkable chemical adsorption of manganese-doped titanate for direct carbon dioxide electrolysis

Wentao Qi、Yun Gan、Di Yin 等 7 位作者2014-01-01Journal of Materials Chemistry A

Remarkable chemical adsorption of CO 2 has been achieved in titanate with significant concentration of oxygen vacancies towards the efficient direct CO 2 electrolysis in solid oxide electrolysers.

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Recent progress in the preparation of polyaniline nanostructures and their applications in anticorrosive coatings

Zhifei Tian、Haojie Yu、Li Wang 等 10 位作者2014-01-01RSC Advances

Research on composites/blends containing polyaniline (PANI) has attracted numerous scientists and engineers due to their excellent adhesion and anticorrosive properties. Nano-structured PANI composites and matrix resins play a key role in physical and anticorrosive performance. This paper reviews the synthesis, growth…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Morphological effects of the nanostructured ceria support on the activity and stability of CuO/CeO 2 catalysts for the water-gas shift reaction

Siyu Yao、Wenqian Xu、Aaron C. Johnston‐Peck 等 10 位作者2014-01-01Physical Chemistry Chemical Physics

Three CuO/CeO2 catalyst with different morphologies of ceria, namely nanospheres, nanorods and nanocubes, were synthesized and used to catalyze the water-gas shift (WGS) reaction. The reactivity tests showed that the Cu supported on the ceria nanospheres exhibited both the highest activity and superior stability when…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Stochastic surface walking method for crystal structure and phase transition pathway prediction

Cheng Shang、Xiaojie Zhang、Zhi‐Pan Liu2014-01-01Physical Chemistry Chemical Physics

The determination of crystal structures and the solid-to-solid phase transition mechanisms are two important and related subjects in material science. Here we develop an unbiased general-purpose potential energy surface (PES) searching method, namely, SSW-crystal method, for prediction of both the crystal structure an…

Enzyme Structure and FunctionMachine Learning in Materials Sciencenanoparticles nucleation surface interactions