Materials Literature
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We have investigated the mechanism of the spontaneous growth of a gold nanoparticle film on a container wall when an aqueous dispersion of gold nanoparticles is shaken with an oil phase containing octadecylamine, as first described by Mayya and Sastry (Mayya, K. S.; Sastry, M. Langmuir 1999, 15, 1902.). Experimental e…
This paper investigates the harmonic behavior of three phase power transformers under nonsinusoidal operations. The terminal behavior of the transformer was obtained by coupling the transformer transient finite-element (FE) model and external electric circuits. Such a technique would allow the physical representation…
The cluster [NaCu4L2(N3)2](ClO4) [1; H3L is 2-(2'-hydroxyphenyl)-1,3-bis[3'-aza-4'-(2''-hydroxyphenyl)prop-4'-en-1'-yl]-1,3-imidazolidine] has been synthesized and structurally characterized. Complex 1 is formed by the template assembly of two [Cu2L(N3)] neutral fragments through their weak oxophilic interactions with…
The combination of biomass gasification systems with fuel cells promises adequate systems for sustainable, decentralized energy conversion. Especially high temperature fuel cells are suited for this task because of their higher tolerance to impurities, their internal steam reforming potential, and favorable thermal in…
This paper describes the modeling and design of two-color microbolometers for uncooled infrared (IR) detection. The goal is to develop a high resolution IR detector array that can measure the actual temperature and color of an object based on two spectral wavelength regions. The microbolometer consists of high tempera…
In this paper, a new principle of a smart sensor is proposed, based on three different magnetic effects or operational modes, using the same sensor topology, which consists of a magnetic wire as sensing core, two coils as excitation or search means, and two electric contacts at the ends of the magnetic wire. The magne…
The true three-dimensional finite element numerical solution of Maxwell's equations shows that the propagation of light through a thin flat free-standing metallic screen containing a hole of twisted shape is sensitive to whether the incident wave is left or right circularly polarized. <br/>The intensity map and…
An accurate and efficient nonlinear anisotropic model for soft magnetic materials is developed. In this model, the cross effects of the magnetic field in the different principle directions are decoupled by introducing an equivalent magnetic field magnitude in each principle direction. This equivalence is based on an a…
Abstract Summary: Films of poly( L ‐lactic acid) (PLLA) and copolymers of L ‐lactide (LLA) with either glycolide [P(LLA‐GA)](81/19) or D ‐lactide [P(LLA‐DLA)](77/23) were prepared and an effect of comonomer type on the hydrolytic degradation of the films was studied in phosphate‐buffered solutions at 37 °C. The degrad…
Semicrystalline poly(ethylene terephthalate) (PET) was oriented with an equal channel angular extrusion (ECAE) process at room temperature, which applied simple shear deformation and generated unique asymmetric lamellar texture. In-situ small-angle X-ray scattering (SAXS) measurements were utilized to study the change…
A dynamical vector hysteresis model is presented, which is a generalization of a quasistatic model proposed in a recent paper. The model can be considered from the point of view of a mechanical analogy with the pinning of Bloch walls phenomenon represented by a friction force. By combining several elementary submodels…
This paper presents a method to calculate the vibrations of rotating electrical machines when the magnetostriction and the magnetomechanical coupling are of interest. The method is applied to two kinds of machines (cage induction and synchronous machine). The computations use dynamic numerical models for both magnetic…
Abstract A reversible addition–fragmentation chain transfer (RAFT) polymerization technique was applied to graft polymerize brushes of poly(methyl methacrylate) (PMMA) and poly(poly(ethylene glycol) monomethacrylate) (PPEGMA) from poly(vinylidene fluoride) (PVDF) surfaces. PVDF surfaces were exposed to aqueous LiOH, f…
Abstract A series of novel aromatic poly(ether imide)s (PEI) containing ortho‐catenated phenylene rings and pendant trifluoromethyl group have been prepared from 1,2‐bis(3,4‐dicarboxyphenoxy)benzene dianhydride (1) with seven trifluoromethyl‐substituted aromatic bis(ether amine)s ( 2a‐g ) via a conventional two‐stage…
Poly( l -lactic acid) (PLLA) is a candidate for feedstock recycling materials, because it easily depolymerizes back into the cyclic monomer, l, l -lactide. To examine the recycling of PLLA from blends with other kinds of polymers, a polymer blend of PLLA and linear low-density polyethylene (LLDPE) was prepared and the…
A finite element method is presented to compute the electromagnetic field and hence the temperature rise in complex three-dimensional structures such as power transformers. The temperature dependence of both the heat transfer coefficients and the electric conductivity is taken into account establishing a strong coupli…
Structural, dynamical, and thermal properties of germanium dioxide are investigated with classical molecular dynamics simulations from the amorphous to the liquid state. Pair correlation functions and coordination numbers are computed under pressure change and show the progressive conversion of the tetrahedral network…
This communication reports on the study of microphase separation of well-defined mixed poly(tert-butyl acrylate) (PtBA)/polystyrene (PS) brushes on silica nanoparticles under equilibrium melt conditions. Mixed PtBA/PS brushes were synthesized from an asymmetric, difunctional initiator-terminated self-assembled monolay…
The azido-bridged manganese complex of formula [Mn(tptz)(mu(1,1)-N3)2]n [1; tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine] has been synthesized and characterized by single-crystal X-ray diffraction analysis and a low-temperature magnetic study. The complex 1 crystallizes in the orthorhombic space group Pbcn, with a = 17…
Propylsulfonic acid-functionalized mesoporous silica materials were synthesized using a co-condensation technique. The catalytic performance of the resulting acidic mesoporous materials was evaluated in the methanol esterification of free fatty acids in beef tallow as a pretreatment step for alkyl ester production. Th…